Intimate Distance: The Unconscious Dimensions of the Rapport Between Researcher and Researched

To explore how psychoanalysis might contribute to the methodology of human geography, this article returns to Freud's experiences of psycho-logical analysis before he develops psychoanalysis as a distinct understanding of the mind, identity formation, and subjectivity. Going back over the early history of psychoanalysis, Freud's psychoanalysis can be seen as an attempt to solve a set of problems inherent in late nineteenth-century psycho-logical analysis. Thus, it is possible to cast his methodological solutions in a new light. In particular, this article explores the problems associated with the unconscious rapport that developed in the therapeutic use of hypnotism in the cure of hysterical symptoms, for both doctor and patient. Freud's techniques can be seen as a way to produce an appropriate detachment—or intimate distance—between himself and his clients. This intimate distance is instructive. As a corrective to certain trajectories within human geography, this article identifies five methodological propositions that might inform future research.     

Reconstructing epilimnetic total phosphorus using diatoms: statistical and ecological constraints

Diatoms respond rapidly to eutrophication and diatom-based models for inferring total phosphorus (TP) have found wide application in palaeolimnology, especially in tracking trajectories of past and recent nutrient enrichment and in establishing pre-disturbance targets for restoration. Using new analysis of existing training sets and sediment-cores we examine the statistical and ecological constraints of diatom-inferred TP (DI-TP) models. Although the models show an apparently strong relationship between measured and inferred TP in the training sets, even under cross-validation, the models display three fundamental weaknesses, namely (1) the relationship between TP and diatom relative abundance is heavily confounded with secondary variables such as alkalinity and lake depth, (2) the models contain many taxa that are not significantly related to TP, and (3) comparison between different models shows poor or no spatial replicability. At some sites the sediment-core diatom assemblage change tracks the TP gradient in the training sets and DI-TP reconstructions are consistent with monitored TP data and known catchment histories for the recent past. At others diatom species turnover is apparently related to variables other than TP, and DI-TP fails to even reproduce plausible trends. Pre-disturbance DI-TP values are also questionable at most sites. We argue that these problems pervade many DI-TP models, particularly those where violations of the basic assumptions of the transfer function approach are ignored.     

A late Pleistocene human presence at Huaca Prieta,Peru, and early Pacific Coastal adaptations

Archaeological excavations in deep pre-mound levels at Huaca Prieta in northern Peru have yielded new evidence of late Pleistocene cultural deposits that shed insights into the early human occupation of the Pacific coast of South America. Radiocarbon dates place this occupation between ~ 14,200 and 13,300 cal yr BP. The cultural evidence shares certain basic technological and subsistence traits, including maritime resources and simple flake tools, with previously discovered late Pleistocene sites along the Pacific coast of Peru and Chile. The results help to expand our knowledge of early maritime societies and human adaption to changing coastal environments.     

Updating the Phase 1 habitat map of Wales, UK, using satellite sensor data

The Phase 1 Survey is the most comprehensive and widely used national level map of semi-natural habitats in Wales. However, the survey was based largely on field survey and was conducted over several decades, before being completed in 1997. Given that resources for a repeat survey were limited, this study has used an object-orientated rule-based classification implemented within eCognition of multi-temporal satellite sensor data acquired between 2003 and 2006 to map semi-natural habitats and agricultural land across Wales, thereby allowing a progressive update of the Phase 1 Survey. The classification of objects to Phase 1 habitat classes was undertaken in two steps; firstly the landscape of Wales was divided into objects using orthorectified SPOT-5 High Resolution Geometric (HRG) reflectance data (10 m spatial resolution) and Land Parcel Information System (LPIS) boundaries. A rule-base was then developed to progressively discriminate and map the distribution of 105 sub-habitats across Wales based on time-series of SPOT HRG, Terra-1 Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Indian Remote Sensing Satellite (IRS) LISS-3 data, derived datasets (e.g., vegetation indices, fractional images) and ancillary information (e.g., topography). The rules coupled knowledge of ecology and the information content of these remote sensing data using a combination of thresholds, Boolean operations and fuzzy membership functions. A second rule-base was then developed to translate the more detailed sub-habitat classification to Phase 1 habitat classes. Indicative accuracies of the revised Phase 1 mapping, based on comparisons with the later Phase 2 survey (for selected habitats), were >80% overall and typically between 70% and 90% for many classes. Through this exercise, Wales has become the first country in Europe to produce a national map of habitats (as opposed to land cover) through object-orientated classification of satellite sensor data. Furthermore, the approach can be adapted to allow continual monitoring of the extent and condition of habitats and agricultural land.     

