Distributions of dissolved and particulate biogenic thiols in the subartic Pacific Ocean

Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.     

Interpreting tracer breakthrough tailing in a conduit-dominated karstic aquifer

Breakthrough tailing has been observed during dye-tracing recovery tests in the Norville aquifer system (chalk), France. Karst-conduit flow and transport parameters were assessed using two different interpretative methods: the linear graphical method and the Chatwin method (implemented in the Qtracer2 program). The linear graphical method was used to model the observed tailing effects, which was explained by a second smaller delayed breakthrough curve. By comparing the results of tracer-test interpretation for the two methods, it was possible to relate the area of this second curve to the importance of turbulent flow in spring discharge. The more turbulent the flow, the less important the contribution of the second breakthrough curve and the tailing effect. The observed tailing could possibly be controlled by hydrodynamics to a greater extent than usually expected, the tailing effects being mostly attributed to diffusion phenomena. Tailing effects were expected to increase with discharge and the piezometric level, which would have resulted in overpressure in conduits, fissure flooding, etc. Instead, breakthrough tailing tended to disappear with increasing aquifer discharge, which would support the hypothesis of there being mostly hydrodynamic-controlled tailing effects instead of matrix- or fissure-diffusion.An erratum to this article can be found at     

Experimental characterization of the impact of temperature and humidity on the breakdown of soil water repellency in sandy soils and composts

Soil water repellency is a widespread phenomenon with the capacity to alter hydrological and geomorphological processes. Water repellency decays with time, and the consequences are only of concern during the timescale at which the water repellency persists. This study aimed to characterize the influence of temperature and humidity on the breakdown of water repellency. Apparent contact angle measurements were carried out on samples consisting of sand treated with stearic acid as well as naturally repellent dune sands and composts. Temperature and humidity were controlled using a cooled incubator and a purpose designed enclosed box in which humidity could be raised or lowered. Results showed the contact angle of the stearic‐acid‐treated sands decayed with time and that there was a significant increase with stearic acid concentration. For all samples, the decay in apparent contact angle could be described with a continuous breakdown model. The stearic‐acid‐treated sands showed a significant increase in contact angle with relative humidity at a temperature of 10 and 20 °C. These differences diminished with increasing temperature. Similar results were seen for the dune sands and composts. Despite the influence of temperature and humidity on contact angles, there was no significant change in the rate at which the contact angle decayed in any sample. Absolute humidity was found to provide a more relevant indicator than relative humidity when assessing the influence of humidity on repellency over a range of temperatures. The contact angle initially increased with absolute humidity before plateauing owing to the confounding effect of temperature. Copyright © 2014 John Wiley & Sons, Ltd.     

Lateral extrusion along the Altyn Tagh Fault,Qilian Shan (NE Tibet): insight from a 3D crustal budget

The lithospheric strike‐slip Altyn Tagh Fault has accommodated hundreds of kilometres of displacement between the Qaidam and Tarim blocks since its Eocene reactivation. However, the way the deformation is accommodated in the Qilian Shan and further east remains uncertain. Based on 360 km of north‐eastward migration of the relatively rigid Qaidam block along the Altyn Tagh Fault and 3D isovolumetric balancing of the crustal deformation within the Altyn Tagh Fault–Qilian Shan system, we demonstrate that 250 ± 28 km (43.8–49.4%) of N20E directed crustal shortening and an additional ~250–370 km of eastward motion of the Qilian Shan crust must be accounted for by strike‐slip faulting in the Qilian Shan and crustal thickening in the Qinling area, as well as by extension in the adjoining North China block graben systems.     

Orbital scale vegetation change in Africa

Palynological records of Middle and Late Pleistocene marine sediments off African shores is reviewed in order to reveal long-term patterns of vegetation change during climate cycles. Whether the transport of pollen and spores from the source areas on the continent to the ocean floor is mainly by wind or predominantly by rivers depends on the region. Despite the differences in transportation, accumulation rates in the marine sediments decline exponentially with distance to the shore. The marine sediments provide well-dated records presenting the vegetation history of the main biomes of western and southern Africa. The extent of different biomes varied with the climate changes of the glacial interglacial cycle. The Mediterranean forest area expanded during interglacials, the northern Saharan desert during glacials, and the semi-desert area in between during the transitions. In the sub-Saharan mountains ericaceous scrubland spread mainly during glacials and the mountainous forest area often increased during intermediate periods. Savannahs extended or shifted to lower latitudes during glacials. While the representation of the tropical rain forest fluctuated with summer insolation and precession, that of the subtropical biomes showed more obliquity variability or followed the pattern of glacial and interglacials.     

Influence des rejets atmosphériques d'anhydride sulfureux sur la qualité de l'eau des lacs de la région de Rouyn‐Noranda*

Résumé

En mars 1982, le ministère de l'Environnement du Québec a entrepris un échantillonnage physico‐chimique de 64 lacs de tête de la région de Rouyn‐Noranda. Les objectifs de l'étude étaient de déterminer la sensibilité des lacs de cette région et de délimiter l'aire d'influence de la plus importante source anthropique d'émission d'anhydride sulfureux au Québec.

