Organotemplate silica deposition in Neoproterozoic deep-marine environments: evidence from the Penganga Group, Adilabad, India

Silica in bedded cherts interstratified with manganese carbonates in a deep‐water carbonate ramp succession of the Neoproterozoic Penganga Group, India, displays film‐like, spherical to rod‐shaped, and tubular branching microstructures. The microstructures resemble mineralized extracellular polysaccharides, biofilms and bacterial morphologies. The microstructures suggest silicification by nucleation of silica on organic‐templates or indirectly as sorbed species accumulating on organic templates. Given that similar microstructures have also been documented in Archean cherts it is proposed that organotemplates might have been an important sink for the deposition of silica in Precambrian deep‐water marine environments.     

A time series analysis of sound propagation in a strongly multipathshallow water environment with an adiabatic normal mode approach

Measured time series were generated by small omnidirectional explosive sources in a shallow water area. A bottom-mounted hydrophone recorded sound signals that propagated over a sloping bottom. The time series in the 250-500 Hz band were analyzed with a broad-band adiabatic normal mode approach. The measured waveforms contain numerous bottom interacting multipaths that are complicated by the subbottom structure that contains high-velocity layers near the water-sediment interface. Several of the details of the geoacoustic structure and the depth of the water column at the receiver are inferred from comparisons of the measured data to simulated time series. The sensitivity of broad-band matched-field ambiguity surfaces in the range-depth plane for a single receiver to selected waveguide parameters is examined. A consistent analysis is made where the simulated time series are compared to the measured time series along with the single-receiver matched-field localization solutions for ranges out to 5 km. In this range interval, it was found that the peak cross-correlation between the measured and simulated time series varied between 0.84 and 0.69. The difference between the GPS range and the range obtained from the matched-field solution varied from 0 to 63 m. The geoacoustic structure obtained in the analysis consists of an 8-m low-velocity sediment layer over an 8-m high-velocity layer followed by a higher velocity, infinite half-space     

A global wave parameter database for geophysical applications. Part 1: Wave-current–turbulence interaction parameters for the open ocean based on traditional parameterizations

Ocean surface mixing and drift are influenced by the mixed layer depth, buoyancy fluxes and currents below the mixed layer. Drift and mixing are also functions of the surface Stokes drift U_ss, volume Stokes transport T_S, a wave breaking height scale H_swg, and the flux of energy from waves to ocean turbulence Φ_oc. Here we describe a global database of these parameters, estimated from a well-validated numerical wave model, that uses traditional forms of the wave generation and dissipation parameterizations, and covers the years 2003–2007. Compared to previous studies, the present work has the advantage of being consistent with the known physical processes that regulate the wave field and the air–sea fluxes, and also consistent with a very large number of in situ and satellite observations of wave parameters. Consequently, some of our estimates differ significantly from previous estimates. In particular, we find that the mean global integral of Φ_oc is 68 TW, and the yearly mean value of T_S is typically 10–30% of the Ekman transport, except in well-defined regions where it can reach 60%. We also have refined our previous estimates of U_ss by using a better treatment of the high frequency part of the wave spectrum. In the open ocean, U_ss  0.013U₁₀, where U₁₀ is the wind speed at 10 m height.     

TEM evidence for intracellular accumulation of lead by bacteria in subsurface environments

We monitored near-surface atmospheric fallout (15-cm above ground) and soil solution (at 15, 35 and 55 cm below ground) derived nanoparticles over an 8-month period by collecting the particles directly onto TEM grids in anthropogenically-influenced (vineyard) and pristine (native forest) sites in France. Particle clusters trapped on the grid were selected randomly and individual particles were binned into eight different groups (euhedral clays, weathered clays, salts, oxi-hydroxides, bacteria, non-living organic matter, aggregates and undetermined). Bacteria represent 9–23% of the collected nanoparticle area (ave. 9.4% and 18% for two atmospheric collection sites and ave. 23% for soil infiltration samples). Bacteria were most often associated with non-living organic matter and comprised a variety of morpho-types. Interestingly, 45% of all the bacteria analyzed by transmission electron microscopy and electron dispersive spectroscopy (TEM-EDX) showed the presence of intracellular grains significantly enriched in lead and phosphorus. Intracellular sequestration of Pb into polyphosphate bodies has been observed in the laboratory, but this is the first observation of this phenomenon in a natural environment. Furthermore, this suggests that microbial-bound Pb may be an important transport mechanism in subsurface environments.     

Anthropogenic influence on trace element geochemistry of healing mud (peloid) from Makirina Cove (Croatia)

Due to their balneotherapeutic features, the organic-rich sediments in Makirina Cove are an important source of healing mud. An environmental geochemistry approach using normalization techniques was applied to evaluate the anthropogenic contribution of trace metals to sediments used as healing mud. Sediment geochemistry was found to be associated with land-use change and storm events, as well as with proximity of a road with heavy traffic in the summer months. Local valley topography preferentially channels lithogenic and pollutant transport to the cove. Concentrations and distribution of trace metals indicate lithogenic (Ni, Cr, Co) and anthropogenic (Pb, Cu, Zn and Se) contributions to the sediments. The calculation of enrichment factors indicates a moderate (EFs between 2–3.5) input of anthropogenic Cu and Pb in surficial sediments to a depth of 10 cm. Patients using the Makirina Cove sediments as healing mud could be to some extent exposed to enhanced uptake of metals from anthropogenic sources via dermal contact.     

