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1.
2.
Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia 总被引:1,自引:0,他引:1
Christophe Migon Sylvain Ouillon Xavier Mari Emmanuel Nicolas 《Estuarine, Coastal and Shelf Science》2007,74(4):756
Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L−1), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L−1 near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources. 相似文献
3.
Christopher L. Dupont James. W. Moffett Robert R. Bidigare Beth A. Ahner 《Deep Sea Research Part I: Oceanographic Research Papers》2006,53(12):1961-1974
Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation. 相似文献
4.
Christoph Förste Roland Schmidt Richard Stubenvoll Frank Flechtner Ulrich Meyer Rolf König Hans Neumayer Richard Biancale Jean-Michel Lemoine Sean Bruinsma Sylvain Loyer Franz Barthelmes Saskia Esselborn 《Journal of Geodesy》2008,82(6):331-346
The recent improvements in the Gravity Recovery And Climate Experiment (GRACE) tracking data processing at GeoForschungsZentrum
Potsdam (GFZ) and Groupe de Recherche de Géodésie Spatiale (GRGS) Toulouse, the availability of newer surface gravity data
sets in the Arctic, Antarctica and North-America, and the availability of a new mean sea surface height model from altimetry
processing at GFZ gave rise to the generation of two new global gravity field models. The first, EIGEN-GL04S1, a satellite-only
model complete to degree and order 150 in terms of spherical harmonics, was derived by combination of the latest GFZ Potsdam
GRACE-only (EIGEN-GRACE04S) and GRGS Toulouse GRACE/LAGEOS (EIGEN-GL04S) mean field solutions. The second, EIGEN-GL04S1 was
combined with surface gravity data from altimetry over the oceans and gravimetry over the continents to derive a new high-resolution
global gravity field model called EIGEN-GL04C. This model is complete to degree and order 360 and thus resolves geoid and
gravity anomalies at half- wavelengths of 55 km at the equator. A degree-dependent combination method has been applied in
order to preserve the high accuracy from the GRACE satellite data in the lower frequency band of the geopotential and to form
a smooth transition to the high-frequency information coming from the surface data. Compared to pre-CHAMP global high-resolution
models, the accuracy was improved at a spatial resolution of 200 km (half-wavelength) by one order of magnitude to 3 cm in
terms of geoid heights. The accuracy of this model (i.e. the commission error) at its full spatial resolution is estimated
to be 15 cm. The model shows a reduced artificial meridional striping and an increased correlation of EIGEN-GL04C-derived
geostrophic meridional currents with World Ocean Atlas 2001 (WOA01) data. These improvements have led to select EIGEN-GL04C
for JASON-1 satellite altimeter data reprocessing.
Electronic Supplementary Material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
5.
Breakthrough tailing has been observed during dye-tracing recovery tests in the Norville aquifer system (chalk), France. Karst-conduit flow and transport parameters were assessed using two different interpretative methods: the linear graphical method and the Chatwin method (implemented in the Qtracer2 program). The linear graphical method was used to model the observed tailing effects, which was explained by a second smaller delayed breakthrough curve. By comparing the results of tracer-test interpretation for the two methods, it was possible to relate the area of this second curve to the importance of turbulent flow in spring discharge. The more turbulent the flow, the less important the contribution of the second breakthrough curve and the tailing effect. The observed tailing could possibly be controlled by hydrodynamics to a greater extent than usually expected, the tailing effects being mostly attributed to diffusion phenomena. Tailing effects were expected to increase with discharge and the piezometric level, which would have resulted in overpressure in conduits, fissure flooding, etc. Instead, breakthrough tailing tended to disappear with increasing aquifer discharge, which would support the hypothesis of there being mostly hydrodynamic-controlled tailing effects instead of matrix- or fissure-diffusion.An erratum to this article can be found at 相似文献
6.
Quality Assessment of Cartographic Generalisation 总被引:2,自引:1,他引:2
Sylvain Bard 《Transactions in GIS》2004,8(1):63-81
This paper proposes a methodology to assess the quality of cartographic generalisa‐tion, which consists of representing geographic space in a simplified way according to the scale and the objectives of the intended map. The automation of this process makes the derivation of data easier, but the quality of the results is often not evaluated. This paper proposes an assessment model based on: (1) characterisation of the data in their initial and final states at different levels of analysis; (2) a data quality assessment by comparison of the two characterisations; and (3) aggregation of the various assessment results to summarise data quality. The assessment algorithm has been implemented and the method has been tested to assess the generalisation of a small urban area. A visualisation tool for assessment of the results has been developed to validate the generalisation evaluation. The results of the research are presented and discussed at the end of the paper. 相似文献
7.
