辽西中生代火山岩岩浆成因——稀土元素配分及同位素定量模式

本文通过对辽西及邻区中生代盆地火山岩稀土元素配分特征的研究及模拟运算，探讨了其岩浆成因及过程。结果显示南北岩区岩浆成因不同，南岩区岩源为MORB地幔和长期富集型幔熔融混合而成，北岩区为MORB和近期亏损型地幔熔融混合而成。     

遥感技术在化工环境保护中的应用

遥感技术获取的可见光、红外及微波信息，可以对化工企业及化学矿山环境污染（水、粉尘、大气、废渣污染等）及环境地质灾害（滑坡、泥石流、地面塌陷等）进行实时动态监测，并可获得较高的社会经济效益，达到地面环保及常规环境地质工作难以达到的效果。特别是对重点大中型化工企业及化学矿山建立环境遥感信息动态监测系统，可以为国家决策部门及时准确地提供环境治理和改造的依据。     

Application of discovery process models in estimating petroleum resources at the play level in China

Discovery process modeling has gained wide acceptance in the Chinese exploration community. In recent years, a variety of discovery process models have been applied to the prediction of undiscovered petroleum resources at the play level in sedimentary basins in China. However, challenging problems have been encountered, particularly when one method alone has been applied to small plays in nonmarine sedimentary basins or in plays with an unusual order of discovery wells. This paper presents results gotten by using the lognormal discovery process model of the Geological Survey of Canada and the geoanchored method for three petroleum plays in basins with different geologic settings. Although the predicted shapes of the parentsize distributions which use these two models, were not always similar, the expected values of the total resources and the number of fields (pools) to be discovered are comparable. The combined use of two discovery process models in the same play compensates for the weaknesses in one method compared with the other and vice versa. Thus, more reliable estimates are the result.     

Geochronology, geochemistry and tectonic implications of Xiongshan diabasic dike swarm, northern Fujian

Sm/Nd isotopic age determination showed that Xiongshan dike swarm was at 585.7 Ma ± 30 Ma. The trace element geochemistry and Sr/Nd/Pb isotope gemhemistry studies indicate that the dike swarm was products of back-arc basin spreading ridge and the magma originated from the depleted mantle region which was metasomatized by LILE-rich liquids/melts derived from subduction slab. Project supported by the National Natural Science Foundation of China.     

The influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes in pyrolysates of selected terrestrial kerogens

Expulsion of petroleum from source rock is a complex part of the entire migration process. There exist fractional effects on chemical compositions in hydrocarbon expulsion. Does the carbon isotopic fractionation occur during expulsion and to what extent? Here the influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes from pyrolysates of selected terrestrial kerogens from Tuha basin and Fushun, Liaoning Province of China has been experimentally studied. The pyrogeneration-expulsion experiments were carried out under semi-closed system. The carbon isotopic compositions of individual n-alkanes were measured by GC-IRMS. The main conclusions are as follows. First, there is carbon isotopic fractionation associated with hydrocarbon expulsion from Type III kerogens in Tuha Basin. There exist differences of carbon isotopic compositions between the unexpelled n-alkanes and expelled n-alkanes from Tuha desmocollinite and Tuha mudstone. Second, there is almost no carbon isotopic fractionation associated with hydrocarbon expulsion from Type II kerogens in Fushun and Liaohe Basin. Third, carbon isotopic fractionation in hydrocarbon expulsion should be considered in making oil-source correlation of Type III kerogens at least in the Tuha Basin. Further studies need to be carried out to determine whether this is true in other basins. Fourth, oil and source at different maturity levels cannot be correlated directly for Type III kerogens since the carbon isotopic compositions of expelled hydrocarbons at different temperatures are different. The expelled hydrocarbons are usually lighter (depleted in ¹³C) than the hydrocarbons remaining in the source rock at the same maturity.     

长沙地震台北东方向深震sP震相讨论

长沙地震台北东方向深源地震的记录中,发生于日本海边缘和中朝俄接界区域的深源地震存在sP震相,它超前于S波,由于震相能量较大,容易与S波相混淆。本文讨论了如何对它进行辨别。     

Spatio-temporal Variation of Soil Respiration and Its Driving Factors in Semi-arid Regions of North China

