X-ray and ultraviolet observations of the dwarf nova VW Hyi in quiescence

We present an analysis of X-ray and ultraviolet (UV) data of the dwarf nova VW Hyi that were obtained with XMM–Newton during the quiescent state. The X-ray spectrum indicates the presence of an optically thin plasma in the boundary layer that cools as it settles on to the white dwarf. The plasma has a continuous temperature distribution that is well described by a power law or a cooling flow model with a maximum temperature of 6–8 keV. We estimate from the X-ray spectrum a boundary layer luminosity of  8 × 10³⁰ erg s^-1  , which is only 20 per cent of the disc luminosity. The rate of accretion on to the white dwarf is  5 × 10⁻¹² M_⊙ yr⁻¹  , about half of the rate in the disc. From the high-resolution X-ray spectra, we estimate that the X-ray emitting part of the boundary layer is rotating with a velocity of 540 km s⁻¹, which is close to the rotation velocity of the white dwarf but is significantly smaller than the Keplerian velocity. We detect a 60-s quasi-periodic oscillation of the X-ray flux, which is likely to be due to the rotation of the boundary layer. The X-ray and the UV flux show strong variability on a time-scale of ∼1500 s. We find that the variability in the two bands is correlated and that the X-ray fluctuations are delayed by ∼100 s. The correlation indicates that the variable UV flux is emitted near the transition region between the disc and the boundary layer and that accretion rate fluctuations in this region are propagated to the X-ray emitting part of the boundary layer within ∼100 s. An orbital modulation of the X-ray flux suggests that the inner accretion disc is tilted with respect to the orbital plane. The elemental abundances in the boundary layer are close to their solar values.     

Supercritical gas sorption on moist coals

The effect of moisture on the CO₂ and CH₄ sorption capacity of three bituminous coals from Australia and China was investigated at 55 °C and at pressures up to 20 MPa. A gravimetric apparatus was used to measure the gas adsorption isotherms of coal with moisture contents ranging from 0 to about 8%. A modified Dubinin–Radushkevich (DR) adsorption model was found to fit the experimental data under all conditions. Moisture adsorption isotherms of these coals were measured at 21 °C. The Guggenheim–Anderson–de Boer (GAB) model was capable of accurately representing the moisture isotherms over the full range of relative pressures.Moist coal had a significantly lower maximum sorption capacity for both CO₂ and CH₄ than dry coal. However, the extent to which the capacity was reduced was dependent upon the rank of the coal. Higher rank coals were less affected by the presence of moisture than low rank coals. All coals exhibited a certain moisture content beyond which further moisture did not affect the sorption capacity. This limiting moisture content was dependent on the rank of the coal and the sorbate gas and, for these coals, corresponded approximately to the equilibrium moisture content that would be attained by exposing the coal to about 40–80% relative humidity. The experimental results indicate that the loss of sorption capacity by the coal in the presence of water can be simply explained by volumetric displacement of the CO₂ and CH₄ by the water. Below the limiting moisture content, the CO₂ sorption capacity reduced by about 7.3 kg t^− 1 for each 1% increase in moisture. For CH₄, sorption capacity was reduced by about 1.8 kg t^− 1 for each 1% increase in moisture.The heat of sorption calculated from the DR model decreased slightly on addition of moisture. One explanation is that water is preferentially attracted to high energy adsorption sites (that have high energy by virtue of their electrostatic nature), expelling CO₂ and CH₄ molecules.     

