On the detailed magnetostratigraphy of greigite — (Smythite) mineralization,Sokolov Brown-Coal Basin,bohemia

Summary In the Middle Miocene claystones containing fossil micro-organic matter and overlying the brown-coal seams in the Jii quarry of the Sokolov Brown-Coal Basin, a strongly magnetic layer was found and subjected to detailed palaeomagnetic investigations. The principal carrier of magnetism in this bed (called Kocián's bed) is the ferrimagnetic mineralization of greigite or greigitesmythite showing pronounced metastable properties. This mineralization must be treated with caution during laboratory tests aimed at deriving palaeomagnetic directions. In Kocián's bed, about two metres thick, two zones of palaeomagnetic field transition were identified. The high degree of demagnetization achieved by using thermal stepwise procedures and a MAVACS apparatus enabled the origin of the self-reversal of remanence to be defined after heating to 360°C. The process of chemo-remanent magnetization of the authigenic greigite-(smythite) mineralization fossilizing the palaeomagnetic field was relatively fast; the transition of the palaeomagnetic field is recorded in layers not exceeding a thickness of 2 × 10^–2 m.Presented at 2nd conference on New Trends in Geomagnetism, Castle of Bechyn, Czechoslovakia, September 24–29, 1990.     

Predicting ground-motion variations at the Turkey-flat test site,California

Results of a single group participating in an international experiment are analyzed. The experiment served to verify computational predictions of the ground-motion variations due to near-surface geological effects at a site established for that purpose by the California Department of Conservation. Based on an acceleration record at a rock location, and geotechnical model of medium, records at the other locations of a nearby sedimentary deposit were predicted. A 2-D finite-difference sensitivity analysis suggested that the lateral wave-propagation effects are negligibly small, and locally 1-D computations are sufficient for the present site. Those computations are compared with observations not available to the authors during the blind prediction. Peak accelerations, peak velocities and RMS accelerations were predicted with errors less than 159%, 114% and 62%, respectively. Maxima of the response spectra were fitted within a factor of 2. The predicted and observed Husid's plots (i.e., the normalized cumulative plots of the acceleration squared) have the correlation coefficients 0.98. The detected misfits do not show any simple relation to the instrument location, component, frequency, or time.     

Geochemical specialization of the tin-bearing granitoid massifs of NW Bohemia

The geochemistry of Hercynian tin-bearing granitoid massifs of the Krune hory Mts. (Erzgebirge), Slavkovský les Forest (Kaiserwald) and Smriny (eastern Fichtelgebirge) is compared by statistical processing of 270 analyses including a wide spectrum of major and trace elements. Seven different types of granites are distinguished. Out of these, five types represent the successive differentiation of the largest massif of NW Bohemia: the Karlovy Vary (Karlsbad) massif. This comprises strongly differentiated peraluminous granites evolving towards extreme Li-Rb-Cs-F-and Sn-enrichment in the youngest members, which are albite-topaz-zinwaldite lithium granites. The sixth and seventh types are different from the former by their location in the eastern Krune hory and tectonic setting, and they display geochemical features of anorogenic granites: they are metaluminous albite-zinwaldite granites with marked enrichment of Nb, Y, and HREE in addition to Li, Rb, Cs, F and Sn, indicating contamination by sub-crustal material. Sn-W mineralizations, including flat peri-contact greisen bodies, steep greisen veins and tourmalinized phyllites, are all intimately associated with the most strongly differentiated granites — the Li-granite and the Cinovec-granite respectively.     

Diurnal photometric conditions at Teide observatory and long-term solar irradiance variations

Monochromatic extinction coefficients at four wavelengths have been obtained over a period of more than two years at the Observatorio del Teide (Izaña Tenerife) using a full disc, direct sunlight, quadruple photometer devoted to the detection of integral luminosity oscillations of the Sun. The mean extinction coefficients (0.13 at 500 nm) show a seasonal variation of about 15%, the best atmospheric conditions being in winter and autumn. Moreover, in anyone day the extinction coefficient in the afternoon is always lower than the one in the morning by 7%. A one-year period fluctuation, with an amplitude of 0.035 mag, has been identified in the instrumental magnitudes outside the atmosphere, and is interpreted as the variation produced by the different Sun-Earth distance from winter to summer. Finally, the study made to detect periodic time fluctuations in both, Sun's magnitude and extinction coefficients, has given null results at levels of 0.04 and 1.8%, respectively.     

