Microdistribution of primordial Ne and Ar in fine‐grained rims,matrices, and dark inclusions of unequilibrated chondrites—Clues on nebular processes

Abstract— The low temperature fine‐grained material in unequilibrated chondrites, which occurs as matrix, rims, and dark inclusions, carries information about the solar nebula and the earliest stages of planetesimal accretion. The microdistribution of primordial noble gases among these components helps to reveal their accretionary and alteration histories. We measured the Ne and Ar isotopic ratios and concentrations of small samples of matrix, rims, and dark inclusions from the unequilibrated carbonaceous chondrites Allende (CV3), Leoville (CV3), and Renazzo (CR2) and from the ordinary chondrites Semarkona (LL3.0), Bishunpur (LL3.1), and Krymka (LL3.1) to decipher their genetic relationships. The primordial noble gas concentrations of Semarkona, and—with certain restrictions—also of Leoville, Bishunpur, and Allende decrease from rims to matrices. This indicates a progressive accretion of nebular dust from regions with decreasing noble gas contents and cannot be explained by a formation of the rims on parent bodies. The decrease is probably due to dilution of the noble‐gas‐carrying phases with noble‐gas‐poor material in the nebula. Krymka and Renazzo both show an increase of primordial noble gas concentrations from rims to matrices. In the case of Krymka, this indicates the admixture of noble gas‐rich dust to the nebular region from which first rims and then matrix accreted. This also explains the increase of the primordial elemental ratio 36Ar/ 20Ne from rims to matrix. Larger clasts of the noble‐gas‐rich dust form macroscopic dark inclusions in this meteorite, which seem to represent unusually pristine material. The interpretation of the Renazzo data is ambiguous. Rims could have formed by aqueous alteration of matrix or—as in the case of Krymka—by progressive admixture of noble gas‐rich dust to the reservoir from which the Renazzo constituents accreted. The Leoville and Krymka dark inclusions, as well as one dark inclusion of Allende, show noble gas signatures different from those of the respective host meteorites. The Allende dark inclusion probably accreted from the same region as Allende rims and matrix but suffered a higher degree of alteration. The Leoville and Krymka dark inclusions must have accreted from regions different from those of their respective rims and matrices and were later incorporated into their host meteorites. The noble gas data imply a heterogeneous reservoir with respect to its primordial noble gas content in the accretion region of the studied meteorites. Further studies will have to decide whether these differences are primary or evolved from an originally uniform reservoir.     

Generation of Porphyritic and Equigranular Mafic Enclaves During Magma Recharge Events at Unzen Volcano, Japan

Mafic to intermediate enclaves are evenly distributed throughoutthe dacitic 1991–1995 lava sequence of Unzen volcano,Japan, representing hundreds of mafic recharge events over thelife of the volcano. This study documents the morphological,textural, chemical, and petrological characteristics of theenclaves and coexisting silicic host lavas. The eruptive productsdescribed in this study appear to be general products of magmamingling, as the same textural types are seen at many othervolcanoes. Two types of magmatic enclaves, referred to as Porphyriticand Equigranular, are easily distinguished texturally. Porphyriticenclaves display a wide range in composition from basalt toandesite, are glass-rich, spherical and porphyritic, and containlarge, resorbed, plagioclase phenocrysts in a matrix of acicularcrystals and glass. Equigranular enclaves are andesitic, non-porphyritic,and consist of tabular, medium-grained microphenocrysts in amatrix glass that is in equilibrium with the host dacite magma.Porphyritic enclaves are produced when intruding basaltic magmaengulfs melt and phenocrysts of resident silicic magma at theirmutual interface. Equigranular enclaves are a product of a moreprolonged mixing and gradual crystallization at a slower coolingrate within the interior of the mafic intrusion. KEY WORDS: mafic enclaves; quenched mafic inclusions; magma mingling; Unzen volcano; Unzen Scientific Drilling Project; resorbed plagioclase     

Isotopic and elemental fractionation of solar wind implanted in the Genesis concentrator target characterized and quantified by noble gases