Brine-pool deposition for the Zn–Pb–Cu massive sulphide deposits of the Bathurst mining camp, New Brunswick, Canada. II. Ocean anoxia during mineralisation

Current models of massive sulphide ore genesis in the Bathurst mining camp, New Brunswick, involve settling of sulphide particles from a stagnating, low-salinity hydrothermal plume spreading laterally in an anoxic ocean layer with minimal sulphate content. There is fragmentary evidence of ocean anoxia in the form of local fine lamination in the shales that host some of the deposits but the total organic carbon, S, Fe, U/Th, Ni/Co, V/Ni and V/Cr relationships indicate deposition under oxic or dysoxic conditions. Vanadium and Mn values range from oxic to anoxic and sulphate-reducing to non-sulphate reducing but Mn may be anomalously low due to derivation by erosion of acidic volcanic rocks. The somewhat equivocal physical and chemical data, combined with the likely disturbing effects of penecontemporaneous volcanism, considerably weaken the case for an anoxic bottom layer in a static ocean. The presence of barite with ambient seawater ³⁴S values in Brunswick no. 12 ore, and the abundance of sulphate in modern euxinic basin waters, make a sulphate-free layer unlikely, even if anoxic. Sulphate-bearing, low-salinity fluids mixing with seawater would lead to growth of barite-bearing chimneys and baritic rubble mounds, which are not observed. A model involving brine-pool deposition better explains the major features of the Bathurst ores.     

Manganese and iron distributions off central California influenced by upwelling and shelf width

In July 2002, a combination of underway mapping and discrete profiles revealed significant along-shore variability in the concentrations of manganese and iron in the vicinity of Monterey Bay, California. Both metals had lower concentrations in surface waters south of Monterey Bay, where the shelf is about 2.5 km wide, than north of Monterey Bay, where the shelf is about 10 km wide. During non-upwelling conditions over the northern broad shelf, dissolvable iron concentrations measured underway in surface waters reached 3.5 nmol L⁻¹ and dissolved manganese reached 25 nmol L⁻¹. In contrast, during non-upwelling conditions over the southern narrow shelf, dissolvable iron concentrations in surface waters were less than 1 nmol L⁻¹ and dissolved manganese concentrations were less than 5 nmol L⁻¹. A pair of vertical profiles at 1000 m water depth collected during an upwelling event showed dissolved manganese concentrations of 10 decreasing to 2 nmol L⁻¹, and dissolvable iron concentrations of 12–20 nmol L⁻¹ in the upper 100 m in the north, compared to 3.5–2 nmol L⁻¹ Mn and 0.6 nmol L⁻¹ Fe in the upper 100 m in the south, suggesting the effect of shelf width influences the chemistry of waters beyond the shelf.These observations are consistent with current understanding of the mechanism of iron supply to coastal upwelling systems: Iron from shelf sediments, predominantly associated with particles greater than 20 μm, is brought to the surface during upwelling conditions. We hypothesize that manganese oxides are brought to the surface with upwelling and are then reduced to dissolved manganese, perhaps by photoreduction, following a lag after upwelling.Greater phytoplankton biomass, primary productivity, and nutrient drawdown were observed over the broad shelf, consistent with the greater supply of iron. Incubation experiments conducted 20 km offshore in both regions, during a period of wind relaxation, confirm the potential of these sites to become limited by iron. There was no additional growth response when copper, manganese or cobalt was added in addition to iron. The growth response of surface water incubated with bottom sediment (4 nmol L⁻¹ dissolvable Fe) was slightly greater than in control incubations, but less than in the presence of 4 nmol L⁻¹ dissolved iron. This may indicate that dissolvable iron is not as bioavailable as dissolved iron, although the influence of additional inhibitory elements in the sediment cannot be ruled out.     