Changes in Arctic clouds during intervals of rapid sea ice loss

We investigate the behavior of clouds during rapid sea ice loss events (RILEs) in the Arctic, as simulated by multiple ensemble projections of the 21st century in the Community Climate System Model (CCSM3). Trends in cloud properties and sea ice coverage during RILEs are compared with their secular trends between 2000 and 2049 during summer, autumn, and winter. The results suggest that clouds promote abrupt Arctic climate change during RILEs through increased (decreased) cloudiness in autumn (summer) relative to the changes over the first half of the 21st century. The trends in cloud characteristics (cloud amount, water content, and radiative forcing) during RILEs are most strongly and consistently an amplifying effect during autumn, the season in which RILEs account for the majority of the secular trends. The total cloud trends in every season are primarily due to low clouds, which show a more robust response than middle and high clouds across RILEs. Lead-lag correlations of monthly sea ice concentration and cloud cover during autumn reveal that the relationship between less ice and more clouds is enhanced during RILEs, but there is no evidence that either variable is leading the other. Given that Arctic cloud projections in CCSM3 are similar to those from other state-of-the-art GCMs and that observations show increased autumn cloudiness associated with the extreme 2007 and 2008 sea ice minima, this study suggests that the rapidly declining Arctic sea ice will be accentuated by changes in polar clouds.     

Contrasting isotopic signatures between anthropogenic and geogenic Zn and evidence for post-depositional fractionation processes in smelter-impacted soils from Northern France

Zinc isotopes have been studied along two smelter-impacted soil profiles sampled near one of the largest Pb and Zn processing plants in Europe located in northern France, about 50 km south of Lille. Mean δ⁶⁶Zn values along these two soil profiles range from +0.22 ± 0.17‰ (2σ) to +0.34 ± 0.17‰ (2σ) at the lowest horizons and from +0.38 ± 0.45‰ (2σ) to +0.76 ± 0.14‰ (2σ) near the surface. The δ⁶⁶Zn values in the lowest horizons of the soils are interpreted as being representative of the local geochemical background (mean value +0.31 ± 0.38‰), whereas heavier δ⁶⁶Zn values near the surface of the two soils are related to anthropogenic Zn. This anthropogenic Zn occurs in the form of franklinite (ZnFe₂O₄)-bearing slag grains originating from processing wastes at the smelter site and exhibiting δ⁶⁶Zn values of +0.81 ± 0.20‰ (2σ). The presence of franklinite is indicated by EXAFS analysis of the topsoil samples from both soil profiles as well as by micro-XANES analysis of the surface horizon of a third smelter-impacted soil from a distant site. These results indicate that naturally occurring Zn and smelter-derived Zn exhibit significantly different δ⁶⁶Zn values, which suggests that zinc isotopes can be used to distinguish between geogenic and anthropogenic sources of Zn in smelter-impacted soils. In addition to a possible influence of additional past sources of light Zn (likely Zn-sulfides and Zn-sulfates directly emitted by the smelter), the light δ⁶⁶Zn values in the surface horizons compared to smelter-derived slag materials are interpreted as resulting mainly from fractionation processes associated with biotic and/or abiotic pedological processes (Zn-bearing mineral precipitation, Zn complexation by organic matter, and plant uptake of Zn). This conclusion emphasizes the need for additional Zn isotopic studies before being able to use Zn isotopes to trace sources and pathways of this element in surface environments.     

