Structural Evolvement of Heating Treatment of Mg/Al-LDH and Preparation of Mineral Mesoporous Materials

Although hydrotalcite, or layered double hydroxides (LDHs), is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/Al-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of (Mg, Al)-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like (Mg, Al)-oxide is transformed into a composite with periclase (MgO) and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.     

山地大倾角地层三维地震资料处理研究

山地大倾角地层的三维地震资料处理的核心问题是如何解决3D反射面元发散，增加反射面元内道集同相叠加，而静校正技术和偏移成像技术正是解决这一问题的关键技术。以XJ区的三维地震勘探为例，对其资料进行综合静校正及叠前偏移成像技术处理，较好地解决了该区的地层构造成像和分辨率问题，保证了勘探精度。     

Rock Deformation, Component Migration and ^18O/^16O Variations during Mylonitization in the Southern Tan-Lu Fault Belt

This paper discusses the relationship between the volume loss, fluid flow and component variations in the ductile shear zone of the southern Tan-Lu fault belt. The results show that there is a large amount of fluids flowing through the shear zone during mylonitization, accompanied with the loss of volume of rocks and variations of elements and oxygen isotopes. The calculated temperature for mylonitization in different mylonites ranges from 446 to 484℃, corresponding to that of 475 to 500℃ for the wall rocks. The condition of differential stress during mylonization has been obtained between 99 and 210 MPa, whereas the differential stress in the wall rock gneiss is 70-78 MPa. The mylonites are enriched by factors of 1.32-1.87 in elements such as TiO2, P2O5, MnO, Y, Zr and V and depleted in SiO2, Na2O, K2O, Al203, Sr, Rb and light REEs compared to their protolith gneiss. The immobile element enrichments are attributed to enrichments in residual phases such as ilmentite, zircon, apatite and epidote in mylonites and are interpreted as due to volume losses from 15% to 60% in the ductile shear zone. The largest amount of SiO2 loss is 35.76 g/100 g in the ductile shear zone, which shows the fluid infiltration. Modeling calculated results of the fluid/rock ratio for the ductile shear zone range from 196 to 1192 by assuming different degrees of fluid saturation. Oxygen isotope changes of quartz and feldspar and the calculated fluid are corresponding to the variations of differential flow stress in the ductile shear zone. With increasing differential flow stress, the mylonites show a slight decrease of δ^18O in quartz, K-feldspar and fluid.     

^40 Ar/^39 Ar Dating of the Shaxi Porphyry Cu-Au Deposit in the Southern Tan-Lu Fault Zone, Anhui Province

Four samples of plagioclase and biotite from the Shaxi porphyry in the lower part of the Yangtze metallogenic belt were analyzed for age determination with the 40Ar/39Ar method. The results yield reproducible ages of 126 Ma to 135 Ma with a high level of confidence according to the agreement between isochron and plateau ages. The four Ar-Ar ages are relatively consistent within the analytical error. These ages are also consistent with, but more precise than, previous K-Ar and Rb-Sr ages and thus provide better constraints on the time of porphyry formation and associated Cu-Au mineralization along the middle to lower part of the Yangtze metaliogenic belt. The ages of 126 to 135 Ma are interpreted to represent the intrusive time of the Shaxi porphyry, so that the Cu-Au mineralization should have occurred later due to the post-magmatic hydrothermal event.     

SHRIMP U-Pb Zircon Age of the Ka''erjiao Intrusion in the Sawur Region in West Junggar,Xinjiang

Acid intrusions are widespread in the Sawur region, Xinjiang. The Ka'erjiao intrusion is mainly composed of albite granite porphyry, K-feldspar granite porphyry, ivernite and granite porphyry. Being a transitional product between magma intrusion and eruption in the Sawur region, the Ka'erjiao intrusion was formed at the telophase of the late Carboniferous to the begining of early Permian as determined by the SHRIMP U-Pb zircon dating, with an age of 302.6±7.6 Ma (1σ). The intrusion consists of alkali-enriched rock, whose REE distribution patterns are of the LREE enrichment type, theδEu value is low and Nd, Sr, Pb isotopes reflect its mantle source characteristics. Theδ18O value of intrusion is low as a result of isotope exchange with meteoric water. The geochemical characteristics show that it was formed in a post-collisional tectonic setting. Taking combined considerations of current studies of A-type granites and Permian volcanic rocks, we think that in the telophase of the late Carboniferous to the beginning of the early Permian, the Sawur region was within the extension or compressional to extensional period of a post-collisional stage. The Ka'erjiao intrusion from mantle sources can confirm the vertical continental crust growth in the late Paleozoic. The Sawur region in west Junggar is consistent with east Junggar in post-collisional tectonic evolution process.     