Abstract– We report concentrations and isotopic compositions of He, Ne, and Ar measured with high spatial resolution along a radial traverse of a silicon carbide (SiC) quadrant of the Genesis mission concentrator target. The Ne isotopic composition maps instrumental fractionation as a function of radial position in the target: the maximum observed isotopic fractionation is approximately 33‰ per mass unit between the center and periphery. The Ne fluence is enhanced by a factor of 43 at the target center and decreases to 5.5 times at the periphery relative to the bulk solar wind fluence. Neon isotopic profiles measured along all four arms of the “gold cross” mount which held the quadrants in the concentrator target demonstrate that the concentrator target was symmetrically irradiated during operation as designed. We used implantation experiments of Ne into SiC and gold to quantify backscatter loss and isotopic fractionation and compared measurements with numerical simulations from the code “stopping and range of ions in matter.” The ²⁰Ne fluence curve as a function of radial distance on the target may be used to construct concentration factors relative to bulk solar wind for accurate corrections for solar wind fluences of other light elements to be measured in the concentrator target. The Ne isotopic composition as a function of the radial distance in the SiC quadrant provides a correction for the instrumental mass‐dependent isotopic fractionation by the concentrator and can be used to correct measured solar wind oxygen and nitrogen isotopic compositions to obtain bulk solar wind isotopic compositions.     

Metamorphism of the Crystalline Basement of Central Chile

The metamorphic basement of the Cordillera de la Costa, in CentralChile, consists mainly of slate, meta-sandstone, phyllite, andmica schist but contains small quantities of greenschist. Thegreater part of the basement is comprised in the Curepto series,and is characterized by dynamo-metamorphism whose intensityincreases westward. East of this is the smaller Nirivilo series,characterized by contact metamorphism whose intensity increaseseastward toward a granodiorite batholith. At the northern endof the metamorphic belt lies the Pichilemu series, in whichthe metamorphism is dynamo-thermal and increases in intensityto the east. The rocks in the first two areas are divisibleinto zones that trend north-north-east, essentially parallelto the margin of the batholith and to the Pacific coast; butin the Pichilemu area the zoning trends north-west. In the Cureptoseries three zones were distinguished; these are, in order fromeast to west: (1) a muscovite-chlorite(-albite) slate zone,(2) a muscovite-biotite(-albite) phyllite zone, and (3) a muscovite-chlorite-albite(±garnet) schist zone. The rocks in all three zones belongto the greenschist facies; the chlorite in the third zone isbelieved to be a product of H metasomatism. In the much narrowerNirivilo area no zones were mapped, but the following eastwardsuccession of critical assemblages was recognized: (1) muscovite-biotite-chlorite-albite;(2) muscovite-biotite-chlorite-andalusite-albite; (3) biotite-muscovite-andalusite-oligoclase;(4) biotite(± muscovite)-andalusite-sillimanite (or cordierite).The muscovite in the rocks that have undergone highgrade metamorphismis largely of metasomatic origin. Part of the sillimanite hasbeen formed at the expense of biotite and andalusite. In mostof the Nirivilo area the most strongly metamorphosed rocks areof the hornblende-hornfels facies, but small parts of that areamay contain rocks of the pyroxene-hornfels facies. The Pichilemuarea comprises the following zones and subzones: (1) a biotitezone, which includes (a) a muscovite-chlorite-biotite-albitesubzone and (b) a muscovite-biotite-albite subzone; (2) a garnet-oligoclasezone; (3) a staurolite-andalusite zone; (4) a muscovite-sillimanitezone; and (5) a sillimanite-orthoclase zone which includes (a)a sillimanite-orthoclase subzone and (b) a sillimanite-orthoclase-cordierite-almandinesubzone. Some thermal metamorphism is superimposed on the regionalmetamorphism. The facies grade from the greenschist to the granuliteor intermediate between the granulite and the amphibolite facies.The three series represent different pressure conditions: theNirivilo series corresponds to a low-pressure (contact) type,Pichilemu represents a low-pressure intermediate, dynamo-thermaltype, and Curepto is a dynamothermal, high-pressure intermediatetype series. The Curepto area was affected first, the Pichilemuarea next, and the Nirivilo area last. The metamorphism in allthree series is thought to have occurred during a single tectoniccycle within Late Paleozoic time, but it was probably interruptedby periods of erosional unloading. The width of the contactaureole is thought to have been determined by the irregularexpansion of the batholith. The analogy between the metamorphicseries of the Cordillera de la Costa and Miyashiro's circum-Pacificpaired belts is briefly discussed.     

