Comparison of Kansas Data with High-resolution Large-eddy Simulation Fields

The surface layer of an atmospheric boundary layer (ABL) is most accessible to field measurements and hence its ensemble-mean structure has been well established. The Kansas field measurements were the first detailed study of this layer, providing numerous benchmark statistical profiles for a wide range of stability states. Large-eddy simulation (LES), in contrast, is most suitable for studying the mixed layer of the ABL where the energy-containing range of the vertical velocity field is well resolved. In the surface layer, typical large-eddy simulations barely resolve the energy-containing vertical-velocity fields and hence do not provide sufficient data for a detailed analysis.We carried out a nested-mesh simulation of a moderately convective ABL (-z_i/L = 8) in which the lower 6% of the boundary layer had an effective grid resolution of 512³. We analyze the LES fields above the 6th vertical grid level (z = 23 m) where the vertical velocity field has a well formed inertial subrange, for a detailed comparison with the Kansas results. Various terms in the budgets of turbulent kinetic energy, temperature variance, Reynolds stress, temperature flux, and some higher order moments are compared. The agreement is generally quite good; however, we do observe certain discrepancies, particularly in the terms involving pressure fluctuations.     

Coupling Between Seismic Activity and Hydrogeochemistry at the Shillong Plateau, Northeastern India

Transient hydrogeochemical anomalies were detected in a granite-hosted aquifer, which is located at a depth of 110 m, north of the Shillong Plateau, Assam, India, where groundwater chemistry is mainly buffered by feldspar alteration to kaolinite. Their onsets preceded moderate earthquakes on December 9, 2004 (M_W = 5.3) and February 15, 2005 (M_W = 5.0), respectively, 206 and 213 km from the aquifer. The ratios [Na+K]/Si, Na/K and [Na+K]/Ca, conductivity, alkalinity and chloride concentration began increasing 3–5 weeks before the M_W = 5.3 earthquake. By comparison with field, experimental and theoretical studies, we interpret a transient switchover between source aquifers, which induced an influx of groundwater from a second aquifer, where groundwater chemistry was dominantly buffered by the alteration of feldspar to smectite. This could have occurred in response to fracturing of a hydrological barrier. The ratio Ba/Sr began decreasing 3–6 days before the M_W = 5.0 earthquake. We interpret a transient switchover to anorthite dissolution caused by exposure of fresh plagioclase to groundwater interaction. This could have been induced by microfracturing, locally within the main aquifer. By comparison with experimental studies of feldspar dissolution, we interpret that hydrogeochemical recovery was facilitated by groundwater interaction and clay mineralization, which could have been coupled with fracture sealing. The coincidence in timing of these two hydrogeochemical events with the only two M_W ≥ 5 earthquakes in the study area argues in favor of cause-and-effect seismic-hydrogeochemical coupling. However, reasons for ambiguity include the lack of similar hydrogeochemical anomalies coupled with smaller seismic events near the monitoring station, the >200 km length scale of inferred seismic-hydrogeochemical coupling, and the potential for far-field effects related to the Great Sumatra–Andaman Islands Earthquake of December 26, 2004.     

Soilscapes,geomorphic processes and soil taxonomic new subgroups identified in the Ghaggar river basin of Haryana and Punjab

Soilscapes of the Ghaggar river basin falling in Haryana and Punjab were interpreted and studied by using the Landsat imagery and aerial photographs. Five major landform units identified and demarcated in the area were : channel courses, levees, flood-plains undulating, basinal floodplains and relict basins. On the basis of sedimentation, nature of the river pattern and soil characteristics, the whole basin was divided into three reaches — upper, middle and lower. Taxonomically the soils were placed under Typic Ustipsamments, Typic Ustorthents and lypic Ustifluvents on channel courses; Aquic Ustifluvents, Typic Ustifluvents and Typic Ustochrepts on levees; Fluventic Ustochrepts, Udic Ustochrepts and lypic Camborthids on floodplains undulating; Typic Ustorthents and Udic Ustochrepts on basinal floodplains; Typic Natrustalfs and Natric Camborthids on relict basins. Two new subgroups were proposed, i.e., Natric within the order of Entisol and Inceptisol, and Aquic-udic within the order of Inceptisol. Two dominant geomorphic processes were observed, i.e., fluvial and aeolian.     