中国大陆西部及周边地区地震活动特征的研究

探讨了中国周缘板块的联合作用对中国大陆地震的控制和影响，进一步研究了中国大陆西部及周边地区的地震活动特征。结果发现，该区域的地震活动除了有高潮和低潮的轮回特征外，还有相互消长的关系，并且地震相互消长有一个特定的比例。这一特点，对于中国大陆强震活动主体区的预测，尤其是对地震高潮期的结束时间提供了一个判据。     

庐江台人工测氡与数字化自动测氡对比分析研究

以安徽庐江台观测资料为基础，分析数字化测氡与人工取样测氡结果的精度、相关性影响因素等。数字化测氡观测精度高，但受气温、气压影响较大；气氡与水氡资料动态特征有较大差异。数字化气氡值与人工测气氡、人工测水氡不相关。Rn气/Rn水与井水温成正比。由于数字化测氡观测时间较短，资料又非常有限，还缺少一定的震例，因此，在一定时间内数字化测氡与人工测水氡应同时进行。     

再论徐(州)-淮(南)推覆体

我们在1987年曾指出过徐州—淮南地区是一个由中—朝板块的古生代盖层组成的大型褶皱推覆体。最近我们经详细研究,认为它是由南段定远—淮南、中段小涧集、北段徐州到台儿庄的山系组成的一个半圆形造山带。根据影响这些地区的应变强度不同,该带可划分为南、北、中三段。最后讨论了该带动力学机制、构造过程及与邻区构造关系。     

The Late Proterozoic Continental Accretionary History of the Southeastern Margin of Jiangnania

The newly obtained Sm-Nd isochron ages are 1034 Ma and 935 Ma for ophiolites from northeasternJiangxi and Fuchuan, southern Anhui respectively. There exist two unconformity surfaces under the initialLate Proterozoic volcanics as well as the Sinian rocks. The Xiuning intrusive body which was intruded into theShangxi Group in southern Anhui yields a whole-rock Rb-Sr isochron age of 963 Ma. There occurs a belt ofLate Proterozoic calc-alkali volcanic rocks extending from northeastern Jiangxi to northwestern Zhejiang. Inthe light of the above facts, the authors consider that the southeastern margin of Jiangnania is an ancient islandarc. At about 1000 Ma ago, the Huanan (South China) oceanic crust was subducted along the line linking Dex-ing and Hangzhou, thus starting the accretion of the island arc system to Jiangnania. At 800 Ma ago Cathaysiaand Jiangnania converged together along the Jiangshan-Shaoxing line, marking the end of the accretion.     

濉溪铁铜矿床中磁铁矿的标型特征及其意义

本文论述了安徽省濉溪几个铁铜矿床中磁铁矿的地质产状、化学成分和物理性质。这些矿床位于中性浅成侵入岩体与含镁质较高的碳酸盐岩的接触带。磁铁矿以含MgO较高,Al_2O_3、TiO_2和V_2O_5偏低;MgO:Al_2O_3>>1为重要特征,Ni:Co=0.81,Ge含量很低,且Ga>>Ge。磁铁矿的物理性质与化学成分关系密切,即磁铁矿的显微硬度随混入组分TiO_2、Al_2O_3、MnO、MgO的含量增高而增大,随FeO的增高而减小,比重也有同样的趋势。磁铁矿的晶胞参数a随FeO的增高而增大,反射率随MgO的增高而降低。据此,我们初步认为,本区铁铜矿床应属接触交代型矿床。