四川理塘地区二叠—三叠纪硅质岩的地球化学特征及地质意义

甘孜—理塘蛇绿混杂岩带位于西南"三江"东缘,为义敦—理塘弧盆系的重要组成部分,其内部发育大量不同时代不同类型的硅质岩。本次研究在理塘县理觉公路硅质岩夹层泥岩、泥灰岩中发现含有大量的中二叠—晚二叠世牙形石,在查日查东村附近硅质岩中采获中三叠世放射虫。通过对研究区硅质岩岩石学、地球化学特征研究,探讨硅质岩的成因类型及其沉积环境。结果表明,理塘地区硅质岩SiO_2质量分数为66.13%～85.89%, Al_2O_3质量分数为4.69%～7.85%, Al/(Al+Fe+Mn)值介于0.44～0.73之间, U/Th比值为0.10～0.19,δCe值为1.00～1.63,这些特征共同指示其为生物成因硅质岩。Al_2O_3/(Al_2O_3+Fe_2O_3)质量比为0.52～0.79, MnO/TiO_2质量比为0.05～0.27,∑REE为(49.26～165.41)×10~(–6),平均为94.37×10~(–6),(La/Yb)N比值为0.78～2.32,(La/Ce)N比值为0.72～1.26,指示其应形成于大陆边缘环境。理塘地区理觉公路和查日查东村二叠—三叠纪大陆边缘型硅质岩的厘定,不仅丰富了甘孜—理塘蛇绿混杂岩带的物质组成,也为甘孜—理塘洋盆二叠—三叠纪地质演化提供了新的证据。     

川北小南海剖面栖霞组岩石微相及沉积环境

近年来，四川盆地西北部下二叠统栖霞组已成为油气勘探的热点和重点。但川北地区勘探程度较低，钻井和剖面资料较少，栖霞组岩石类型分类粗略，沉积模式尚存争议。故选取川北地区露头出露良好的小南海剖面，通过实测观察和室内岩石薄片鉴定，共识别出4类11种岩石类型，并在此基础上分析其岩石微相类型及沉积环境。结果表明:川北地区栖霞组为开阔台地相沉积，生物化石类型丰富，碳酸盐颗粒强烈泥晶化，发育相对低能的似球粒颗粒滩，有别于鲕粒滩和生物碎屑滩，为川北地区下二叠统栖霞组台地沉积模式提供了新的依据。似球粒浅滩的形成环境对进一步认识上扬子二叠纪古地理环境具有重要意义，可为川北地区在今后的勘探工作提供理论指导。此外，梁山组—栖霞组应为一个完整的三级层序，海平面变化是栖霞组沉积相横向迁移和纵向演化的主要控制因素。     

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.     

地理国情普查专题图制作系统设计

研究从地理国情普查专题图编制具体需求出发,在分析普查专题图工艺流程的基础上,提出一种专题图制作系统设计方案,从基础制图平台设计、自动化模块设计和交互式制图处理等3个方面进行研究。该成果期望为地理国情普查专题图快速、自动化制图等方面提供借鉴。     

Mineral Deposit Model of Cu–Fe–Au Skarn System in the Edongnan Region, Eastern China

Cu and Fe skarns are the world’s most abundant and largest skarn type deposits, especially in China, and Au-rich skarn deposits have received much attention in the past two decades and yet there are few papers focused on schematic mineral deposit models of Cu–Fe–Au skarn systems. Three types of Au-rich deposits are recognized in the Edongnan region, Middle–Lower Yangtze River metallogenic belt: ~140 Ma Cu–Au and Au–Cu skarn deposits and distal Au–Tl deposits; 137–148 Ma Cu–Fe; and 130–133 Ma Fe skarn deposits. The Cu–Fe skarn deposits have a greater contribution of mantle components than the Fe skarn deposits, and the hydrothermal fluids responsible for formation of the Fe skarn deposits involved a greater contribution from evaporitic sedimentary rocks compared to Cu–Fe skarn deposits. The carbonate-hosted Au–Tl deposits in the Edongnan region are interpreted as distal products of Cu–Au skarn mineralization. A new schematic mineral deposit model of the Cu–Fe–Au skarn system is proposed to illustrate the relationship between the Cu–Fe–Au skarn mineralization, the evaporitic sedimentary rocks, and distal Au–Tl deposits. This model has important implications for the exploration for carbonate–hosted Au–Tl deposits in the more distal parts of Cu–Au skarn systems, and Fe skarn deposits with the occurrence of gypsum-bearing host sedimentary rocks in the MLYRB, and possibly elsewhere.     

