Survival,growth and shell deformities of copper- and cadmium-exposed mussels (Mytilus edulis L.) in brackish water

Mussels, Mytilus edulis L., were exposed to elevated concentrations of copper or cadmium in the laboratory, then placed in cages in the sea (salinity 7‰). One year later maximum lengths of the mussels were measured and shells screened for deformities. Growth was 0·6 cm year^?1 in the control cages and retarded in cages of exposed mussels. A total of 63% of cadmium-exposed and 46% of copper-exposed mussels had shell deformities. In the control cages 26% were deformed while in a natural population only 3% were deformed. The proportion of deformities to growth was inversely related. Low concentrations showed their injuriousness in this long-term test, probably due to the closing of the valves during exposure to high concentrations.     

A detailed study of the duality relation for the least squares adjustment in euclidean spaces

The Euclidean spaces with their inner products are used to describe methods of least squares adjustment as orthogonal projections on finite-dimensional subspaces. A unified Euclidean space approach to the least squares adjustment methods “observation equations” and “condition equations” is suggested. Hence not only the two adjustment solutions are treated from the view-point of Euclidean space theory in a unified frame but also the existing duality relation between the methods of “observation equations” and “condition equations” is discussed in full detail. Another purpose of this paper is to contribute to the development of some familiarity with Euclidean and Hilbert space concepts. We are convinced that Euclidean and Hilbert space techniques in least squares adjustment are elegant and powerful geodetic methods.     

Turbulent characteristics of a shallow convective internal boundary layer

Turbulent characteristics of a 50 to 100 m deep convective internal boundary layer (I.B.L.) have been studied. The data were gathered at a flat coastal site (Näsudden on the island of Gotland, Sweden) during three consecutive days in May 1980 which were characterized by a steady, very stable stratified marine approach flow. The site is situated on a flat area ca. 1500 m from the shoreline. Only daytime runs have been analysed in the present paper. The sensible heat flux at the ground was typically 200 W m^-2 and was found to decrease more or less linearly with height throughout the I.B.L., being slightly negative at greater heights. The momentum flux was also found to decrease with height, but nevertheless shear production of turbulent kinetic energy was found to be large throughout the entire I.B.L. The analysis shows that the turbulent regime has a mixed character. Certain characteristics, such as the rate of growth of the I.B.L., appear to be almost entirely controlled by mechanical turbulence, while others, notably temperature variance and the spectrum of vertical velocity, scale remarkably well with w _* and z _i, in accordance with the results found in fully convective conditions during the experiments at Minnesota and Aschurch. Other turbulent characteristics, such as spectra of the horizontal wind components measured near the top of the I.B.L. tend to adhere to mixed-layer scaling in the high frequency range, exhibiting much increased energy in the lower (reduced) frequency range. Spectra of the velocity components from 10 m are shown to be in general agreement with findings from ‘ideal’, homogeneous sites (Kansas) when properly normalized, although the low frequency part of u- and v-spectra are slightly reduced compared to the case with deep convection.     

Geochemical exploration of a Precambrian Batholith, source of a Cu-W mineralization of the tourmaline breccia in Southern Finland

The Hämeenkyrö batholith is a round-shaped plutonic body of an areal size of 147 km². It is composed of calc-alkaline to alkaline rocks that intruded previously metamorphosed Svecofennian volcanogenic and sedimentary schists 1860 Ma ago. The Cu-W bearing tourmaline breccia of the Ylörvi deposit occurs in metavolcanic rocks close to the eastern contact of the batholith.The average sampling density in the batholith was 1 sample per km², and 175 samples were analyzed for Cu, Au, Ag, Ni, Pb, Co, Zn, S by AAS for SiO₂, TiO₂, Al₂O₃, FeO, MnO, MgO, CaO, Na₂O, K₂O, As, Sn and P by X-ray fluorescence. Mo and W were determined colorimetrically. Barth mesonorms were calculated for each sample and the rock type was determined according to Streckeisen's classification. Element distributions are displayed on contour maps.The rock types of the batholith exhibit an asymmetric concentric arrangement, the order from the center towards the margin being alkali-feldspar granite, syenogranite, monzogranite, quartz monzonite, quartz syenite, alkali-feldspar, quartz syenite, syenite and alkali-feldspar syenite. Anomalously high Cu, As, Sn, S, K₂O and Na₂O contents have been found at the eastern margin of the batholith in a N—S-trending zone, which is characterized by hydrothermal alteration phenomena, propylitization, tourmalinization and scapolitization. Three anomalous areas have been defined within this zone, one of them is associated with the Ylöjärvi deposit and the other two are regarded as exploration targets.     

The GEOMON network of Czech catchments provides long-term insights into altered forest biogeochemistry: From acid atmospheric deposition to climate change

In 1994, a network of small catchments (GEOMON) was established in the Czech Republic to determine input–output element fluxes in semi-natural forest ecosystems recovering from anthropogenic acidification. The network consists from 16 catchments and the primary observations of elements fluxes were complemented by monitoring of biomass stock, element pools in soil and vegetation, and the main water balance components. Over last three decades, reductions of SO₂, NO_x and NH₃ emissions were followed by sulphur (S) and nitrogen (N) deposition reductions of 75% and 30%, respectively. Steeper declines of strong acid anion concentrations compared to cations (Ca, Mg, Na, K, NH₄) in precipitation resulted in precipitation pH increase from 4.5 to 5.2 in bulk precipitation and from 4.0 to 5.1 in spruce throughfall. Stream chemistry responded to changes in deposition: S leaching declined. However at majority of catchments soils acted as a net source of S to runoff, delaying recovery. Stream pH increased at acidic streams (pH < 6) and aluminium concentration decreased. Stream nitrate (NO₃) concentration declined by 60%, considerably more than N deposition. Stream NO₃ concentration was tightly positively related to stream total dissolved nitrogen to total phosphorus (P) ratio, suggesting the role of P availability on N retention. Trends in dissolved organic carbon fluxes responded to both acidification recovery and to runoff temporal variation. An exceptional drought occurred between 2014 and 2019. Over this recent period, streamflow decreased by ≈ 40% on average compared to 1990s, due to the increases of soil evaporation and vegetation transpiration by ≈ 30% and declines in precipitation by ≈ 15% on average across the elevational gradient. Sharp decreases of stream runoff at catchments <650 m a.s.l. corresponded to areas of recent forest decline caused by bark beetle infestation on drought stressed spruce forests. Understanding of the interactions among legacies of acidification and eutrophication, drought effects on the water cycle and forest disturbance dynamics is requisite for effective management of forested ecosystems under anthropogenic influence.