Isotopic composition of nitrate in five German rivers discharging into the North Sea

We determined concentrations and isotopic composition of nitrate in five German rivers (Rhine, Elbe, Weser, Ems, and Eider) that discharge into the North Sea. Samples were obtained on a biweekly to monthly basis and chemical and isotopic analyses were conducted for the period January 2006 to March 2007 at sampling stations situated before estuarine mixing with North Sea water. We observed maximum nitrate loads in winter and fall, when both discharge and concentration of nitrate are highest. Mean annual isotope values in nitrate ranged from 8.2‰ to 11.3‰ for and 0.4‰ to 2.2‰ for . The ranges of isotope values suggest that nitrate in these rivers derives from soil nitrification, sewage, and/or manure. These and published data on other rivers in northern Europe and northern America reveal a correlation between agricultural land use (>60% in the catchment areas of rivers examined) and values. The rivers Rhine, Elbe, Weser and Ems show similar seasonal patterns of the isotopic fractionation of nitrate with increasing values and simultaneously decreasing concentrations during summer months, indicating that assimilation of nitrate is the main fractionation process of riverine nitrate. Isotopic signals in winter are more depleted than the mean summer isotope values, attributed to less microbial activity and assimilative processes. Load weighted nitrate δ¹⁵N of the riverine input to the German Bight Coastal Water mass before estuarine mixing and processing is between 8‰ and 12‰. The high δ¹⁵N value of river nitrate is matched by high δ¹⁵N of nitrate in surface sediments in the German Bight.     

Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.     

The International GNSS Service in a changing landscape of Global Navigation Satellite Systems

The International GNSS Service (IGS) is an international activity involving more than 200 participating organisations in over 80 countries with a track record of one and a half decades of successful operations. The IGS is a service of the International Association of Geodesy (IAG). It primarily supports scientific research based on highly precise and accurate Earth observations using the technologies of Global Navigation Satellite Systems (GNSS), primarily the US Global Positioning System (GPS). The mission of the IGS is “to provide the highest-quality GNSS data and products in support of the terrestrial reference frame, Earth rotation, Earth observation and research, positioning, navigation and timing and other applications that benefit society”. The IGS will continue to support the IAG’s initiative to coordinate cross-technique global geodesy for the next decade, via the development of the Global Geodetic Observing System (GGOS), which focuses on the needs of global geodesy at the mm-level. IGS activities are fundamental to scientific disciplines related to climate, weather, sea level change, and space weather. The IGS also supports many other applications, including precise navigation, machine automation, and surveying and mapping. This article discusses the IGS Strategic Plan and future directions of the globally-coordinated ~400 station IGS network, tracking data and information products, and outlines the scope of a few of its numerous working groups and pilot projects as the world anticipates a truly multi-system GNSS in the coming decade.     

The 13th and 14th Workshops on Antarctic Meteorology and Climate

1.Overview In July 2018,the Antarctic community came together to meet at the 13th Workshop on Antarctic Meteorology and Climate(WAMC)in Madison,Wisconsin,USA(Fig.1);and in the following year in June 2019,the 14th WAMC was held in Charleston,South Carolina,USA(Fig.2).With a growing history,the WAMC addresses the topics of Antarctic meteorology and climate(Kameda et al.,2008;Colwell et al.,2016;Lazzara et al.,2018)as well as weather-related issues of scientific and operational support.The workshops bring together researchers,operational forecasters,numerical modelers,observational specialists,and students.The themes of both workshops included Antarctic meteorological observations,Antarctic atmospheric numerical modeling,Antarctic meteorological and climate research,and Antarctic weather forecasting and operational services.The 2018 and 2019 WAMC were both followed by a one-day focus on the Year of Polar Prediction-Southern Hemisphere(YOPP-SH),when preparations and follow-up discussions were made with regard to the YOPP Special Observing Period from 16 November 2018 to 15 February 2019.     