A methodology for regionalizing 3‐D effective porosity at watershed scale in crystalline aquifers 下载免费PDF全文
Benoît Dewandel Yvan Caballero Jérôme Perrin Alexandre Boisson Fabrice Dazin Sylvain Ferrant Subash Chandra Jean‐Christophe Maréchal 《水文研究》2017,31(12):2277-2295
An innovative approach for regionalizing the 3‐D effective porosity field is presented and applied to two large, overexploited, and deeply weathered crystalline aquifers located in southern India. The method derives from earlier work on regionalizing a 2‐D effective porosity field in that part of an aquifer where the water table fluctuates, which is now extended over the entire aquifer using a 3‐D approach. A method based on geological and geophysical surveys has also been developed for mapping the weathering profile layers (saprolite and fractured layers). The method for regionalizing 3‐D effective porosity combines water table fluctuation and groundwater budget techniques at various cell sizes with the use of satellite‐based data (for groundwater abstraction), the structure of the weathering profile, and geostatistical techniques. The approach is presented in detail for the Kudaliar watershed (983 km2) and tested on the 730 km2 Anantapur watershed. At watershed scale, the effective porosity of the aquifer ranges from 0.5% to 2% in Kudaliar and between 0.3% and 1% in Anantapur, which agrees with earlier works. Results show that (a) depending on the geology and on the structure of the weathering profile, the vertical distribution of effective porosity can be very different and that the fractured layers in crystalline aquifers are not necessarily characterized by a rapid decrease in effective porosity and (b) that the lateral variations in effective porosity can be larger than the vertical ones. These variations suggest that within a same weathering profile, the density of open fractures and/or degree of weathering in the fractured zone may significantly vary from a place to another. The proposed method provides information on the spatial distribution of effective porosity that is of prime interest in terms of flux and contaminant transport in crystalline aquifers. Implications for mapping groundwater storage and scarcity are also discussed, which should help in improving groundwater resource management strategies. 相似文献
8.
Lateral extrusion along the Altyn Tagh Fault,Qilian Shan (NE Tibet): insight from a 3D crustal budget 下载免费PDF全文
Feng Cheng Marc Jolivet Guillaume Dupont‐Nivet Lin Wang Xiangjiang Yu Zhaojie Guo 《地学学报》2015,27(6):416-425
The lithospheric strike‐slip Altyn Tagh Fault has accommodated hundreds of kilometres of displacement between the Qaidam and Tarim blocks since its Eocene reactivation. However, the way the deformation is accommodated in the Qilian Shan and further east remains uncertain. Based on 360 km of north‐eastward migration of the relatively rigid Qaidam block along the Altyn Tagh Fault and 3D isovolumetric balancing of the crustal deformation within the Altyn Tagh Fault–Qilian Shan system, we demonstrate that 250 ± 28 km (43.8–49.4%) of N20E directed crustal shortening and an additional ~250–370 km of eastward motion of the Qilian Shan crust must be accounted for by strike‐slip faulting in the Qilian Shan and crustal thickening in the Qinling area, as well as by extension in the adjoining North China block graben systems. 相似文献
9.
Lydie Dupont 《Quaternary Science Reviews》2011,30(25-26):3589-3602
Palynological records of Middle and Late Pleistocene marine sediments off African shores is reviewed in order to reveal long-term patterns of vegetation change during climate cycles. Whether the transport of pollen and spores from the source areas on the continent to the ocean floor is mainly by wind or predominantly by rivers depends on the region. Despite the differences in transportation, accumulation rates in the marine sediments decline exponentially with distance to the shore. The marine sediments provide well-dated records presenting the vegetation history of the main biomes of western and southern Africa. The extent of different biomes varied with the climate changes of the glacial interglacial cycle. The Mediterranean forest area expanded during interglacials, the northern Saharan desert during glacials, and the semi-desert area in between during the transitions. In the sub-Saharan mountains ericaceous scrubland spread mainly during glacials and the mountainous forest area often increased during intermediate periods. Savannahs extended or shifted to lower latitudes during glacials. While the representation of the tropical rain forest fluctuated with summer insolation and precession, that of the subtropical biomes showed more obliquity variability or followed the pattern of glacial and interglacials. 相似文献
10.
Résumé En mars 1982, le ministère de l'Environnement du Québec a entrepris un échantillonnage physico‐chimique de 64 lacs de tête de la région de Rouyn‐Noranda. Les objectifs de l'étude étaient de déterminer la sensibilité des lacs de cette région et de délimiter l'aire d'influence de la plus importante source anthropique d'émission d'anhydride sulfureux au Québec. Le traitement graphique et statistique des résultats, ainsi que l'application de modèles empiriques d'acidification ont permis de dégager les zones les plus vulnérables à l'acidification. L'application de ces techniques d'analyse a montré, entre autres, que les concentrations de sulfates en lac étaient beaucoup plus élevées à proximité de Rouyn‐Noranda où est située l'usine Mines Noranda Itée. De fait, la concentration de sulfates dans les lacs de cette région passe de 16 mg L?1, aux alentours de Rouyn‐Noranda, à moins de 2 mg L?1 en direction du nord‐est, alors qu'elle baisse à 8 mg L?1 en bordure de la rivière des Outaouais. De plus, en faisant abstraction de la distribution en forme de cloche des concentrations de sulfates autour de Rouyn‐Noranda, l'étude a permis de faire ressortir la décroissance générale des sulfates du sud‐ouest vers le nord‐est. Les points majeurs qui ressortent de cette étude sont la présence de lacs très acides à proximité de Rouyn‐Noranda et V extrême vulnérabilité des plans d'eau situés au sud et sud‐est de la ville. En effet, l'eau des lacs de la région du Témiscamingue est en général moins minéralisée et plus acide que celle des lacs au nord de cette région. Cette distinction est due à la nature géologique des substrats dans les bassins versants. Ainsi, les lacs sensibles à l'acidification sont principalement situés sur des bassins versants associés à des roches granitiques et gneissiques, comparativement aux roches volcaniques et aux dépôts d'argiles lacustres qui caractérisent les lacs aux eaux plus minéralisées. 相似文献