Challenges to addressing non-CO2 greenhouse gases in China’s long-term climate strategy

Under the Paris Agreement, countries are encouraged to submit long-term low greenhouse gas emissions development strategies. Such strategies will merge emissions goals with socio-economic objectives and enable countries to increase their ambition over time, thus offering an opportunity to close the gap between the current emissions trajectory and the Agreement’s ‘well below 2°C’ target. China is in the process of preparing its own long-term strategy. We argue in this article that non-CO₂ greenhouse gases (NCGGs) should be an essential component of China’s long-term low-emissions strategy. To incorporate NCGGs into China’s long-term low-emissions development strategy, key scientific and institutional challenges should be addressed, such as uncertainty about the accuracy of NCGG emissions inventories; uncertainty about future projections of NCGG emissions; and institutional coordination deficits and imbalanced policy approaches. Overcoming these barriers will have significant implications for climate change mitigation and can open a path for the development of concrete follow-up actions.

Key policy insights

• Non-CO₂ greenhouse gases (NCGGs) make up around 17% of China’s GHG emissions, but China has no quantified target to limit or reduce these gases.

• NCGG emissions mitigation should be an essential component of China's long-term low-emissions strategy, which is currently under development.

• Considerable uncertainty exists over both historical NCGG emissions data and forecasts. This poses challenges to developing a comprehensive multi-gas strategy.

• Institutional challenges must also be addressed, such as fragmentation of responsibility for NCGGs.

     

Rapid Determination of Trace and Ultra Trace Level Elements in Diverse Silicate Rocks in Pressed Powder Pellet Targets by LA‐ICP‐MS using a Matrix‐Independent Protocol

A simple, single sample preparation involving pressed rock powder pellets was utilised to determine the trace and ultra trace abundances of petrogenetically important elements including high field‐strength elements and REEs by laser ablation‐ICP‐MS. One of the elements predetermined by XRF spectrometry served as an internal standard. The influence of sample preparation parameters (grain size, pellet compactness and amount of binding media) on analytical performance was also investigated, including sample homogeneity issues at the laser sampling scale. Line scanning with a high repetition frequency (20 Hz) and large beam diameter (200 μm) ensured ablation from a larger sample surface area, eliminating issues related to sample heterogeneity. A median grain size of about 10 μm for silicate rock powders was found to be sufficiently representative at this scale of laser sampling. Granitic rocks or samples containing resistant minerals such as zircon needed extra grinding to achieve grain sizes down to < 5 μm for better precision for elements that are concentrated in these phases. Using ¹³⁷Ba as an internal standard, reasonable accuracies within 15–20% for most of the high mass trace elements were achieved; in the case of low mass elements, it may deviate up to 40%. Precision of measurements rarely exceeded 15% RSD.     

Preparation and Characterisation of Two Geochemical Reference Materials: DG‐H (Granite) and AM‐H (Amphibolite) from the Himalayan Orogenic Belt

Two geochemical reference materials of Himalayan origin named DG‐H (a granite) and AM‐H (an amphibolite) prepared by the Wadia Institute of Himalayan Geology Dehradun are described. Both samples were collected from the NW Himachal Himalaya in India. With the participation of analysts from more than forty international laboratories, element determination data collected during the past 10 years for characterisation of the samples was processed to assign working values using statistical procedures in use for this purpose. Earlier work published on these samples is incorporated in the present communication making it an updated document. The typical chemical and petrological characteristics of these two samples may prove useful for method validation and calibration of analytical instruments used for analysing similar rock types, and for widening the analytical range of several analytical methods used for geochemical analysis.