Testing optically stimulated luminescence dating on sand-sized quartz of deltaic deposits from the Sperchios delta plain,central Greece

This study reports on the first investigation into the potential of luminescence dating to establish a chronological framework for the depositional sequences of the Sperchios delta plain, central Greece. A series of three borehole cores(20 m deep) and two shallow cores(4 m deep), from across the delta plain, were extracted, and samples were collected for luminescence dating. The luminescence ages of sand-sized quartz grains were obtained from small aliquots of quartz, using the Single-Aliquot Regenerative-dose(SAR) protocol.The equivalent dose determination included a series of tests and the selection of the Minimum Age Model(MAM) as the most appropriate statistical model. This made it possible to confirm the applicability of quartz Optically Stimulated Luminescence(OSL) dating to establish absolute chronology for deltaic sediments from the Sperchios delta plain.Testing age results of the five cores showed that the deltaic sediments were deposited during the Holocene.A relatively rapid deposition is implied for the top ~14 m possibly as a result of the deceleration in the rate of the sea-level rise and the transition to terrestrial conditions, while on the deeper parts, the reduced sedimentation rate may indicate a lagoonal or coastal environment.     

A model for swelling rock in tunnelling

Summary In this paper, the phenomenon of swelling in tunnelling will be treated as a hydraulic-mechanical coupled process. This approach allows one to model the observed floor heaves realistically, i. e. without the prediction inevitable in the previous models of movements at the tunnel crown and walls. Furthermore, the development of heave and pressure over the course of time can be studied. The absence of deformations above the floor level is here interpreted as a consequence of the hydraulic boundary conditions. Besides the importance of seepage flow, the influence of rock strength is illustrated. Swelling rock is considered as an elastoplastic material. This allows one to predict the often large haaves of a tunnel floor as observed in situ. According to the numerical results, the area of practically relevant swelling strains extends as far as the plastic zone.     

Comparison of Deep Underwater Measurements and Radar Observations of Rainfall

Deep-water acoustical measurements of rainfall are compared to high-resolution ground radar observations for the first time. The measurements of underwater ambient sound were made from a subsurface mooring near Methoni, Greece, in 2004. The acoustical measurements were at 60-, 200-, 1000-, and 2000-m depths. Simultaneous ground-based polarimetric -band radar observations were made over the acoustic mooring. Comparisons show acoustic detection of rain events and storm structure that are in agreement with the radar observations. Results from a comparison between the underwater sound pressure level at different depths and the observed radar reflectivities are presented.     

Comparison of Raindrop Size Distribution Estimates From X-Band and S-Band Polarimetric Observations

This letter evaluates the consistency of rainfall drop size distribution (DSD) parameters that were estimated from attenuation-corrected X-band dual-polarization (XPOL) radar measurements with estimates from a colocated S-band dual-polarization radar (S-Pol). The DSD retrieval technique uses reflectivity and differential reflectivity, and a constrained relationship to estimate the three parameters of a ldquonormalizedrdquo gamma distribution model. The more definitive S-Pol DSD parameter estimates are used as a reference to assess the performance of the corresponding XPOL estimates for different rain-path attenuation values. Results show that XPOL attenuation-corrected profiles can provide rainfall DSD estimations that are consistent to an S-band dual-polarization radar, even in cases of moderate to high rain-path attenuation.     

Sources of Inaccuracy in Boron Isotope Measurement Using LA-MC-ICP-MS

Laser ablation multi-collector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) has become a valuable tool for the in situ measurement of the boron isotope composition of geological samples at high (tens to hundreds of μm) spatial resolution. That said, this application suffers from significant analytical challenges. We focus in this study on the underlying processes of two of the main causes for inaccuracies using this technique. We provide empirical evidence that not only Ca ions (Sadekov et al. 2019, Standish et al. 2019, Evans et al. 2021) but also Ar ions, that are reflected within the flight tube of the mass spectrometer, are the source for previously reported issues with spectral baselines. We also address the impact of plasma conditions on the instrumental mass fractionation as a source for matrix- and mass-load-related analytical biases. Comparing experimental data with the results of a dedicated release and diffusion model (RDM) we estimate that a close to complete (~ 97%) release of boron from the sample aerosol is needed to allow for consistently accurate LA boron isotope measurement results without the need for corrections.     

Impact of sub-grid variability of precipitation and canopy water storage on hydrological processes in a coupled land–atmosphere model

The impact of sub-grid variability of precipitation and canopy water storage is investigated by applying a new canopy interception scheme into the Community Atmosphere Model version 3 (CAM3) coupled with the Community Land Model version 3 (CLM3). Including such sub-grid variability alters the partitioning of net radiation between sensible heat flux and latent heat flux on land surface, which leads to changes in precipitation through various pathways/mechanisms. The areas with most substantial changes are Amazonia and Central Africa where convective rain is dominant and vegetation is very dense. In these areas, precipitation during December–January–February is increased by up to 2 mm/day. This increase is due to the enhanced large-scale circulation and atmospheric instability caused by including the sub-grid variability. Cloud feedback plays an important role in modifying the large-scale circulation and atmospheric instability. Turning off cloud feedback mitigates the changes in surface convergence and boundary layer height caused by inclusion of sub-grid variability of precipitation and water storage canopy, which moderate the effect on precipitation.     

