Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.     

浅覆盖区土壤化学成分与基岩化学成分的关系及其意义——以大兴安岭北部地区为例

以大兴安岭北部地区为例，研究了浅覆盖区土壤与基岩化学成分的关系。指出浅覆盖区残积型土壤主要造岩元素组合继承了基岩元素组合特征；在岩石风化成土过程中，元素再分配和迁移使土壤中大多数元素（氧化物）含量产生明显的“均一化”。在此基础上，对土壤地球化学异常的识别与评价问题进行了讨论并提出了建议。     

青海湖地区生态环境动态变化遥感监测

由于青海湖地区的生态环境较为脆弱，且人类活动进一步加剧，人口、资源与环境的矛盾日渐突出，因此，近年来．青海湖及其周边地区的生态环境出现了明显变化，主要表现在水位下降及水域面积减小、草原退化、沙质荒漠化土地面积扩大等。文章采用1975年MSS卫星图像及1987、2000年TM卫星图像作为遥感信息源，并结合地理信息系统方法，旨在查明青海满地区耕地、沙质荒漠化土地和水域等生态环境要素的时空演化规律，为青海湖地区实现资源开发与环境协调发展提供科学依据。监测结果表明，25a来，青海湖地区的耕地及沙质荒漠化土地面积出现明显的扩大，而水域面积出现明显缩小，同时由于湖周各河流土壤侵蚀的加剧，在部分河流入湖处泥沙淤积较为严重，生态环境出现明显恶化。     

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。     

非海相沉积层序的成因和构型特征

根据东部盆地的地质、地球物理特征,初步对非海相层序地层学应用研究进行了总结.非海相沉积层序的形成要素,既有外旋回、又有自旋回,构造和气候因素很重要,强调了环境因素.沉积基准面在海上为海平面,在陆上为潜水面、湖平面、河流平衡剖面.相对基准面的周期性变化引起了可容纳空间的周期性变化,并由之形成了一系列旋回式的层序.大多数情况下内陆基准面的变化不受海平面变化的控制,在全球最大海泛期有某种联系.湖盆小而沉积速率高,形成层序的频率高于海相.以沾化凹陷为依据,提出了5种层序构型特征:冲积-河湖型,(半)盐湖-淡水湖泊过渡型,海流-深湖型,半深湖-缓坡型,河流-冲积平原型.在盆地主要发育期,断阶式坡折对沉积体系有明显的控制作用.除低水位扇外,低水位楔是构成隐蔽圈闭或复合圈闭的有利场所。     

粉喷桩技术加固软土地基

简介了水泥粉体喷射搅拌加固软土地基的工作机理,结合沪蓉高速公路(沪宁段)地基处理实践,论述了粉喷桩加固软土地基的计算方法.采用粉喷桩加固软基,可加快路堤填土速率,铺筑路面后的工后沉降量能得到有效地控制,保证了工程质量.     

柴北缘绿梁山地区辉长岩的锆石U-Pb年龄及意义

柴达木盆地北缘绿梁山地区的辉长岩侵入到古生代滩间山群及超基性岩中 ,地球化学、微量元素、稀土元素显示出源幔特征。选自其中的锆石明显具岩浆型锆石特点 ,4个单颗粒锆石U -Pb同位素年龄均为谐和年龄 ,2 0 6 Pb 2 38U表面年龄统计权重平均值为 (496 .3± 6 .2 )Ma ,代表了该岩体的结晶年龄 ,从而间接地否定了本区滩间山群的时代为晚奥陶世 -志留纪的认识。辉长岩与滩间山群是柴北缘活动大陆边缘火山岛弧的组成部分。此类岩体同位素地质年龄的确定对柴北缘榴辉岩、滩间山群时代及大地构造性质的重新认识具有重要意义     

新疆伽师及邻近地区现今地壳形变的GPS监测与研究

利用高精度数据软件对伽师及邻近地区的GPS监测网观测数据进行计算分析(基线精度达到了 10 - 8～ 10 - 9) ,获得了该地区的现今地壳形变速率图 .结果表明 ,伽师及邻近地区在印度板块的推挤作用下 ,地壳正快速缩短变形 ,主压应力为近南北方向 .各地块运动速率不同 ,平均应变率为 0 .0 4× 10 - 6 /a .