Seasonal and interannual variability of phytoplankton pigment in the Laccadive (Lakshadweep) Sea as observed by the Coastal Zone Color scanner

Based on Coastal Zone Color Scanner data from November 1978 through December 1981, the seasonal cycle of phytoplankton pigment in the upper part of the euphotic zone is established for the offshore Laccadive Sea. Year-round, the pigment content is low and the seasonal range is small, following the pattern of the nutrient-poor Arabian Sea to the west. Apparently, indigenous phytoplankton blooms are absent. July and August, however, were poorly studied because of cloud cover. Interannual differences during the northeast monsoon and the spring intermonsoon periods are minor. The abundant phytoplankton caused by the upwelling off India during the southwest monsoon remains essentially restricted to the shelf, but there are occasional large, zonal outbreaks into the Laccadive Sea, as well as others advected to the south of India. Visual inspection of the raw CZCS scenes for June through November 1982–1985, with almost no data until August or even September, shows such outbreaks of pigment-rich water to be common. Inspection of monthly SeaWiFS images for 1997 through part of 2001 confirms the absence of indigenous phytoplankton blooms.     

GPS navigation data bit decoding error during strong equatorial scintillation

Strong equatorial scintillation is often characterized by simultaneous fast phase changes and deep amplitude fading. The combined effect poses a challenge for GNSS receiver carrier tracking performance. One of the consequences of the strong scintillation is increased navigation message data bit decoding error. Understanding the rate of the data bit decoding error under equatorial scintillation is essential for high accuracy and high integrity applications. We present the statistical relationship between the data bit decoding error occurrences and the intensity of amplitude scintillation based on the processing of intermediate frequency GPS scintillation data collected on Ascension Island in March 2013. A third-order phase lock loop (PLL) is implemented to process the data and to access the data bit error typically expected in conventional receivers. A Kalman filter-based PLL is also used to process the same data to demonstrate that the data bit decoding error can be reduced through advanced carrier tracking designs.     

Meteorological monitoring of an active volcano: Implications for eruption prediction

Rainfall data collected on and around the Soufriere Hills Volcano, Montserrat between 1998 and 2003 were analysed to assess the impact on primary volcanic activity, defined here as pyroclastic flows, dome collapses, and explosions. Fifteen such rainfall-triggered events were identified. If greater than 20 mm of rain fell on a particular day, the probability of a dome collapse occurring on that day increased by a factor of 6.3% to 9.2%, compared to a randomly chosen day. Similarly, the probability of observing pyroclastic flows and explosions on a day with > 20 mm of rainfall increased by factors of 2.6 and 5.4, respectively. These statistically significant links increased as the rainfall threshold was increased. Seventy percent of these rainfall-induced dome collapse episodes occurred on the same calendar day (most within a few hours) as the onset of intense rainfall, but an extra 3 occurred one or two calendar days later. The state of the volcano was important, with the rainfall–volcanic activity link being strongest during periods of unstable dome growth and weakest during periods of no dome growth or after a recent major collapse.Over 50% of the heavy rain days were associated with large-scale weather systems that can potentially be forecast up to a few days ahead. However, the remaining heavy rain days were associated with small-scale, essentially unpredictable weather systems. There was significant variability in the amount of rainfall recorded by different rain gauges, reflecting topographic variations around the volcano but also the inherent small-scale variability within an individual weather system. Hence, any monitoring/warning program is recommended to use a network, rather than just a single gauge. The seasonal cycle in rainfall was pronounced, with nearly all the heavy rain days occurring in the May–December wet season. Hence, the dome was at its most vulnerable at the beginning of the wet season after a period of uninterrupted growth. Interannual variability in rainfall was related to tropical Pacific and Atlantic sea surface temperature anomalies, and holds out the prospect of some limited skill in volcanic hazard forecasts at even longer lead times.     

