Deriving characteristic parameters of the convective boundary layer from sodar measurements of the vertical velocity variance

This paper deals with the derivation of the convective mixing height and the characteristic convective velocity w _* from profiles of _w measured by sodar. The parameters were obtained by fitting an analytical profile to the observed data. Results were compared with values obtained by the meteorological preprocessor of a dispersion model and from noon radiosoundings. In addition, a Monte Carlo method was applied to study the influence of measurement errors. It turned out that it is inherently difficult to determine the depth of deep mixed layers from sodar measurements with a limited range, although the determination of w _* should be possible. However, a significant underestimation of _w , and thus w _*, was found, which is probably due to disproportional sampling of updrafts and downdrafts.     

A Simplified Analytical Procedure for the Determination of Organically Bound Halogens in Salt‐containing Water Samples

A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established.     

Thermodynamic mixing properties of Mg(Al,Cr)2O4 spinel crystalline solution at high temperatures and pressures

Three Al-Cr exchange isotherms at 1,250°, 1,050°, and 796° between Mg(Al, Cr)₂O₄ spinel and (Al, Cr)₂O₃ corundum crystalline solutions have been studied experimentally at 25 kbar pressure. Starting from gels of suitable bulk compositions, close approach to equilibrium has been demonstrated in each case by time studies. Using the equation of state for (Al, Cr)₂O₃ crystalline solution (Chatterjee et al. 1982a) and assuming that the Mg(Al, Cr)₂O₄ can be treated in terms of the asymmetric Margules relation, the exchange isotherms were solved for Δ G ^*, and . The best constrained data set from the 1,250° C isotherm clearly shows that the latter two quantities do not overlap within three standard deviations, justifying the choice of asymmetric Margules relation for describing the excess mixing properties of Mg(Al, Cr)₂O₄ spinels. Based on these experiments, the following polybaric-polythermal equation of state can be formulated: , P expressed in bars, T in K, G _m ^ex and W _G,i ^Sp in joules/mol. Temperature-dependence of G _m ^ex is best constrained in the range 796–1,250° C; extrapolation beyond that range would have to be done with caution. Such extrapolation to lower temperature shows tentatively that at 1 bar pressure the critical temperature, T _c, of the spinel solvus is 427° C, with dT_c/dP≈1.3 K/kbar. The critical composition, X _c, is 0.42 , and changes barely with pressure. Substantial error in calculated phase diagrams will result if the significant positive deviation from ideality is ignored for Al-Cr mixing in such spinels.     

Isotopic variation in the Tuolumne Intrusive Suite,central Sierra Nevada,California

Granitoid rocks of the compositionally zoned Late Cretaceous Toulumne Intrusive Suite in the central Sierra Nevada, California, have initial⁸⁷Sr/⁸⁶Sr values (Sri) and¹⁴³Nd/¹⁴⁴Nd values (Ndi) that vary from 0.7057 to 0.7067 and from 0.51239 to 0.51211 respectively. The observed variation of both Sri and Ndi and of chemical composition in rocks of the suite cannot be due to crystal fractionation of magma solely under closed system conditons. The largest variation in chemistry, Ndi, and Sri is present in the outer-most equigranular units of the Tuolumne Intrusive Suite. Sri varies positively with SiO₂, Na₂O, K₂O, and Rb concentrations, and negatively with Ndi, Al₂O₃, Fe₂O₃, MgO, FeO, CaO, MnO, P₂O₅, TiO₂, and Sr concentrations. This covariation of Sri, Ndi and chemistry can be modeled by a process of simple mixing of basaltic and granitic magmas having weight percent SiO₂ of 48.0 and 73.3 respectively. Isotopic characteristic of the mafic magma are Sri=0.7047, Ndi=0.51269 and ¹⁸O=6.0, and of the felsic magma are Sri=0.7068, Ndi=0.51212 and ¹⁸O=8.9. The rocks sampled contain from 50 to 80% of the felsic component. An aplite in the outer equigranular unit of the Tuolumne Intrusive Suite apparently was derived by fractional crystallization of plagioclase and hornblende from magma with granudiorite composition that was a product of mixing of the magmas described above. Siliceous magmas derived from the lower crust, having a maximum of 15 percent mantle-derived mafic component, are represented by the inner prophyritic units of the Tuolumne Intrusive Suite.     

Nd isotopic characteristics of S- and I-type granites

The initial Nd and Sr isotopic composition has been determined in S- and I-type granites from the Paleozoic Berridale and Kosciusko Batholiths of southeast Australia. The Nd and Sr isotopic variations form a strongly covariant array with S-types granites having a relatively restricted range inε_Nd values from ?6.1 to ?9.8 but a large range in initial⁸⁷Sr⁸⁶Sr of from 0.7094 to 0.7184. These characteristics are indicative of an～1400-m.y. sedimentary or metasedimentary source for S-types. I-types have variable initial Nd ranging from +0.4 to ?8.9, and a more limited range in initial⁸⁷Sr⁸⁶Sr of from 0.70453 to 0.7119. These isotopic characteristics are consistent with a two-component mixing model whereby a depleted mantle-like component (DMC) withε_Nd = +6 and⁸⁷Sr⁸⁶Sr= 0.703, is mixed with a crustal component (CC) havingε_Nd = ?9 and⁸⁷Sr⁸⁶Sr= 0.720. Although this two-component mixing model satisfies the isotopic constraints the source rock chemistry of the I-types is not compatible with the large proportion (up to 50%) of sedimentary material implied by the isotopic data. This indicates that more than two components are required to account for both the isotopic and chemical data. Both the chemical and isotopic data are consistent with I-type granites having been formed from source rocks of predominantly mantle derivation and obtained progressively from the mantle over a period of 1000 m.y. prior to granite formation.     

Auswirkungen des Ablassens von Hochwasserrückhaltebecken auf deren Limnochemie und Phytoplankton-Biozönose

Reservoirs have to be released when repairing of the dams is necessary. In 1995, two reservoirs in Baden-Württemberg (Germany) of similar age and volume (Lake Herrenbach near Göppingen, 1.0 Mio. m³ and Lake Breitenau near Heilbronn, 2.3 Mio. m³) were emptied. This allowed the singular possibility to investigate the effects of drainage and refilling on the limnochemistry and the phytoplankton biocoenosis of such artificial lakes.Before the drainage of the reservoirs, both lakes showed phosphorus release from the sediment during summer stagnation. Phosphorus values of Lake Herrenbach were regularly higher than those of Lake Breitenau (Lake Herrenbach 88 μg/l, Lake Breitenau 33 μg/l). During release, both lakes indicated higher phosphorus and chlorophyll concentrations as well as rising biomasses. Remarkable differences were observed during refilling of the reservoirs: while Lake Herrenbach showed higher transparency and lower phosphorus concentrations, Lake Breitenau progressed towards eutrophication (total phosphorus during summer 1996: Lake Herrenbach 30 μg/l, Lake Breitenau 55 μg/l). One reason for the reaction of Lake Breitenau was the reduced ground drainage during the refilling, which caused an accumulation of nutrients in the hypolimnion. Another reason was the mineralisation of vegetation which covered great parts of the dry lake sediment. The limnological change of Lake Herrenbach was not as clear but could be caused by the restauration of the pre-reservoir which was drainaged and dredged before the emptying of the main reservoir started as well as many other facts which differed Lake Herrenbach from Lake Breitenau.