氯化铁对磷酸铁锂中锂浸出性能研究

随着新能源电动汽车的发展,磷酸铁锂(LiFePO₄,LFP)电池的报废量逐年剧增,由于其有价金属锂含量低,回收经济性差,近年来废旧LFP的低成本回收成为研究热点。基于同构诱导置换浸出,以FeCl₃为浸出剂,在固-液反应体系中探究了FeCl₃对LFP中的锂浸出的影响因素,利用未反应核收缩模型探究了两个浸出阶段的宏观动力学。结果表明,增大FeCl₃/LFP摩尔比、减小固液比和升高反应温度可以显著促进锂的浸出;在浸出前4 min内,锂浸出速率主要受固态产物层内扩散过程控制,表观活化能为6.68 kJ/mol; 4 min后锂浸出速率受流体膜外扩散、产物层内扩散和化学反应混合机制的控制。     

镁源种类对制备碱式硼酸镁的影响

采用MgO、MgCl_2·6H_2O和Mg(NO_3)_2·6H_2O为原料,通过XRD、SEM、FTIR等测试方法,研究不同镁源对碱式硼酸镁形貌和组成的影响。在190℃条件下反应10 h,制备碱式硼酸镁(MgBO_2(OH))。结果表明,以MgO为反应物时,由于其反应活性较差,导致产物中出现大量氢氧化镁杂质;以MgCl_2·6H_2O为反应物时,所得产物长径比较小;以Mg(NO_3)_2·6H_2O为反应物时,得到分散性高、形貌规整的棒状产物。     

热电离质谱法测定锂同位素的研究进展

锂的两种稳定同位素6Li和7Li存在很大的相对质量差,质量分馏效应十分明显,因此要精确地测定锂同位素比值十分困难。近年来,随着质谱测定方法的发展,锂同位素的测定取得了长足进展。目前,使用热电离质谱仪(TIMS)和多接受电感耦合等离子质谱仪(MC-ICP-MS)测定锂同位素比值的较多。TIMS相比于MC-ICP-MS,其测定精度较高。主要对使用热电离质谱仪(TIMS)测定锂同位素进行了详细的介绍,主要包括带材料和带结构、涂样形式以及电离温度这3方面的研究进展,并指出了此方法存在的一些问题。     

贵州铜仁塘边铅锌矿矿床地质特征及成矿物质来源

<正>塘边铅锌矿床位于铜仁市西南约10 km,是笔者所在"湖南新晃-贵州铜仁地区矿产远景调查"项目组在项目实施过程中新发现的,初步估算规模可达中型以上。矿区赋矿地层为清虚洞组(C1q)第三段厚层块状细-粉晶藻灰岩。主要金属矿物方铅矿、闪锌矿、黄铁矿及少量胶黄铁矿,其中方铅矿以细脉状、团块状产于灰岩中,亦有呈团块状分布于方解石中,闪锌     

沼泽湿地生态储水量及生态需水量计算方法

As one of the most typical wetlands, marsh plays an important role in hydrological and economic aspects, especially in keeping biological diversity. In this study, the definition and connotation of the ecological water storage of marsh is discussed for the first time, and its distinction and relationship with ecological water requirement are also analyzed. Furthermore, the gist and method of calculating ecological water storage and ecological water requirement have been provided, and Momoge wetland has been given as an example of calculation of the two variables. Ecological water use of marsh can be ascertained according to ecological water storage and ecological water requirement. For reasonably spatial and temporal varia-tion of water storage and rational water resources planning, the suitable quantity of water supply to marsh can be calculated according to the hydrological conditions, ecological de-mand and actual water resources.     

TMPA降水数据在澜沧江流域干旱监测中的评估(英文)