Contemporary deformation in the Kashmir–Himachal,Garhwal and Kumaon Himalaya: significant insights from 1995–2008 GPS time series

We present new insights on the time-averaged surface velocities, convergence and extension rates along arc-normal transects in Kumaon, Garhwal and Kashmir–Himachal regions in the Indian Himalaya from 13 years of high-precision Global Positioning System (GPS) time series (1995–2008) derived from GPS data at 14 GPS permanent and 42 campaign stations between $29.5{-}35^{\circ }\hbox {N}$ and $76{-}81^{\circ }\hbox {E}$ . The GPS surface horizontal velocities vary significantly from the Higher to Lesser Himalaya and are of the order of 30 to 48 mm/year NE in ITRF 2005 reference frame, and 17 to 2 mm/year SW in an India fixed reference frame indicating that this region is accommodating less than 2 cm/year of the India–Eurasia plate motion ( ${\sim }4~\hbox {cm/year}$ ). The total arc-normal shortening varies between ${\sim }10{-}14~\hbox {mm/year}$ along the different transects of the northwest Himalayan wedge, between the Indo-Tsangpo suture to the north and the Indo-Gangetic foreland to the south indicating high strain accumulation in the Himalayan wedge. This convergence is being accommodated differentially along the arc-normal transects; ${\sim } 5{-}10~\hbox {mm/year}$ in Lesser Himalaya and 3–4 mm/year in Higher Himalaya south of South Tibetan Detachment. Most of the convergence in the Lesser Himalaya of Garhwal and Kumaon is being accommodated just south of the Main Central Thrust fault trace, indicating high strain accumulation in this region which is also consistent with the high seismic activity in this region. In addition, for the first time an arc-normal extension of ${\sim }6~\hbox {mm/year}$ has also been observed in the Tethyan Himalaya of Kumaon. Inverse modeling of GPS-derived surface deformation rates in Garhwal and Kumaon Himalaya using a single dislocation indicate that the Main Himalayan Thrust is locked from the surface to a depth of ${\sim }15{-}20~\hbox {km}$ over a width of 110 km with associated slip rate of ${\sim }16{-}18~\hbox {mm/year}$ . These results indicate that the arc-normal rates in the Northwest Himalaya have a complex deformation pattern involving both convergence and extension, and rigorous seismo-tectonic models in the Himalaya are necessary to account for this pattern. In addition, the results also gave an estimate of co-seismic and post-seismic motion associated with the 1999 Chamoli earthquake, which is modeled to derive the slip and geometry of the rupture plane.     

A density-dependent multi-species model to assess groundwater flow and nutrient transport in the coastal Keauhou aquifer,Hawai‘i,USA

Hydrogeology Journal - Fresh groundwater is a critical resource supporting coastal ecosystems that rely on low-salinity, nutrient-rich groundwater discharge. This resource, however, is subject to...     

Intensified oxygen minimum zone on the western shelf of Bay of Bengal during summer monsoon: influence of river discharge

A study on biogeochemical cycling in the west coastal Bay of Bengal was undertaken during the peak discharge period to understand the influence of enhanced stratification and primary production on the possible intensification of the oxygen minimum zone (OMZ). Our study reveals that oxygen concentrations were below the detection limits in the northwestern (NW) coastal Bay of Bengal between 100 and 500 m associated with strong stratification and high phytoplankton biomass. Such low oxygen concentrations have never been reported so far from the coastal Bay of Bengal. Despite the existence of an environment conducive to denitrification in the coastal Bay of Bengal, accumulation of neither secondary nitrite nor nitrous oxide (N₂O) was observed. The absence of denitrification was reported to be caused by faster scavenging of organic matter and low bacterial respiration rates; in contrast, our results suggest that neither of these factors are potential reasons for the absence of denitrification in the coastal Bay of Bengal.     