Formation of Zn–Ca phyllomanganate nanoparticles in grass roots

It is now well established that a number of terrestrial and aquatic microorganisms have the capacity to oxidize and precipitate Mn as phyllomanganate. However, this biomineralization has never been shown to occur in plant tissues, nor has the structure of a natural Mn(IV) biooxide been characterized in detail. We show that the graminaceous plant Festuca rubra (red fescue) produces a Zn-rich phyllomanganate with constant Zn:Mn and Ca:Mn atomic ratios (0.46 and 0.38, respectively) when grown on a contaminated sediment. This new phase is so far the Zn-richest manganate known to form in nature (chalcophanite has a Zn:Mn ratio of 0.33) and has no synthetic equivalent. Visual examination of root fragments under a microscope shows black precipitates about ten to several tens of microns in size, and their imaging with backscattered and secondary electrons demonstrates that they are located in the root epidermis. In situ measurements by Mn and Zn K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray diffraction (XRD) with a micro-focused beam can be quantitatively described by a single-phase model consisting of Mn(IV) octahedral layers with 22% vacant sites capped with tetrahedral and octahedral Zn in proportions of 3:1. The layer charge deficit is also partly balanced by interlayer Mn and Ca. Diffracting crystallites have a domain radius of 33 Å in the ab plane and contain only 1.2 layers (8.6 Å) on average. Since this biogenic Mn oxide consists mostly of isolated layers, basal 00l reflections are essentially absent despite its lamellar structure. Individual Mn layers are probably held together in the Mn–Zn precipitates by stabilizing organic molecules. Zinc biomineralization by plants likely is a defense mechanism against toxicity induced by excess concentrations of this metal in the rhizosphere.     

Participation in payments for ecosystem services: Case studies from the Lacandon rainforest, Mexico

Understanding people’s willingness to participate in projects and programmes of payments for ecosystem services (PES) has not been a key analytical concern of the scholarly literature around this new field of environmental policy and practice. This paper analyses participation in four communities benefiting from payments for biodiversity and carbon fixation in Mexico, and contrasts the results for each case with neighbouring communities that do not receive payments. We take a holistic approach that accounts for procedural rules, actors’ interactions, institutions and values, and individuals’ characteristics. We show that the nature of PES rules and the effectiveness of communication with government officers and NGOs influence resource managers’ ability and willingness to participate. We highlight community size, resource managers’ ability to diversify livelihood activities and local perspectives on the conservation of common forests, particularly sacred values and intergenerational concerns on forest conservation, as critical participation drivers. This analysis provides insights on why and how these new institutions may be attractive for some resource managers and permits to draw some recommendations for the future design of PES projects and programmes.     

Leaching of lead metallurgical slags and pollutant mobility far from equilibrium conditions

Lead metallurgical slags are partially vitrified materials containing residual amounts of Zn, Pb, Cr, Cd and As. These hazardous materials are generally buried on heaps exposed to weathering. In this study, leaching behavior of lead blast furnace slags has been tested using pure water and open flow experiments. It appears that in such far from equilibrium and slightly acidic conditions, the main phase to be altered is the vitreous phase. As for lunar, basaltic and nuclear glasses, alkalis/proton exchanges prevail and lead to the formation of a non-protective altered layer enriched in Si, Fe and Al. The composition of the altered layer is quite constant except for Si whose concentration decreases towards the leachate interface. Owing to their sizes, micrometric Pb droplets are not always totally dissolved at the slag surface. Nevertheless, nanometric Pb droplets are instantaneously dissolved while a surrounding altered layer is formed. This leads to high Pb releases in open flow systems. Leachate chemistry and dissolution rates of the vitreous phase are closely comparable to previous leaching tests with basaltic and nuclear glasses in conditions far from equilibrium. Moreover, this study confirms that Fe is a stable element in such conditions.     

Interstitial water chemistry of villefranche bay sediments: Trace metal diagenesis

Pore water aliquots were taken with an in situ close interval sampler: the “Peeper”.We report here the pore water concentration profiles of TCO₂, SO₄, TH₂S, Ca and the trace metals Mn, Cu, Pb, Cd and Cr from sediments of a relatively polluted area, the Villefranche Bay, on the French Riviera (close to Nice).We investigated the major ion concentrations in order to establish geochemical mass balances of organic matter oxidation. ΔTCO₂/ΔSO₄ was <−2.0, reflecting the precipitation of calcite as confirmed by the calcium profile. Reduction of sulfate led to increasing sulfide concentrations with depth.Trace metal interstitial water concentrations decreased from 63 to 5 nM, 18 to 4 nM and 6.6 to less than 2 nM for Cu, Pb and Cr, respectively. Cd showed a different pattern with top and deep values of 0.7 nM and a minimum of 0.27 nM.Thermodynamic calculations were performed which suggest the potential formation of mineral phases such as sulfides.