Transformation of debris flows into turbidity currents: mechanisms inferred from laboratory experiments

Three sets of lock exchange experiments were run to look at the generation of turbidity currents from debris flows. The flows ranged from reasonably dilute (4% volumetric concentration) to dense (40% volumetric concentration) with cohesive, non-cohesive and mixed cohesive/non-cohesive sediment. Concentration was measured at one height using an Ultrasonic High Concentration Meter. Velocity was measured using Ultrasonic Doppler Velocimetry Profiling at 10 different heights in each run. The resulting flows range from plug flows to well mixed flows. Comparison of the concentration profiles, velocity time–height plots and vertical profiles of downstream velocity and root mean square velocity showed several different transformation mechanisms. Depending on the concentration and composition of the flow, transformation took place through one or more of the following processes: erosion of material from the dense mass, breaking apart of the dense underflow, breaking of internal waves and turbulent mixing. The extent of transformation depends on the viscosity and density of the flow. Initially very dense and viscous flows experience minor transformation only at the surface, resulting in a dilute turbidity current. Flows that are initially not so dense and viscous are churned up entirely, undergoing the different transformation processes. For these flows, transformation processes work throughout the entire flow, not just at the surface. Transformation of the less-dense flows is efficient with all or most material ending up in the resulting turbidity current.     

Late Pleistocene and Holocene cool‐water carbonates of the Western Mediterranean Sea

Post‐glacial, neritic cool‐water carbonates of the Western Mediterranean Sea were examined by means of hydroacoustic data, sediment surface sampling and vibrocoring to unravel geometries and to reconstruct sedimentary evolution in response to the last sea‐level rise. The analysed areas, located on the Alboran Ridge, in the Bay of Oran, and at the southern shelf of the island of Mallorca, are microtidal and bathed by oligotrophic to weakly mesotrophic waters. Seasonal water temperature varies between 13 °C and 27 °C. Echosounder profiles show that the Bay of Oran and the southern shelf of Mallorca are distally steepened ramps, while the Alboran Ridge forms a steep‐flanked rugged plateau around the Alboran Island. In the three areas, an up to 10 m thick post‐glacial sediment cover overlies an unconformity. In Oran and Mallorca, stacked lowstand wedges occur in water depths of 120 to 130 m. On the Alboran Ridge and in the Bay of Oran, highstand wedges occur at 35 to 40 m. Up to 5 m long cores of upper Pleistocene to Holocene successions were recovered in water depths between 40 and 81 m. Deposits contain more than 80% carbonate, with mixed carbonate‐volcaniclastics in the lower part of some cores in Alboran. The carbonates consist of up to 53% of aragonite and up to 83% of high magnesium calcite. Radiocarbon dating of bivalve shells, coralline algae and serpulid tubes indicates that deposits are as old as 12 400 cal yr bp . The carbonate factories in the three areas are dominated mostly by red algae, but some intervals in the cores are richer in bivalves. A facies rich in the gastropod Turritella, reflecting elevated surface productivity, is restricted to the Mallorca Shelf. Rhodoliths occur at the sediment surface in most areas at water depths shallower than 70 m; they form a 10 to 20 cm thick veneer overlying rhodolith‐poor bioclastic sediments which, nonetheless, contain abundant red algal debris. This rhodolith layer has been developing for the past 800 to 1000 years. Similar layers at different positions in the cores are interpreted as reflecting in situ growth of rhodoliths at times of reduced net sedimentation. Sedimentary successions in the cores record the post‐glacial sea‐level rise and the degree of sediment exposure to bottom currents. Deepening‐upward trends in the successions are either reflected by shallow to deep facies transitions or by a corresponding change of depth‐indicative red algae. There are only weak downcore variations of carbonate mineralogy, which indicate that no dissolution or high magnesium to low magnesium calcite neomorphism occurs in the shallow subsurface. These new data support the approach of using the Recent facies distribution for interpretation of past cool‐water, low‐energy, microtidal carbonate depositional systems. Hydroacoustic data show that previous Pleistocene transgressive and highstand inner ramp deposits and wedges were removed during sea‐level lowstands and accumulated downslope as stacked lowstand wedges; this suggests that, under conditions of high‐amplitude sea‐level fluctuations, the stratigraphic record of similar cool‐water carbonates may be biased.     

Fossil pollen, molluscs, and stable isotopes in the Dättnau valley, Switzerland

Pollen and mollusc deposits in a sedimentation series laid down in the Dattnau valley during the Late Glacial and early Post-glacial were studied. For the first time δ¹³C and δ¹⁸O in land-snail shells were measured. It was possible to reconstruct vegetational and climatic developments from the Bölling ( c . 12,500 B.P.) until well into the early Boreal ( c . 9,000 B.P.). The two sets of findings agree well. The Late Glacial is seen to comprise two intervals: the continuous, locally rather moist, warm Bölling/Alleröd period, and the subsequent dry . cold Younger Dryas. The profile ceases after the changeover from the Late Glacial to the Post-glacial. The transitions from the Alleröd to the Younger Dryas and hence to the Preboreal and Boreal are both clearly identifiable in the pollen diagram; the mollusc record, however, ceases to be interpretable shortly before the climatic change to the Post-glacial. The δ¹⁸O curve shows a clear distinction between the AllerÖd and the Younger Dryas. The Gerzensee fluctuation, immediately before this transition. is evident as a negative deviation.     