Contemporary 14C radiocarbon levels of oxygenated polybrominated diphenyl ethers (O-PBDEs) isolated in sponge-cyanobacteria associations

Considerable debate surrounds the sources of oxygenated polybrominated diphenyl ethers (O-PBDEs) in wildlife as to whether they are naturally produced or result from anthropogenic industrial activities. Natural radiocarbon (¹⁴C) abundance has proven to be a powerful tool to address this problem as recently biosynthesized compounds contain contemporary (i.e. modern) amounts of atmospheric radiocarbon; whereas industrial chemicals, mostly produced from fossil fuels, contain no detectable ¹⁴C. However, few compounds isolated from organisms have been analyzed for their radiocarbon content. To provide a baseline, we analyzed the ¹⁴C content of four O-PBDEs. These compounds, 6-OH-BDE47, 2′-OH-BDE68, 2′,6-diOH-BDE159, and a recently identified compound, 2′-MeO-6-OH-BDE120, were isolated from the tropical marine sponges Dysidea granulosa and Lendenfeldia dendyi. The modern radiocarbon content of their chemical structures (i.e. diphenyl ethers, C₁₂H₂₂O) indicates that they are naturally produced. This adds to a growing baseline on, at least, the sources of these unusual compounds.     

Evidence of microbially mediated arsenic mobilization from sediments of the Aquia aquifer, Maryland, USA

Sediments from the Aquia aquifer in coastal Maryland were collected as part of a larger study of As in the Aquia groundwater flow system where As concentration are reported to reach levels as high as 1072 nmol kg⁻¹, (i.e., ∼80 μg/L). To test whether As release is microbially mediated by reductive dissolution of Fe(III) oxides/oxyhydroxides within the aquifer sediments, the Aquia aquifer sediment samples were employed in a series of microcosm experiments. The microcosm experiments consisted of sterilized serum bottles prepared with aquifer sediments and sterilized (i.e., autoclaved), artificial groundwater using four experimental conditions and one control condition. The four experimental conditions included the following scenarios: (1) aerobic; (2) anaerobic; (3) anaerobic + acetate; and (4) anaerobic + acetate + AQDS (anthraquinone-2,6-disulfonic acid). AQDS acts as an electron shuttle. The control condition contained sterilized aquifer sediments kept under anaerobic conditions with an addition of AQDS. Over the course of the 27 day microcosm experiments, dissolved As in the unamended (aerobic and anaerobic) microcosms remained constant at around ∼28 nmol kg⁻¹ (2 μg/L). With the addition of acetate, the amount of As released to the solution approximately doubled reaching ∼51 nmol kg⁻¹ (3.8 μg/L). For microcosm experiments amended with acetate and AQDS, the dissolved As concentrations exceeded 75 nmol kg⁻¹ (5.6 μg/L). The As concentrations in the acetate and acetate + AQDS amended microcosms are of similar orders of magnitude to As concentrations in groundwaters from the aquifer sediment sampling site (127-170 nmol kg⁻¹). Arsenic concentrations in the sterilized control experiments were generally less than 15 nmol kg⁻¹ (1.1 μg/L), which is interpreted to be the amount of As released from Aquia aquifer sediments owing to abiotic, surface exchange processes. Iron concentrations released to solution in each of the microcosm experiments were higher and more variable than the As concentrations, but generally exhibited similar trends to the As concentrations. Specifically, the acetate and acetate + AQDS amended microcosm typically exhibited the highest Fe concentrations (up to 1725 and 6566 nmol kg⁻¹, respectively). The increase in both As and Fe in the artificial groundwater solutions in these amended microcosm experiments strongly suggests that microbes within the Aquia aquifer sediments mobilize As from the sediment substrate to the groundwaters via Fe(III) reduction.     