Le traitement graphique et statistique des résultats, ainsi que l'application de modèles empiriques d'acidification ont permis de dégager les zones les plus vulnérables à l'acidification. L'application de ces techniques d'analyse a montré, entre autres, que les concentrations de sulfates en lac étaient beaucoup plus élevées à proximité de Rouyn‐Noranda où est située l'usine Mines Noranda Itée. De fait, la concentration de sulfates dans les lacs de cette région passe de 16 mg L^?1, aux alentours de Rouyn‐Noranda, à moins de 2 mg L^?1 en direction du nord‐est, alors qu'elle baisse à 8 mg L^?1 en bordure de la rivière des Outaouais. De plus, en faisant abstraction de la distribution en forme de cloche des concentrations de sulfates autour de Rouyn‐Noranda, l'étude a permis de faire ressortir la décroissance générale des sulfates du sud‐ouest vers le nord‐est.

Les points majeurs qui ressortent de cette étude sont la présence de lacs très acides à proximité de Rouyn‐Noranda et V extrême vulnérabilité des plans d'eau situés au sud et sud‐est de la ville. En effet, l'eau des lacs de la région du Témiscamingue est en général moins minéralisée et plus acide que celle des lacs au nord de cette région. Cette distinction est due à la nature géologique des substrats dans les bassins versants. Ainsi, les lacs sensibles à l'acidification sont principalement situés sur des bassins versants associés à des roches granitiques et gneissiques, comparativement aux roches volcaniques et aux dépôts d'argiles lacustres qui caractérisent les lacs aux eaux plus minéralisées.     

What meta-analysis can tell us about vulnerability of marine biodiversity to ocean acidification?

Ocean acidification has been proposed as a major threat for marine biodiversity. Hendriks et al. [Hendriks, I.E., Duarte, C.M., Alvarez, M., 2010. Vulnerability of marine biodiversity to ocean acidification: a meta-analysis. Estuarine, Coastal and Shelf Science, doi:10.1016/j.ecss.2009.11.022.] proposed an alternative view and suggested, based on a meta-analysis, that marine biota may be far more resistant to ocean acidification than hitherto believed. However, such a meta-analytical approach can mask more subtle features, for example differing sensitivities during the life-cycle of an organism. Using a similar metric on an echinoderm database, we show that key bottlenecks present in the life-cycle (e.g. larvae being more vulnerable than adults) and responsible for driving the whole species response may be hidden in a global meta-analysis. Our data illustrate that any ecological meta-analysis should be hypothesis driven, taking into account the complexity of biological systems, including all life-cycle stages and key biological processes. Available data allow us to conclude that near-future ocean acidification can/will have dramatic negative impact on some marine species, including echinoderms, with likely consequences at the ecosystem level.     

Study of the moist Convective Boundary Layer structure by backscattering lidar

Measurements of the structure of the Convective Boundary Layer (CBL) were made from the ground and from the ARAT aircraft with a backscattering lidar during the preliminary phase of the French project LEANDRE. A numerical model of Mie theory diffusion was used to determine a theoretical profile of the extinction coefficient, as a function of relative humidity. Comparisons between theoretical and measured profiles were made. Good agreement was found, which confirms that the variation of the extinction coefficient in the CBL is primarily controlled by the relative humidity. This paper also presents a detailed analysis of the small-scale structure of the CBL. The normalized length and number of thermals are estimated. Results are in agreement with previousin-situ measurements. An analysis of the bidimensional cross-section of the extinction coefficient shows that this coefficient permits one to retrieve more quantitative information than the range-corrected signal, as the fractions of entrained air and surface-layer air at a given altitude.     

The pre-Cretaceous deep-seated tectonics of the Abukuma massif and its place in the structural framework of Japan

The structures and microstructures of the Takanuki and Hitachi areas in the Abukuma massif, Northeast Japan are described. In the Takanuki area, the basic Gosaisho series thrusts the pelitic Takanuki ones in a HP metamorphic context. The nappe structure is afterwards refolded by a migmatitic dome: the Samegawa dome, in a HT metamorphic context. Microtectonic analysis shows that the nappe was transported from south to north along the stretching lineation. Geometric features suggest that the Samegawa dome was emplaced by diapirism. The role of the thrust surface as an instable interface promoting the doming is emphasized. The Hitachi metamorphic rocks composed of basic schist, limestone and sandstone shist thrust the pelitic rocks of the western Hitachi gneisses. As for the Takanuki area, the thrusting occurred in ductile synmetamorphic conditions with a north or northeastward displacement. Owing to lithologic, petrologic, structural similitudes, the nappe of the Hitachi metamorphic rocks and that of the Gosaisho series are unified into a unique nappe with a northward motion. The emplacement occurred between late Permian and late Cretaceous likely in late Jurassic. The allochthonous units of the Abukuma massif are correlated with the Green Schist nappe described in Southwest Japan, since they are surrounded by the same zones, namely the Tanba zone and the Kurosegawa-Kitakami one. Moreover both in Southwest and Northeast Japan, the emplacement of the Green Schist nappes is due to a shear deformation inducing rotational structures along the stretching lineation indicating the same sense of transport, that is eastward in Southwest Japan and northward in Northeast Japan, owing to the late bending of the Japanese Islands. The late Jurassic nappe structure is obliquely overprinted by a HT metamorphism, Ryoke in Southwest Japan, Abukuma in Northeast Japan, and afterwards cut by late faults as the Median Tectonic Line or the Tanakura fault, giving rise to the present complexity.