Silicon in iron meteorite metal

Abstract– We report Si concentrations in the metal phases of iron meteorites. Analyses were performed by secondary ion mass spectrometry using a CAMECA 1270 ion probe. The Si concentrations are low (0.09–0.46 μg g^?1), with no apparent difference in concentration between magmatic and nonmagmatic iron meteorites. Coexisting kamacite and Ni‐rich metal phases have similar Si contents. Thermodynamic calculations show that Fe,Ni‐metal in equilibrium with silicate melts at temperatures where metal crystallizes should contain approximately 100 times more Si than found in iron meteorites in this work. The missing Si may either occur as tiny silicate inclusions in metal or it may have diffused as Si‐metal into surrounding silicates at low temperatures. In both cases, extensive low‐temperature diffusion of Si in metal is required. It is therefore concluded that low Si in iron meteorites is a result of subsolidus reactions during slow cooling.     

Hydrological runoff modelling by the use of remote sensing data with reference to the 1993–1994 and 1995 floods in the river Rhine catchment

In hydrological modelling of runoff processes, including water balance, various input data and parameters can be acquired or estimated by the use of remote sensing (RS) techniques.The acquisition and use of synoptic RS areal information rather than traditional point information is an important issue in hydrology. Hydrological models allow runoff/water balance in catchments to be calculated and flow routing within flow channels to be done. For runoff and water balance computations land use, soil moisture, detection of snow and ice, digital terrain models (DTM), as well as hydrometeorological information and discharge are important. For flow routing, water level information, geometric–topographic information such as cross-sections for normal and flood conditions, coefficient of roughness and velocity of flow and its cross-sectional distribution are required. In addition, water level information (lower and upper level) is needed for shipping and for design purposes. In the German part of the River Rhine catchment, several focus areas in the December 1993–January 1994 and January 1995 floods were covered with RS data [ERS-1 and airborne SAR, both C-band VV, passive microwave (18·7, 36·5, 89 GHz), TIR, UV, aerial photographs (b/w PAN, b/w NIR)], giving a good opportunity for a comparison of methods. Evaluation is still continuing. The importance of soil saturation for flood generation and, therefore, for flood monitoring, was shown on this occasion. The use of ERS SAR data for soil moisture estimation is currently being investigated by the Federal Institute of Hydrology. Also, the need for emergency schemes for data acquisition and easy, quick and affordable RS data dissemination was demonstrated. The assimilation of RS data with GIS information such as DTMs, including relevant topographic features like dams, which is omitted in currently available raster digital elevation models, is promising. RS altimetry techniques can be a step towards high resolution DTMs for hydrological purposes. Ground truth reference data are still needed. © 1997 John Wiley & Sons, Ltd.     

The H2/CO ratio of emissions from combustion sources: comparison of top-down with bottom-up measurements in southwest Germany

The hydrogen-to-carbon monoxide (H₂/CO) emission ratio of anthropogenic combustion sources was determined from more than two years of quasi-continuous atmospheric observations in Heidelberg (49°24' N, 8°42' E), located in the polluted Rhein-Neckar region. Evaluating concurrent mixing ratio changes of H₂ and CO during morning rush hours yielded mean molar H₂/CO ratios of 0.40 ± 0.06, while respective results inferred from synoptic pollution events gave a mean value of 0.31 ± 0.05 mole H₂/mole CO. After correction for the influence of the H₂ soil sink on the measured ratios, mean values of 0.46 ± 0.07 resp. 0.48 ± 0.07 mole H₂/mole CO were obtained, which are in excellent agreement with direct source studies of traffic emissions in the Heidelberg/Mannheim region (0.448 ± 0.003 mole H₂/mole CO). Including results from other European studies, our best estimate of the mean H₂/CO emission ratio from anthropogenic combustion sources (mainly traffic) ranges from 0.45 to 0.48 mole H₂/mole CO, which is about 20% smaller than the value of 0.59 mole H₂/mole CO which is frequently used as the basis to calculate global H₂ emissions from anthropogenic combustion sources.