基于混合聚类的岩体结构面优势分组方法

提出一种基于凝聚层次法和模糊C均值法的混合聚类法,用于对岩体结构面的优势组划分。该方法将结构面投放到在单位球面上,并使用欧式距离作为极点的相似性度量准则。先剔除结构面数据中的孤值产状,然后用凝聚层次法得到初步聚类结果,并将其作为FCM法的初始聚类中心,最后用FCM法划分优势组。通对人工生成产状样本的分组,验证了该法的正确性。将该方法应用于大藤峡坝址区实测的结构面数据的划分。在实测数据中寻找到两个孤值产状,成功将大藤峡D1y^1-3地层岩体结构面划分为两组,得到了符合实际的分组结果。     

探秘“能源新星”——干热岩

干热岩是近些年逐渐发展起来的清洁能源，指埋藏于地球表面3000 m以深，不含或含少量水或蒸汽等流体，温度在180 ℃以上且渗透率极低的岩体。对干热岩的应用主要是建立增强型地热系统进行发电。目前对干热岩的研究尚处于起步阶段,干热岩的热源、热储、形成机理、埋藏机制等都未形成完整的理论体系，干热岩的开发过程也面临诸如储层改造、高温钻探以及随钻监测等一系列的技术“瓶颈”。干热岩资源储量大，开发利用过程低碳环保、节能高效，是国际社会公认的优质清洁能源，但是干热岩研究程度低，开发难度大，需要不断的知识积累和技术积累。本文从科普的角度列举了干热岩的相关研究现状及存在的问题，以期能让更多的人对这一“能源新星”加深了解。     

硼的地球化学性质及其在俯冲带的循环与成矿初探

硼是广泛应用于化工、农业、材料科学及核工业领域的重要元素。硼与氢的核聚变反应是未来具备运用潜力的清洁能源。硼作为典型的亲石元素,是高度不相容元素。硼元素容易富集于蚀变洋壳及蛇纹石化地幔橄榄岩中。而在板块俯冲过程中,由于硼具有强的流体活动性,会优先赋存于流体中。因此,当蛇纹石化的大洋岩石圈及覆于其上的沉积物在俯冲过程中发生脱水,这使得弧前地幔楔发生大规模的蛇纹石化。此时大量硼元素很可能随俯冲流体释放并封存于弧前地幔楔中。目前已发现的超大型硼矿床主要位于聚合型板块边缘,尤其土耳其拥有世界上最大的硼酸盐储量。我们推测这些矿床的形成基础条件之一可能与弧前高度蛇纹石化的地幔楔有关。尤其是在洋 陆俯冲环境,弧前蛇纹岩或蛇绿混杂岩首先通过俯冲侵蚀再循环到火山弧岩浆中,使得岩浆更富集硼。随后弧火山喷发大量富硼的火山岩、岩浆热液及水气。在岩浆冷却过程中,硼元素析出、沉淀于火山表面,并伴随风化、侵蚀过程汇聚至碰撞造山带的封闭湖盆之中。此外,干冷的气候条件下也进一步促进了硼的成矿。我国具有形成大型、超大型硼矿的地质条件,应加大研究及探勘力度,并适当购买硼作为战略储备。     

花岗岩残积土动态冲击性能的SHPB试验研究

为研究花岗岩残积土的动态冲击性能，开展了高速冲击下的分离式霍普金森压杆（SHPB）试验，与常规应变率下的试验结果比较，分析了高应变率对花岗岩残积土的应力?应变特性和强度的影响。结果表明：低、高应变率下的花岗岩残积土的?-?a（轴向应力?轴向应变）曲线均呈现出软化型。随着应变率 增加，?-?a曲线向?a增大的方向移动，破坏应变?af增加。但高应变率下?af增加的程度更加明显。花岗岩残积土的峰值强度普遍具有应变率依赖性，二者可用直线关系拟合，但低、高应变率下的拟合关系并不一致。提出了率敏性因子m定量评价依赖性强弱。研究发现，随着应变率的提高，强度的应变率依赖性减弱，低应变率下的m为26.694，而高应变率下仅为0.013。相关试验结果指出，高速冲击荷载对土体总体有害。工程中应该采取合理措施控制冲击荷载的危害。该研究有助于深化花岗岩残积土动态冲击性能的理解，为相关工程的施工与设计提供技术参考。