Emission features in the solar corona after the perihelion passage of Comet 1979 XI

On the coronograph spectrophotographic records taken on 31.372 UT, August 1979, some faint emission features were found which can be ascribed to Siii and Niii. These emissions were obviously a transient phenomena which were detected only 10 hr after the supposed fall of Comet 1979 XI in the Sun's photosphere. It cannot be excluded that the appearance of Si and Ni lines was triggered by the evaporation of dust particles with a high abundance of heavier elements in the solar corona. This assumption is also supported by intensity distribution of the Fex coronal line around the Sun's limb. The maximum coincide with the position angle of the projected path of the comet.     

Age and depositional environment of the Draa Sfar massive sulfide deposit, Morocco

The Draa Sfar mineralization consists of two main stratabound orebodies, Sidi M’Barek and Tazacourt, located north and south of the Tensift River (“Oued Tessift”), respectively. Each orebody is comprised by at least two massive sulfide lenses. The hosting rocks are predominantly black shales, although minor rhyolitic rocks are also present in the footwall to the southern orebody. Shales, rhyolitic volcanic rocks, and massive sulfides are all included into the Sarhlef Series, which is recognized as one of the main stratigraphic units of the Moroccan Variscan Meseta. Hydrothermal activity related with an anomalous thermal gradient, together with a high sedimentation rate in a tectonically driven pull-apart marine basin, favored the accumulation of organic-rich mud in the deepest parts of the basin and the sedimentary environment suitable for massive sulfide deposition and preservation. This took place by replacement of the hosting unlithified wet mud below the sediment–water interface. Geochemical data suggest a sedimentary environment characterized by oxic water column and anoxic sediment pile with the redox boundary below the sediment–water interface. The low oxygen availability within the sediment pile inhibited oxidation and pyritization of pyrrhotite. Biostratigraphic analysis, based on the palynological content of the hosting black shales, restricts the age of the sulfides to the Asbian substage (mid-Mississippian). This age is consistent with earlier geochronological constraints.     

Impact evaluation on groundwater of the infiltration of an urban wastewater geopurification system placed over a detrital aquifer in a semiarid region (Spain)

Over a period of 4 years and 4 months, the geopurification installations at Dehesas de Guadix (Granada, Spain) were monitored to determine the impact on soil and groundwater of the controlled discharge of urban wastewater, and also to identify the best indicators of the entry of the recharged water into the aquifer. The installations are located in an area where the climate is Mediterranean sub-arid, with an average precipitation of less than 287 mm/year, and a rate of evapotranspiration that is almost three times greater. The system was controlled by determining the balance of majority nutrients and boron in the soil and in the groundwater, both at the points affected directly by the wastewater discharge and at others. The quantity of mass discharged was relatively large (COD 14,656 g/m², NO₃ 85 g/m², NO₂ 4 g/m², NH₄ 2,425 g/m², PO₄ 1,143 g/m², K 1,531 g/m², B 63 g/m²). It was observed that the elimination of nutrients within the soil (COD 97.5%, PO₄ 94.4%, K 59.17%, N _total 18.8%, B 12.69%) was very efficient except for the nitrogen, which nevertheless did not reach the groundwater, as it was eliminated at deep levels of the unsaturated zone. Only 12.69% of the boron was removed, and appreciable, increasing amounts of this element did reach the groundwater. Unexpectedly, none of the majority nutrients behaved as a reliable indicator of the impact on groundwater; despite this, the boron and the bicarbonate did clearly reflect the arrival of the recharged water, and are proposed as the best indicators.     

Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain)

Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of the Iberian Pyrite Belt. Concentrations were 19–994 mg kg⁻¹ for As, 41–4,890 mg kg⁻¹ for Pb, 95–897 mg kg⁻¹ for Zn and of 27–1,160 mg kg⁻¹ for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input, such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction. According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn, Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where the concentrations are not so high.     

Environmental risk evaluation of the use of mine spoils and treated sewage sludge in the ecological restoration of limestone quarries

The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality, came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications. Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium, phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values obtained were very elevated.