A lacustrine GDGT-temperature calibration from the Scandinavian Arctic to Antarctic: Renewed potential for the application of GDGT-paleothermometry in lakes

Quantitative climate reconstructions are fundamental to understand long-term trends in natural climate variability and to test climate models used to predict future climate change. Recent advances in molecular geochemistry have led to calibrations using glycerol dialkyl glycerol tetraethers (GDGTs), a group of temperature-sensitive membrane lipids found in Archaea and bacteria. GDGTs have been used to construct temperature indices for oceans (TEX₈₆ index) and soils (MBT/CBT index). The aim of this study is to examine GDGT-temperature relationships and assess the potential of constructing a GDGT-based palaeo-thermometer for lakes. We examine GDGT-temperature relationships using core top sediments from 90 lakes across a north-south transect from the Scandinavian Arctic to Antarctica including sites from Finland, Sweden, Siberia, the UK, Austria, Turkey, Ethiopia, Uganda, Chile, South Georgia and the Antarctic Peninsula. We examine a suite of 15 GDGTs, including compounds used in the TEX₈₆ and MBT/CBT indices and reflecting the broad range of GDGT inputs to small lake systems.GDGTs are present in varying proportions in all lakes examined. The TEX₈₆ index is not applicable to our sites because of the large relative proportions of soil derived and methanogenic components. Similarly, the MBT/CBT index is also not applicable and predicts temperatures considerably lower than those measured. We examine relationships between individual GDGT compounds and temperature, pH, conductivity and water depth. Temperature accounts for a large and statistically independent fraction of variation in branched GDGT composition. We propose a GDGT-temperature regression model with high accuracy and precision (R² = 0.88; RMSE = 2.0 °C; RMSEP = 2.1 °C) for use in lakes based on a subset of branched GDGT compounds and highlight the potential of this new method for reconstructing past temperatures using lake sediments.     

Contact angles in CO2-water-coal systems at elevated pressures

Injection of carbon dioxide into coal seams is considered to be a potential method for its sequestration away from the atmosphere. However, water present in coals may retard injection: especially if carbon dioxide does not wet the coal as well as water. Thus contact angles in the coal-water-CO₂ system were measured using CO₂ bubbles in water/coal systems at 40 °C and pressures up to 15 MPa using five bituminous coals. At low pressures, in this CO₂/water/coal system, receding contact angles for the coals ranged between 80° to 100°; except for one coal that had both high ash yield and low rank, with a contact angle of 115°, indicating that it was hydrophilic. With increasing pressure, the receding contact angles for the different coals decreased, indicating that they became more CO₂-wetting. The relationship between contact angle and pressure was approximately linear. For low ash or high rank coals, at high pressure the contact angle was reduced to 30-50°, indicating the coals became strongly CO₂-wetting; that is CO₂ fluids will spontaneously penetrate these wet coals. In the case of the coal that was both high ash and hydrophilic, the contact angle did not drop to 90° even at the highest pressures used. These results suggest that CO₂ will not be efficiently adsorbed by all wet coals equally well, even at high pressure. It was found that at high pressures (> 2 MPa) the rate of penetration of carbon dioxide into the coals increased rapidly with decreasing contact angle, independently of pressure. Injecting CO₂ into wet coals that have both low rank and high ash will not trap CO₂ as well as injecting it into high rank or low ash coals.     

Using FTIR spectroscopy to characterise the soil mineralogy and geochemistry of cryoconite from Aldegondabreen glacier,Svalbard

Mineralogical and geochemical diversity in cryoconite granules from Aldegondabreen glacier was investigated using FTIR spectroscopy. Results suggest that the technique is an effective tool for investigating mineralogy and identifying spatial differences in geochemistry, based upon characteristic spectral signatures.