Geochemical exploration of a Precambrian Batholith, source of a Cu-W mineralization of the tourmaline breccia in Southern Finland

The Hämeenkyrö batholith is a round-shaped plutonic body of an areal size of 147 km². It is composed of calc-alkaline to alkaline rocks that intruded previously metamorphosed Svecofennian volcanogenic and sedimentary schists 1860 Ma ago. The Cu-W bearing tourmaline breccia of the Ylörvi deposit occurs in metavolcanic rocks close to the eastern contact of the batholith.The average sampling density in the batholith was 1 sample per km², and 175 samples were analyzed for Cu, Au, Ag, Ni, Pb, Co, Zn, S by AAS for SiO₂, TiO₂, Al₂O₃, FeO, MnO, MgO, CaO, Na₂O, K₂O, As, Sn and P by X-ray fluorescence. Mo and W were determined colorimetrically. Barth mesonorms were calculated for each sample and the rock type was determined according to Streckeisen's classification. Element distributions are displayed on contour maps.The rock types of the batholith exhibit an asymmetric concentric arrangement, the order from the center towards the margin being alkali-feldspar granite, syenogranite, monzogranite, quartz monzonite, quartz syenite, alkali-feldspar, quartz syenite, syenite and alkali-feldspar syenite. Anomalously high Cu, As, Sn, S, K₂O and Na₂O contents have been found at the eastern margin of the batholith in a N—S-trending zone, which is characterized by hydrothermal alteration phenomena, propylitization, tourmalinization and scapolitization. Three anomalous areas have been defined within this zone, one of them is associated with the Ylöjärvi deposit and the other two are regarded as exploration targets.     

Construction of three-phase data to model multiphase flow in porous media: Comparing an optimization approach to the finite element approach

Multiphase flow modelling is a major issue in the assessment of groundwater pollution. Three-phase flows are commonly governed by mathematical models that associate a pressure equation with two saturation equations. These equations involve a number of secondary variables that reflect the fluid behaviour in a porous medium. To improve the computational efficiency of multiphase flow simulators, several simplified reformulations of three-phase flow equations have been proposed. However, they require the construction of new secondary variables adapted to the reformulated flow equations. In this article, two different approaches are compared to quantify these variables. A numerical example is given for a typical fine sand.     

On the inclusion of ground-based gravity measurements to the calibration process of a global rainfall-discharge reservoir model: case of the Durzon karst system (Larzac, southern France)

This work examines the relevance of the inclusion of ground-based gravity data in the calibration process of a global rainfall-discharge reservoir model. The analysis is performed for the Durzon karst system (Larzac, France). The first part of the study focuses on the hydrological interpretation of the ground-based gravity measurements. The second part of the study investigates further the information content of the gravity data with respect to water storage dynamics modelling. The gravity-derived information is found unable to either reduce equifinality of the single-objective, discharge-based model calibration process or enhance model performance through assimilation.     

Sites occupancy of Fe3+ in Garfield Nontronite: A spectroscopic study

New data on the structure of Garfield nontronite have been produced by the use of different spectroscopic techniques: Mössbauer spectroscopy, optical spectroscopy, X-ray absorption edges and EXAFS and NMR. The tetrahedral iron content is found to be no higher than 1 percent. All iron atoms belong to the octahedral sheet excluding the possibility of the presence of non crystallized phases. Some ambiguities remain about the coherence of the octahedral sheet because of the presence of two doublets in the Mössbauer spectrum and at least two lineshapes in NMR spectra of OH which correspond to different environments.