The 16th Workshop on Antarctic Meteorology and Climate and 6th Year of Polar Prediction in the Southern Hemisphere Meeting

1. Overview In June 2021, the 16th Workshop on Antarctic Meteorology and Climate (WAMC) and the 6th Year of Polar Prediction in the Southern Hemisphere (YOPP-SH) Meeting (http://polarmet.osu.edu/WAMC;021/) were held online and hosted by the Polar Meteorology Group at Byrd Polar and Climate Research Center, The Ohio State University, Columbus,Ohio (Fig. 1).     

Future emissions of marine halogenated very-short lived substances under climate change

Halogenated Very Short-lived Substances (VSLS), such as bromoform, dibromomethane and methyl iodide, are naturally produced in the oceans and are involved in ozone depletion in the troposphere and the stratosphere. The effect of climate change on the oceanic emissions of these compounds is not well quantified. Based on present-day observed global oceanic and atmospheric concentrations, and historic and future data from three CMIP5 models, past and future sea-to-air fluxes of these VSLS are calculated. The simulations are used to infer possible effects of projected changes of physical forcing on emissions in different oceanic regimes. CMIP5 model output for 1979–2100 from the historical scenario and the RCP scenarios 2.6 and 8.5 are used as input data for the emission calculations. Of the parameters that have the main influence on the sea-to-air fluxes, the global sea surface temperatures show a steady increase during the twenty-first century, while the projected changes of sea surface wind speed is very small. The calculated emissions based on the historical CMIP5 model runs (1979–2005) increased over the 26 year period and agree well with the emissions based on ERA-Interim data. The future sea-to-air fluxes of VSLS generally increase during the twenty-first century under the assumption of constant concentration fields in the ocean and atmosphere. The multi-model mean global emissions of bromoform increase by 29.4% (9.0%) between 1986 and 2005 and 2081–2100 under RCP 8.5 (2.6) and dibromomethane and methyl iodide emissions increase by 23.3% (6.4%) and 5.5% (1.5%), respectively. Uncertainties of the future emission estimates, driven by ongoing environmental changes such as changing oceanic productivity (not considered in this study) are discussed.     

TG/plus—a pyrolysis method for following maturation of oil and gas generation zones using Tmax of methane

Thermogravimetric Fourier transform infrared spectroscopy (TG-FTIR) analyses were carried out on two sets of isolated kerogens covering a wide maturity range from low mature (0.46% R_o) through the end of oil and gas generation (maximum R_{o = 5.32%}). Data onweight percent and T_max for evolution of methane, volatile tars, ethylene, SO₂, NH₃, CO₂, and CO are reported. The T_max of methane shows the most consistent response to increasing maturation in both sets of samples. Results are comparable to those of whole rocks from an Alaskan North Slope well analyzed previously. The collective data for both whole rocks and isolated kerogens shows a generally linear correlation between %R_o and T_max of methane, with the exception of R_o of about 2.0% where a dip in the curve occurs. The slope of the correlation line was steeper for the predominantly terrigenous Wilcox kerogen than for more marine Colorado kerogen or for the Alaskan North Slope whole rock samples, probably reflecting differences in the chemical nature of various kerogen sets, which is also reflected by differences in the shapes of the pyrolysis curves of SO₂, CO₂, CO, H₂O, and ethylene. These preliminary data indicate that T_max of methane is a good maturation indicator for whole rocks and isolated kerogens up to an R_o of about 4%, which includes all of the wet gas and a considerable portion of the dry gas generation zones. This correlation was also observed for samples containing migrated bitumen, where it was not possible to obtain a reliable T_max for the volatile tar (S2) peak. The more terrigenous Wilcox kerogens also showed a good correlation of the T_max of ethylene with %R_o. T_max of ammonia evolution did not correlate with maturity and occurred 100–200°C lower than previously found for whole rocks, consistent with a whole-rock source of pyrolytic ammonia for Alaskan whole rock samples. HI and OI indices were calculated in several ways and plotted to reflect kerogen type as well as both the residual oil and gas generation potential. The ratio of pyrolyzable to combustible sulfur (evolved as SO₂) was independent of maturity and showed a clear difference between the more terrigenous Wilcox kerogens and the more marine Colorado kerogens.