Fluid and source magma evolution of the Questa porphyry Mo deposit,New Mexico,USA

Combined fluid inclusion microthermometry and microanalysis by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) are used to constrain the hydrothermal processes forming a typical Climax-type porphyry Mo deposit. Molybdenum mineralisation at Questa occurred in two superimposed hydrothermal stages, a magmatic-hydrothermal breccia and later stockwork veining. In both stages, texturally earliest fluids were single-phase, of low salinity (~7 wt.% NaCl_equiv.) and intermediate-density. Upon decompression to ~300 bar, they boiled off a vapour phase, leaving behind a residual brine (up to 45 wt.% NaCl_equiv) at temperatures of ~420°C. The highest average Mo concentrations in this hot brine were ~500 μg/g, exceeding the Mo content of the intermediate-density input fluid by about an order of magnitude and reflecting pre-concentration of Mo by fluid phase separation prior to MoS₂ deposition from the brine. Molybdenum concentrations in brine inclusions, then, decrease down to 5 μg/g, recording Mo precipitation in response to cooling of the saline liquid to ~360°C. Molybdenite precipitation from a dense, residual and probably sulphide-depleted brine is proposed to explain the tabular shape of the ore body and the absence of Cu-Fe sulphides in contrast to the more common Cu-Mo deposits related to porphyry stocks. Cesium and Rb concentrations in the single-phase fluids of the breccia range from 2 to 8 and from 40 to 65 μg/g, respectively. In the stockwork veins, Cs and Rb concentrations are significantly higher (45–90 and 110–230 μg/g, respectively). Because Cs and Rb are incompatible and hydrothermally non-reactive elements, the systematic increase in their concentration requires two distinct pulses of fluid exsolution from a progressively more fractionated magma. By contrast, major element and ore metal concentrations of these two fluid pulses remain essentially constant. Mass balance calculations using fluid chemical data from LA-ICPMS suggest that at least 25 km³ of melt and 7 Gt of deep input fluid were necessary to provide the amount of Mo contained in the stockwork vein stage alone. While the absolute amounts of fluid and melt are uncertain, the well-constrained element ratios in the fluids together with empirical fluid/melt partition coefficients derived from the inclusion analyses suggest a high water content of the source melt of ~10%. In line with other circumstantial evidence, these results suggest that initial fluid exsolution may have occurred at a confining pressure exceeding 5 kbar. The source of the molybdenum-mineralising fluids probably was a particularly large magma chamber that crystallised and fractionated in the lower crust or at mid-crustal level, well below the shallow intrusions immediately underlying Questa and other porphyry molybdenum deposits. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

The Impact of Land-Surface Parameter Properties and Resolution on the Simulated Cloud-Topped Atmospheric Boundary Layer

A method to simulate characteristics of wind speed in the boundary layer of tropical cyclones in an idealized manner is developed and evaluated. The method can be used in a single-column modelling set-up with a planetary boundary-layer parametrization, or within large-eddy simulations (LES). The key step is to include terms in the horizontal velocity equations representing advection and centrifugal acceleration in tropical cyclones that occurs on scales larger than the domain size. Compared to other recently developed methods, which require two input parameters (a reference wind speed, and radius from the centre of a tropical cyclone) this new method also requires a third input parameter: the radial gradient of reference wind speed. With the new method, simulated wind profiles are similar to composite profiles from dropsonde observations; in contrast, a classic Ekman-type method tends to overpredict inflow-layer depth and magnitude, and two recently developed methods for tropical cyclone environments tend to overpredict near-surface wind speed. When used in LES, the new technique produces vertical profiles of total turbulent stress and estimated eddy viscosity that are similar to values determined from low-level aircraft flights in tropical cyclones. Temporal spectra from LES produce an inertial subrange for frequencies \(\gtrsim \)0.1 Hz, but only when the horizontal grid spacing \(\lesssim \)20 m.     

The Basic Formal Ontology as a Reference Framework for Modeling the Evolution of Administrative Units

In information systems, ontologies promise advantages such as enhanced interoperability, knowledge sharing, and integration of data sources. In this article, we show that the upper ontology Basic Formal Ontology can facilitate the modeling of an evolution of administrative units. This is demonstrated by creating a spatiotemporal ontology for the administrative units of Switzerland. The ontology tackles the problem that the geometric data is typically captured by taking snapshots at regular intervals while the thematic data is continually updated. The ontology presented merges time‐stamped geometries with a formally described history of administrative units, allowing for complex spatiotemporal queries neither standard approach would support. The resulting populated knowledge base was evaluated against a set of spatiotemporal test queries. The evaluation showed that this knowledge base supports a wide range of queries on the evolution of the administrative units of Switzerland between 1960 and 2010.     