Drought is one of the most destructive disasters in the Lancang River Basin, which is an ungauged basin with strong heterogeneity on terrain and climate. Our validation suggested the version-6 monthly TRMM multi-satellite precipitation analysis (TMPA; 3B43 V.6) product during the period 1998 to 2009 is an alternative precipitation data source with good accuracy. By using the standard precipitation index (SPI), at the grid point (0.25°×0.25°) and sub-basin spatial scales, this work assessed the effectiveness of TMPA in drought monitoring during the period 1998 to 2009 at the 1-month scale and 3-months scale; validated the monitoring accuracy of TMPA for two severe droughts happened in 2006 and 2009, respectively. Some conclusions are drawn as follows. (1) At the grid point spatial scale, in comparison with the monitoring results between rain gauges (SPI1g) and TMPA grid (SPI1s), both agreed well at the 1-month scale for most of the grid points and those grid points with the lowest critical success index (CSI) are distributed in the middle stream of the Lancang River Basin. (2) The same as SPI1s, the consistency between SPI3s and SPI3g is good for most of the grid points at the 3-months scale, those grid points with the lowest were concentrated in the middle stream and downstream of the Lancang River Basin. (3) At the 1-month scale and 3-months scale, CSI ranged from 50% to 76% for most of the grid points, which demonstrated high accuracy of TMPA in drought monitoring. (4) At the 3-months scale, based on TMPA basin-wide precipitation estimates, though we tended to overestimate (underestimate) the peaks of dry or wet events, SPI3s detected successfully the occurrence of them over the five sub-basins at the most time and captured the occurrence and development of the two severe droughts happened in 2006 and 2009. This analysis shows that TMPA has the potential for drought monitoring in data-sparse regions.     

鄂西震旦系灯影组白鸡河锌矿床地质特征及成因探讨

在鄂西震旦系白云岩地层中,新发现了白鸡河锌矿床、凹子岗铅锌矿床、冰洞山铅锌矿床。白鸡河锌矿床矿石成分简单,富锌贫铅;矿石结构主要为细晶结构、交代结构;矿石构造变化大,存在角砾状、浸染状、纹层状、条带状及"雪顶"构造;成矿温度低,白云石化交代角砾岩作用普遍;矿石硫同位素为重硫,值域很宽,闪锌矿与方铅矿在相对封闭环境沉淀。矿床地质特征可与MVT型铅锌矿床相类比,成因为碳酸盐岩容矿的后生沉积铅锌矿床。     

西藏西南部休古嘎布蛇绿岩的成因:岩石学和地球化学证据

休古嘎布蛇绿岩块位于雅鲁藏布缝合带(YZSZ)西段,主要由地幔橄榄岩和侵入其中的基性岩墙所组成。基性岩墙具有弧后盆地地球化学亲缘性,其LREE亏损,(La/Yb)N为0.39~0.55;具有明显的Nb、Ti负异常及Sr、Ba正异常。Sr、Nd同位素特征表明它们起源于亏损地幔,并且受到了板片析出流体的影响。4个基性岩墙的Sm-Nd同位素样品获得内部等时线年龄为126.2±9.1Ma(MSWD=0.44)。地幔橄榄岩具有汤勺形和U形两组REE分布型式,显示出不同程度部分熔融和地幔交代作用的特征,具有弧-盆体系地球化学亲缘性。第一组橄榄岩的LREE弱富集或近于平坦,尖晶石的Cr#值低而且变化不大,部分熔融程度较低(15%~20%),可能形成于弧后扩张盆地;第二组橄榄岩的LREE明显富集,尖晶石的Cr#值高而且变化较大(0.4~0.77),部分熔融程度较高(25%~30%),并经历了强烈的交代富集作用,可能与洋内岛弧有关。     

A Review of Ocean-Atmosphere Interaction Studies in China

A large number of papers have been published and great efforts have been made in the recent 20 years by the Chinese oceanographic and meteorological scientists in the ocean-atmosphere interaction studies. The present paper is an overview of the major achievements made by Chinese scientists aad their collaborators in studies of larger scale ocean-atmosphere interaction in the following oceans： the South China Sea, the Tropical Pacific, the indian Ocean and the North Pacific. Many interesting phenomena and dynamic mechanisms have been discovered and studied in these papers. These achievements have improved our understanding of climate variability and have great implications in climate prediction, and thus are highly relevant to the ongoing international Climate Variability and Predictability （CLIVAR） efforts.     

遥感水文应用中的尺度问题

遥感技术在水文科学中的广泛应用，极大地拓宽了其研究的领域和范围，增加了其研究的深度。但同时也应该看到，遥感信息的空间分辨率和时间分辨率，以及水文科学自身尺度问题的复杂性，一方面对遥感水文的应用产生困难和问题，限制了水文遥感的应用；另一方面又对水文尺度问题提供了新的技术手段，为遥感水文应用增添了新的亮点。从水文机理与空间尺度、遥感信息的空间分辨率、水文参数的空间延拓，以及遥感技术与水文科学的发展等 4个方面探讨了遥感水文的空间尺度问题；从瞬时遥感信息的时间拓展和遥感信息的时间分辨率 2个方面讨论了遥感水文的时间尺度问题。