铁同位素的MC-ICP-MS测定方法与地质标准物质的铁同位素组成

详细报道了在低分辨和高分辨模式下运用MC-ICP-MS进行Fe同位素比值高精度测试的方法,对Fe同位素测定过程中谱峰干扰、基质效应、浓度效应、仪器测试的长期重现性等问题进行了评估,并对两种运行模式的测试结果进行了对比.在95%的可信度范围内,所建方法的外部精度优于0.5ε/ainu,达到国际同类实验室的先进水平,并且低分辨和高分辨两种模式下获得的Fe同位素测试结果是一致的.在此基础上对国家地质标准物质GBW07105(玄武岩)和GBW 07111(花岗闪长岩)进行了Fe同位素测定.相对于Fe同位素国际标样IRMM-014,GBW07105的Fe同位素成分为:ε57Fe=1.9±0.3(20),ε56Fe=1.3±0.2(2σ),ε57/56Fe=0.6±0.1(2σ);GBW 07111的Fe同位素成分为:ε57Fe=1.8±0.4(2σ),ε56Fe=1.2±0.2(2σ),ε57/56Fe=0.6±0.1(2σ).     

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Numerical Experiment on Two-Dimensional Line Thermal

The time evolution of a two-dimensional line thermal-a turbulent flow produced by an initial element with signifi-cant buoyancy released in a large water body, is numerically studied with the two-equation k - e model for turbulence closure. The numerical results show that the thermal is characterized by a vortex pair flow and a kidney shaped concentra-tion structure with double peak maxima; the computed flow details and scalar mixing characteristics can be described by self-similar relations beyond a dimensionless time around 10. There are two regions in the flow field of a line thermal: a mixing region where the concentration of tracer fluid is high and the flow is turbulent and rotational with a pair of vortex eyes, and an ambient region where the concentration is zero and the flow is potential and well-described by a model of doublet with strength very close to those given by early experimental and analytical studies. The added virtual mass coeffi-cient of the thermal motion is found to be approximat     

影响西太平洋台风形成的大尺度环流条件

根据全球热带气旋频率的统计[1],这些频率有明显的年际变化。在过去二十年中全球热带气旋数年变化的百分率为其平均数的-13%-+23%,最多和最少年热带气旋数差达28个,相当于全球年平均热带气旋数(79)的35%。目前认为有三个原因可能影响热带气旋频率:大尺度环流,海面温度和地球以外的因子。     

黄河口水下底坡微地貌及其成因探讨

高分辨率的回声测深、旁侧声纳及浅地层剖面记录首次直观地揭示了黄河口水下底坡上发育有大量形态不同的微地貌类型。据其形态特征和规模的差异,将它们划分为平滑海底、凹坑与洼地、冲沟、残留岗丘及扰动复合海底等五种类型。这些微地貌分布在不同水深条件下的不同水下三角洲单元上,并存在着相互联系和相互转化。黄河口海域特殊的沉积环境和复杂的动力条件是导致水下底坡微地貌形成发育的主要机制。     

测定陆架区海洋沉积物中细粒分散状金的分选方法

为了制定分异堆积机制．以及开发和加工陆架上细粒分散状金，必须有关于该金属在河-海壁垒区迁移形态的资料．在一系列文章中刊登了有关较高的金含量趋向于有机质高浓度区的论述．其中有细粒金在陆架区河口边缘部分高度分散的生物成因粉砂质软泥中富集实际资料的描述，     

Underwater sounds near a fuel receiving facility in western Hong Kong: relevance to dolphins

Western Hong Kong is home to two species of marine mammals: Indo-Pacific humpbacked dolphins (Sousa chinensis) and finless porpoises (Neophocaena phocaenoides). Both are threatened in many parts of their range in southeast Asia [for example, International Biological Research Institute Reports 9 (1997), 41; Asian Marine Biology 14 (1997) 111]. In 1998, when the new Hong Kong International Airport opened in western Hong Kong, small tankers (about 100 m long, cargo capacity about 6300 metric tons) began delivering fuel to the Aviation Fuel Receiving Facility (AFRF) just off Sha Chau Island, north of the airport. Calibrated sound recordings were taken over a 4-day period from a quiet, anchored boat at distances 80-2000 m from aviation fuel delivery activities at the AFRF. From the recordings, 143 sections were selected for analysis. Narrowband spectral densities on the sound pressures were computed, and one-third octave band levels were derived for center frequencies from 10 to 16,000 Hz. Broadband levels, viz. 10-20,000 Hz. were also computed. The results showed that the Sha Chau area is normally noisy underwater, with the lowest broadband levels measured corresponding to those expected during a storm at sea (sea state 6). This background noise is believed to come largely from heavy vessel traffic in the Urmston Road to the north and east of Sha Chau and from vessels in the Pearl River Estuary to the West. The sound levels from the AFRF tankers are comparable to the levels measured from similar- and smaller-sized supply vessels supporting offshore oil exploration. The strongest sounds recorded were from a tanker leaving the AFRF at distance 100 m from the hydrophone, for which the one-third octave band level at 100 Hz was 141 dB re 1 microPa (spectrum level 127 dB re 1 microPa2/Hz) and the 10-20,000 Hz broadband level was 146 dB. At distances of 100 m or more and frequencies above 300 Hz, the one-third octave band levels were less than 130 dB (spectrum level 111 dB re 1 microPa2/Hz) and decreased with increasing frequency and distance. At distances greater than about 500 m, AFRF-associated sounds were negligible, masked by the generally high noise level of the area and attenuated by poor transmission in the very shallow water (<10 m). Because it is believed that humpbacked dolphins and finless porpoises are not very sensitive to sounds below 300 Hz, the Airport Authority Hong Kong (AA) stipulated that dedicated terminal vessels not radiate underwater sounds at spectrum levels greater than 110 dB re 1 microPa2/Hz at frequencies above 300 Hz and distances greater than 300 m. The spectrum levels at 300 Hz and higher frequencies of sounds from the tankers arriving, departing, or off-loading at AFRF were less than 110 dB re 1 microPa2/Hz even at distances of 200 m or less. The AA stipulation was met. However, it is presently unknown whether the generally strong noise levels of western Hong Kong inhibit acoustically based feeding and communication, or result in increased stress or permanent shifts in hearing thresholds.     

Relationships between chlorophyll a, bacteria, ATP, POC and respiration rates in the Changjiang Estuary and the plume

Bacteria abundance, chlorophyll a, ATP and POC concentrations and respiration rates of microorganisms in the Changjiang Estuary and the plume were determined in July 1986. The high values of bacteria abundance occurred in the river mouth in association with suspended matter. It is assumed that bacteria were the major contributor to ATP and the main consumer of dissolved oxygen, and that the relationship between ATP and POC was present in that area. In the dilution zone (salinity; 25-30), instead of bacteria, phytoplankton was the major contributor to ATP and respiration rates, due to diatom bloom. Close relationships between Chi a and ATP, and ATP and POC were observed. Contribution of microbial carbon to POC was also estimated.