Experimental and numerical investigations on CO2 injection and enhanced gas recovery effects in Altmark gas field (Central Germany)

The feasibility of CO₂ storage and enhanced gas recovery (EGR) effects in the mature Altmark natural gas field in Central Germany has been studied in this paper. The investigations were comprehensive and comprise the characterization of the litho- and diagenetic facies, mineral content, geochemical composition, the petrophysical properties of the reservoir rocks with respect to their potential reactivity to CO₂ as well as reservoir simulation studies to evaluate the CO₂ wellbore injectivity and displacement efficiency of the residual gas by the injected CO₂. The Rotliegend sediments of the Altmark pilot injection area exhibit distinct mineralogical, geochemical, and petrophysical features related to litho- and diagenetic facies types. The reservoir rock reactivity to CO₂ has been studied in autoclave experiments and associated effects on two-phase transport properties have been examined by means of routine and special core analysis before and after the laboratory runs. Dissolution of calcite and anhydrite during the short-term treatments leading to the enhancements of permeability and porosity as well as stabilization of the water saturation relevant for CO₂ injection have been observed. Numerical simulation of the injection process and EGR effects in a sector of the Altmark field coupled with a wellbore model revealed the possibility of injecting the CO₂ gas at temperatures as low as 10 °C and pressures around 40 bar achieving effective inflow in the reservoir without phase transition in the wellbore. The small ratio of injected CO₂ volume versus reservoir volume indicated no significant EGR effects. However, the retention and storage capacity of CO₂ will be maximized. The migration/extension of CO₂ varies as a function of heterogeneity both in the layers and in the reservoir. The investigation of CO₂ extension and pressure propagation suggested no breakthrough of CO₂ at the prospective production well during the 3-year injection period studied.     

The impact of diagenetic fluid–rock reactions on Rotliegend sandstone composition and petrophysical properties (Altmark area, central Germany)

In the framework of the German R&D joint project CLEAN (CO₂ large-scale enhanced gas recovery in the Altmark natural gas field), Rotliegend reservoir sandstones of the Altensalzwedel block in the Altmark area (Saxony-Anhalt, central Germany) have been studied to characterise litho- and diagenetic facies, mineral content, geochemical composition, and petrophysical properties. These sands have been deposited in a playa environment dominated by aeolian dunes, dry to wet sand flats and fluvial channel fills. The sediments exhibit distinct mineralogical, geochemical, and petrophysical features related to litho- and diagenetic facies types. In sandstones of the damp to wet sandflats, their pristine red colours are preserved and porosity and permeability are only low. Rocks of the aeolian environment and most of the channel fill deposits are preferentially bleached and exhibit moderate to high porosity and permeability. Although geochemical element whole rock content in these rocks is very similar, element correlations are different. Variations in porosity and permeability are mainly due to calcite and anhydrite dissolution and differences in clay coatings with Fe-bearing illitic-chloritic composition exposed to the pore space. Moreover, mineral dissolution patterns as well as compositions (of clays and carbonate) and morphotypes of authigenic minerals (chlorite, illite) are different in red and bleached rocks. Comparison of the geochemical composition and mineralogical features of diagenetically altered sandstones and samples exposed to CO₂-bearing fluids in laboratory batch experiments exhibit similar character. Experiments prove an increase in wettability and water binding capacity during CO₂ impact.     

The inversion of accurate data on the extinction coefficient by the transparency method

Summary The problem of the particle distribution restoration by the dependence of the extinction coefficient computed from exactMie formulae (when the absorption is absent) on wave length is considered. The transparency method is used. As an example the inversion of the polydisperse extinction coefficient for two models with the normal logarithmic distribution has been made. The agreement is quite satisfactory.     

Ein selbstkompensierender Elektrometerröhrenverstärker zur Registrierung des luftelektrischen Potentialgefälles

Zusammenfassung Es wird ein selbstkompensierender Elektrometerröhrenverstärker zur Registrierung des luftelektrischen Potentialgefälles beschrieben. Das Gerät hat einen hohen, über den ganzen Meßbereich konstanten Eingangswiderstand von 10¹⁴ Ohm und eine lineare Anzeige über einen beliebig wählbaren Meßbereich, z. B. von –200 bis + 300 Volt.

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Summary A self-compensating electrometer-tube amplifier for recording the electric field of the atmosphere is described. The instrument has a high input resistance of 10¹⁴ ohms constant over the whole range and a linear indication covering any range desired, as e. g. from –200 to +300 volts.

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Résumé On décrit un amplificateur autocompensateur à lampe électromètre pour l'enregistrement du champ électrique de l'atmosphère. L'apparen possède une forte résistance d'entrée de 10¹⁴ ohms, constante pour toute l'échelle de mesure, et une indication linéaire valable pour n'importe quelle échelle, par exemple de –200 à +300 volts.