Factors affecting spatial and temporal variability in material exchange between the Southern Everglades wetlands and Florida Bay (USA)

Physical and biological processes controlling spatial and temporal variations in material concentration and exchange between the Southern Everglades wetlands and Florida Bay were studied for 2.5 years in three of the five major creek systems draining the watershed. Daily total nitrogen (TN), and total phosphorus (TP) fluxes were measured for 2 years in Taylor River, and ten 10-day intensive studies were conducted in this creek to estimate the seasonal flux of dissolved inorganic nitrogen (N), phosphorus (P), total organic carbon (TOC), and suspended matter. Four 10-day studies were conducted simultaneously in Taylor, McCormick, and Trout Creeks to study the spatial variation in concentration and flux. The annual fluxes of TOC, TN, and TP from the Southern Everglades were estimated from regression equations. The Southern Everglades watershed, a 460-km² area that includes Taylor Slough and the area south of the C-111 canal, exported 7.1 g C m⁻², 0.46 g N m⁻², and 0.007 g P m⁻², annually. Everglades P flux is three to four orders of magnitude lower than published flux estimates from wetlands influenced by terrigenous sedimentary inputs. These low P flux values reflect both the inherently low P content of Everglades surface water and the efficiency of Everglades carbonate sediments and biota in conserving and recycling this limiting nutrient. The seasonal variation of freshwater input to the watershed was responsible for major temporal variations in N, P, and C export to Florida Bay; approximately 99% of the export occurred during the rainy season. Wind-driven forcing was most important during the later stages of the dry season when low freshwater head coincided with southerly winds, resulting in a net import of water and materials into the wetlands. We also observed an east to west decrease in TN:TP ratio from 212:1 to 127:1. Major spatial gradients in N:P ratios and nutrient concentration and flux among the creek were consistent with the westward decrease in surface water runoff from the P-limited Everglades and increased advection of relatively P-rich Gulf of Mexico (GOM) waters into Florida Bay. Comparison of measured nutrient flux from Everglades surface water inputs from this study with published estimates of other sources of nutrients to Florida Bay (i.e. atmospheric deposition, anthropogenic inputs from the Florida Keys, advection from the GOM) show that Everglades runoff represents only 2% of N inputs and 0.5% of P input to Florida Bay.     

Pacific subtropical cell variability in coupled climate model simulations of the late 19th–20th century

Observational studies of the Pacific basin since the 1950s have demonstrated that a decrease (increase) in tropical Pacific sea surface temperatures (SSTs) is significantly correlated with a spin-up (slow-down) of the Pacific Subtropical Cells (STCs). STCs are shallow wind-driven overturning circulations that provide a pathway by which extratropical atmospheric variability can impact the equatorial Pacific thermocline and, through upwelling in the eastern equatorial Pacific, tropical Pacific SSTs. Recent studies have shown that this observed relationship between SSTs and STCs is absent in coupled climate model simulations of the late 19th–20th centuries. In this paper we investigate what causes this relationship to breakdown and to what extent this limits the models’ ability to simulate observed climate change in the equatorial Pacific since the late 19th century. To provide insight into these questions we first show that the NCAR Community Climate System Model’s simulation of observed climate change since the 1970s has a robust signal in the equatorial Pacific that bears a close resemblance to observations. Strikingly, absent is a robust signal in the equatorial thermocline. Our results suggest that the coupled model may be reproducing the observed local ocean response to changes in forcing but inadequately reproducing the remote STC-forcing of the tropical Pacific due to the underestimate of extratropical winds that force these ocean circulations. These conclusions are found to be valid in five different coupled climate model simulations of the late 19th–20th centuries (CCSM3, GISS EH, GFDL CM2.1, CSIRO-Mk3, and HadCM3).     

An approach to aid INS using time-differenced GPS carrier phase (TDCP) measurements

This paper presents a simple and effective approach that incorporates single-frequency, L1 time-differenced GPS carrier phase (TDCP) measurements without the need of ambiguity resolution techniques and the complexity to accommodate the delayed-state terms. Static trial results are included to illustrate the stochastic characteristics and effectiveness of the TDCP measurements in controlling position error growth. The formulation of the TDCP observation model is also described in a 17-state tightly-coupled GPS/INS iterative, extended Kalman filter (IEKF) approach. Preliminary land vehicle trial results are also presented to illustrate the effectiveness of the TDCP which provides sub-meter positional accuracies when operating for more than 10 min.