GPS-derived deformation rates in northwestern Himalaya and Ladakh

Deformation rates derived from GPS measurements made at two continuously operating stations at Leh (34.1°N, 77.6°E) and Hanle (32.7°N, 78.9°E), and eight campaign sites in the trans-Himalayan Ladakh spanning 11 years (1997–2008), provide a clear picture of the kinematics of this region as well as the convergence rate across northwestern Himalaya. All the Ladakh sites move 32–34 mm/year NE in the ITRF2005 reference frame, and their relative velocities are 13–16 mm/year SW in the Indian reference frame and ~19 mm/year W with reference to the Lhasa IGS station in southeastern Tibet. The results indicate that there is no statistically significant deformation in the 200-km stretch between the continuous sites Leh and Hanle as well as between Leh and Nubra valley sites along the Karakoram fault, whereas the sites in and around the splayed Karakoram fault region indicate surface deformation of 2.5 mm/year. Campaign sites along the Karakoram fault zone indicate a fault parallel surface motion of 1.4–2.5 mm/year in the Tangste and western Panamik segment of the Karakoram fault, which quantifies the best possible GPS-derived dextral slip rate of 3 mm/year along this fault during this 11-year period. Baselines of Ladakh sites show convergence rates of 15–18 mm/year with respect to south India and 12–15 mm/year with respect to Delhi in north India and Almora in the Himalaya ~400 km north-northeast of Delhi. These constitute an arc normal convergence of 12–15 mm/year across the western Himalaya, which is consistent with arc normal convergence all along the Himalayan arc from west to east. Baseline extension rates of 14–16 mm/year between Lhasa and Ladakh sites are consistent with the east–west extension rate of Tibetan Plateau.     

Ti-in-zircon thermometry: applications and limitations

The titanium concentrations of 484 zircons with U-Pb ages of ∼1 Ma to 4.4 Ga were measured by ion microprobe. Samples come from 45 different igneous rocks (365 zircons), as well as zircon megacrysts (84) from kimberlite, Early Archean detrital zircons (32), and zircon reference materials (3). Samples were chosen to represent a large range of igneous rock compositions. Most of the zircons contain less than 20 ppm Ti. Apparent temperatures for zircon crystallization were calculated using the Ti-in-zircon thermometer (Watson et al. 2006, Contrib Mineral Petrol 151:413–433) without making corrections for reduced oxide activities (e.g., TiO₂ or SiO₂), or variable pressure. Average apparent Ti-in-zircon temperatures range from 500° to 850°C, and are lower than either zircon saturation temperatures (for granitic rocks) or predicted crystallization temperatures of evolved melts (∼15% melt residue for mafic rocks). Temperatures average: 653 ± 124°C (2 standard deviations, 60 zircons) for felsic to intermediate igneous rocks, 758 ± 111°C (261 zircons) for mafic rocks, and 758 ± 98°C (84 zircons) for mantle megacrysts from kimberlite. Individually, the effects of reduced or , variable pressure, deviations from Henry’s Law, and subsolidus Ti exchange are insufficient to explain the seemingly low temperatures for zircon crystallization in igneous rocks. MELTs calculations show that mafic magmas can evolve to hydrous melts with significantly lower crystallization temperature for the last 10–15% melt residue than that of the main rock. While some magmatic zircons surely form in such late hydrous melts, low apparent temperatures are found in zircons that are included within phenocrysts or glass showing that those zircons are not from evolved residue melts. Intracrystalline variability in Ti concentration, in excess of analytical precision, is observed for nearly all zircons that were analyzed more than once. However, there is no systematic change in Ti content from core to rim, or correlation with zoning, age, U content, Th/U ratio, or concordance in U-Pb age. Thus, it is likely that other variables, in addition to temperature and , are important in controlling the Ti content of zircon. The Ti contents of igneous zircons from different rock types worldwide overlap significantly. However, on a more restricted regional scale, apparent Ti-in-zircon temperatures correlate with whole-rock SiO₂ and HfO₂ for plutonic rocks of the Sierra Nevada batholith, averaging 750°C at 50 wt.% SiO₂ and 600°C at 75 wt.%. Among felsic plutons in the Sierra, peraluminous granites average 610 ± 88°C, while metaluminous rocks average 694 ± 94°C. Detrital zircons from the Jack Hills, Western Australia with ages from 4.4 to 4.0 Ga have apparent temperatures of 717 ± 108°C, which are intermediate between values for felsic rocks and those for mafic rocks. Although some mafic zircons have higher Ti content, values for Early Archean detrital zircons from a proposed granitic provenance are similar to zircons from many mafic rocks, including anorthosites from the Adirondack Mts (709 ± 76°C). Furthermore, the Jack Hills zircon apparent Ti-temperatures are significantly higher than measured values for peraluminous granites (610 ± 88°C). Thus the Ti concentration in detrital zircons and apparent Ti-in-zircon temperatures are not sufficient to independently identify parent melt composition. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.