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Compositions of magmatic hydrothermal fluids determined by LA-ICP-MS of fluid inclusions from the porphyry copper–molybdenum deposit at Butte, MT

We analyzed 85 fluid inclusions from seven samples from the porphyry Cu–Mo deposit in Butte, MT, using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). The Butte deposit formed at unusually great depth relative to most porphyry deposits, and fluid inclusions in deep veins trapped a low-salinity, CO₂-bearing, magmatically derived, supercritical fluid as a single aqueous phase. This fluid is interpreted to be the parent fluid that cooled, decompressed, unmixed, and reacted with wall rock to form the gigantic porphyry Cu deposit at Butte. Few previous analyses of such fluids exist.Low-salinity, aqueous fluids from the earliest veins at Butte are trapped in deep veins with biotite-rich alteration envelopes (EDM veins). These veins, and the Butte quartz monzonite surrounding them, host much of the Butte porphyry Cu mineralization. Twenty fluid inclusions in one EDM quartz vein are dominated by Na, K, Fe (from 0.1 to 1 wt.%) and contain up to 1.3 wt.% Cu. These inclusions contain only small amounts (tens of ppm) of Pb, Zn, and Mn, and typically contain Li, B, Ca, As, Mo, Ag, Sn, Sb, Ba, and W in less than detectable quantities. The abundance of Cu in early fluids indicates that a low-salinity, Cu-rich, aqueous ore fluid can be directly produced by aqueous fluid separation from a granitic magma. Similar inclusions (eight) in an early deep quartz–molybdenite vein with a K-feldspar selvage have similar compositions but contain significantly less Cu than most inclusions in the biotite-altered vein. Analyzed inclusions in both veins contain less than detectable concentrations of Mo even though one is molybdenite-bearing.Low-salinity, CO₂-bearing aqueous fluids are also trapped in pyrite–quartz veins with sericitic selvages. These veins cut both of the above vein types and contain inclusions that were trapped at lower pressure and temperature. Thirty-nine inclusions in two such veins have compositions similar to early fluids, but are enriched by up to a factor of 10 in Mn, Pb, and Zn relative to early fluids, and are slightly depleted in Fe. Many of these inclusions contain as much or more Cu than early fluids, although little chalcopyrite is found in or around pyrite–quartz veins.Eighteen halite-bearing inclusions from three veins from both chalcopyrite-bearing and barren veins with both K-silicate and sericitic selvages were analyzed as well. Halite-saturated inclusions are dominated by Na, K, Fe, and in some inclusions Ca. Whereas these inclusions are significantly enriched in Ca, Mn, Fe, Zn, and Pb, fluids in all three veins contain significantly less Cu than early, high temperature, low-salinity inclusions.Analyses of all inclusion types show that whereas bulk-salinity of the hydrothermal fluid must be largely controlled by the magma, fluid–rock interactions have a significant role in controlling fluid compositions and metal ratios. Cu concentrations range over an order of magnitude, more than any other element, in all four samples containing low-salinity inclusions. We infer that variations are the result of fluid trapping after different amounts of fluid–rock reaction and chalcopyrite precipitation. Enrichment, relative to early fluids, of Mn, Pb, and Zn in fluids related to sericitic alteration is also likely the result of fluid–rock reaction, whereby these elements are released from biotite and feldspars as they alter to sericite. In halite-bearing inclusions, concentrations of Sr, Ca, Pb, and Ba are elevated in inclusions from the pyrite–quartz vein with sericitic alteration relative to halite-bearing inclusions from unaltered and potassically altered samples. Such enrichment is likely caused by the breakdown of plagioclase and K-feldspar in the alteration envelope, releasing Sr, Ca, Pb, and Ba.     

Comparison of satellite and air photo based landslide susceptibility maps

Landslide susceptibility maps can be prepared in a variety of ways. Many geoscientists favour the use of an overlay model approach in which several map layers are combined by some arithmetic rules to determine the potential for sliding in an area or region. The resulting susceptibility maps, although based on a subjective weighting of relevant factors, can often be of high accuracy and utility. In order to obtain the relevant input data for this type of analysis, remotely sensed data are often used. To date, susceptibility mapping, just as the mapping of historic and individual landslides, has tended to require higher-resolution imagery. This has somewhat limited the application of landslide susceptibility mapping. While high-resolution air photo or satellite imagery is superior to lower resolution imagery for the purpose of mapping of historic and individual landslides, such higher levels of resolution may not be required for the development of landslide susceptibility maps. In order to determine if medium-resolution satellite imagery, such as SPOT or ASTER, could provide the needed data for landslide susceptibility mapping, a comparison was undertaken of landslide susceptibility model output resulting from the use of stereo NAPP aerial photography versus the use of data obtained from stereo SPOT imagery. The test area selected for this study consisted of two watersheds, Pena Canyon and Big Rock Canyon, situated west of Santa Monica, California, USA, along the Pacific Coast Highway. Both watersheds have a long and well-documented history of landslide activity and sufficient geologic variability and complexity to provide a good test site. The specific overlay model used in this evaluation required input data consistent with the needs of many other models of this type. The model output derived from the two different data sources and presented here in the form of susceptibility maps were virtually identical. Statistical and difference analysis confirmed that both methods of obtaining input data provide similar results and successfully identified landslide prone areas. These results suggest that satellite imagery, in this instance, SPOT images, could potentially be used in lieu of conventional air photos, to evaluate landslide susceptibility. In many situations, especially in the case of remote locations and/or developing countries, this capability should result in substantial savings in terms of time, financial resources, and overall viability.