Authigenic carbonate mineral formation in the Pagassitikos palaeolake during the latest Pleistocene, central Greece

The Pagassitikos Gulf in Greece is a semi-enclosed bay with a maximum depth of 102 m. According to the present-day bathymetric configuration and the sea level during the latest Pleistocene, the gulf would have been isolated from the open sea, forming a palaeolake since ~32 cal. ka b.p. Sediment core B-4 was recovered from the deepest sector of the gulf and revealed evidence of a totally different depositional environment in the lowest part of the core: this contained light grey-coloured sediments, contrasting strongly with overlying olive grey muds. Multi-proxy analyses showed the predominance of carbonate minerals (aragonite, dolomite and calcite) and gypsum in the lowest part of the core. Carbonate mineral deposition can be attributed to autochthonous precipitation that took place in a saline palaeolake with high evaporation rates during the last glacial–early deglacial period; the lowest core sample to be AMS ¹⁴C dated provided an age of 19.53 cal. ka b.p. The palaeolake was presumably reconnected to the open sea at ~13.2 cal. ka b.p. during the last sea-level rise, marking the commencement of marine sedimentation characterised by the predominance of terrigenous aluminosilicates and fairly constant depositional conditions lasting up to the present day.     

Seawater nutrient and carbonate ion concentrations recorded as P/Ca, Ba/Ca, and U/Ca in the deep-sea coral Desmophyllum dianthus

As paleoceanographic archives, deep sea coral skeletons offer the potential for high temporal resolution and precise absolute dating, but have not been fully investigated for geochemical reconstructions of past ocean conditions. Here we assess the utility of skeletal P/Ca, Ba/Ca and U/Ca in the deep sea coral D. dianthus as proxies of dissolved phosphate (remineralized at shallow depths), dissolved barium (trace element with silicate-type distribution) and carbonate ion concentrations, respectively. Measurements of these proxies in globally distributed D. dianthus specimens show clear dependence on corresponding seawater properties. Linear regression fits of mean coral Element/Ca ratios against seawater properties yield the equations: P/Ca_coral (μmol/mol) = (0.6 ± 0.1) P/Ca_sw(μmol/mol) - (23 ± 18), R² = 0.6, n = 16 and Ba/Ca_coral(μmol/mol) = (1.4 ± 0.3) Ba/Ca_sw(μmol/mol) + (0 ± 2), R² = 0.6, n = 17; no significant relationship is observed between the residuals of each regression and seawater temperature, salinity, pressure, pH or carbonate ion concentrations, suggesting that these variables were not significant secondary dependencies of these proxies. Four D. dianthus specimens growing at locations with Ω_arag ? 0.6 displayed markedly depleted P/Ca compared to the regression based on the remaining samples, a behavior attributed to an undersaturation effect. These corals were excluded from the calibration. Coral U/Ca correlates with seawater carbonate ion: U/Ca_coral(μmol/mol) = (−0.016 ± 0.003) (μmol/kg) + (3.2 ± 0.3), R² = 0.6, n = 17. The residuals of the U/Ca calibration are not significantly related to temperature, salinity, or pressure. Scatter about the linear calibration lines is attributed to imperfect spatial-temporal matches between the selected globally distributed specimens and available water column chemical data, and potentially to unresolved additional effects. The uncertainties of these initial proxy calibration regressions predict that dissolved phosphate could be reconstructed to ±0.4 μmol/kg (for 1.3-1.9 μmol/kg phosphate), and dissolved Ba to ±19 nmol/kg (for 41-82 nmol/kg Ba_sw). Carbonate ion concentration derived from U/Ca has an uncertainty of ±31μmol/kg (for ). The effect of microskeletal variability on P/Ca, Ba/Ca, and U/Ca was also assessed, with emphasis on centers of calcification, Fe-Mn phases, and external contaminants. Overall, the results show strong potential for reconstructing aspects of water mass mixing and biogeochemical processes in intermediate and deep waters using fossil deep-sea corals.     

Improving NWP through radar rainfall-driven land surface parameters: A case study on convective precipitation forecasting

In this study we investigate the effect of forcing the land surface scheme of an atmospheric mesoscale model with radar rainfall data instead of the model-generated rainfall fields. The goal is to provide improved surface conditions for the atmospheric model in order to achieve accurate simulations of the mesoscale circulations that can significantly affect the timing, distribution and intensity of convective precipitation. The performance of the approach is evaluated in a set of numerical experiments on the basis of a 2-day-long mesoscale convective system that occurred over the US Great Plains in July 2004. The experimental design includes multiple runs covering a variety of forcing periods. Continuous data integration was initially used to investigate the sensitivity of the model’s performance in varying soil state conditions, while shorter time windows prior to the storm event were utilized to assess the effectiveness of the procedure for improving convective precipitation forecasting. Results indicate that continuous integration of radar rainfall data brings the simulated precipitation fields closer to the observed ones, as compared to the control simulation. The precipitation forecasts (up to 48 h) appear improved also in the cases of shorter integration periods (24 and 36 h), making this technique potentially useful for operational settings of weather forecasting systems. A physical interpretation of the results is provided on the basis of surface moisture and energy exchange.