Soil respiration (SR) is the second-largest flux in ecosystem carbon cycling. Due to the large spatio-temporal variability of environmental factors, SR varied among different vegetation types, thereby impeding accurate estimation of CO₂ emissions via SR. However, studies on spatio-temporal variation of SR are still scarce for semi-arid regions of North China. In this study, we conducted 12-month SR measurements in six land-use types, including two secondary forests (Populus tomentosa (PT) and Robinia pseudoacacia (RP)), three artificial plantations (Armeniaca sibirica (AS), Punica granatum (PG) and Ziziphus jujuba (ZJ)) and one natural grassland (GR), to quantify spatio-temporal variation of SR and distinguish its controlling factors. Results indicated that SR exhibited distinct seasonal patterns for the six sites. Soil respiration peaked in August 2012 and bottomed in April 2013. The temporal coefficient of variation (CV) of SR for the six sites ranged from 76.98% to 94.08%, while the spatial CV of SR ranged from 20.28% to 72.97% across the 12-month measurement. Soil temperature and soil moisture were the major controlling factors of temporal variation of SR in the six sites, while spatial variation in SR was mainly caused by the differences in soil total nitrogen (STN), soil organic carbon (SOC), net photosynthesis rate, and fine root biomass. Our results show that the annual average SR and Q₁₀ (temperature sensitivity of soil respiration) values tended to decrease from secondary forests and grassland to plantations, indicating that the conversion of natural ecosystems to man-made ecosystems may reduce CO₂ emissions and SR temperature sensitivity. Due to the high spatio-temporal variation of SR in our study area, care should be taken when converting secondary forests and grassland to plantations from the point view of accurately quantifying CO₂ emissions via SR at regional scales.     

Emissions of biogenic sulfur gases (H<Subscript>2</Subscript>S,COS) from <Emphasis Type="Italic">Phragmites australis</Emphasis> coastal marsh in the Yellow River estuary of China

Emissions of biogenic sulfur gases (hydrogen sulfide (H₂S) and carbonyl sulfide (COS)) from Phragmites australis coastal marsh in the Yellow River estuary of China were determined during April to December in 2014 using static chamber-gas chromatography technique with monthly sampling. The results showed that the fluxes of H₂S and COS both had distinct seasonal and diurnal variations. The H₂S fluxes ranged from 0.09 μg/(m²·h) to 7.65 μg/(m²·h), and the COS fluxes ranged from–1.10 μg/(m²·h) to 3.32 μg/(m²·h). The mean fluxes of H₂S and COS from the P. australis coastal marsh were 2.28 μg/(m²·h), and 1.05 μg/(m²·h), respectively. The P. australis coastal marsh was the emission source of both H₂S and COS over the whole year. Fluxes of H₂S and COS were both higher in plant growing season than in the non-growing season. Temperature had a dramatic effect on the H₂S emission flux, while the correlations between COS flux and the environmental factors were not found during sampling periods. More in-depth and comprehensive research on other related factors, such as vegetation, sediment substrates, and tidal action is needed to discover and further understand the key factors and the release mechanism of sulfur gases.     

塔河油田奥陶系岩溶塌陷体结构识别及成因分析

塔河油田奥陶系碳酸盐岩古溶洞塌陷是一种特殊的岩溶型储集体,塌陷作用导致早期洞穴的坍塌、围岩多类型的角砾岩化以及孔隙结构在一定范围上的改造等。通过钻井、岩心、常规测井、FMI 成像测井等技术手段来识别和再现了塌陷体裂纹角砾岩、镶嵌角砾岩、混杂角砾岩和溶洞及其沉积充填物等独特的响应特征。展示了岩溶塌陷体及其上覆地层地震同相轴“下凹”和伴随“串珠”状—杂乱反射的地震结构特征。依据塌陷几何结构的生长指数(EI)、垂向海拔变化(ΔZ)以及宽度(W)等参数定量评价,指出塌陷形成具有多期次性,在下巴楚泥岩段达到峰值。通过实例剖面分析,将塌陷体分为3种类型:(1)早期(表生岩溶期)溶蚀塌陷,常发育多层洞穴垮塌,塌陷带内角砾岩发育,构成了灰岩和混杂角砾与泥质支撑的混杂角砾复杂岩性组合,储集体上下整体连通,具有一定的储集性能;(2)中期(早石炭世)负载塌陷,属于埋藏后塌陷,储集体由缝隙、裂纹角砾岩、镶嵌杂乱角砾岩、富碎屑基质支撑的杂乱角砾岩和洞穴沉积的石英砂岩组成,存在未充填的残余洞穴储集空间;(3)晚期(海西晚期)断控塌陷,海西晚期构造导致的埋藏后的古溶洞塌陷,形成新的“缝隙、镶嵌角砾岩、杂乱角砾和原始溶洞”的塌陷结构,储集性能较好。原始洞穴层、塌陷时间和主控因素三者的相互组合导致了古洞穴塌陷的复杂储集体结构。分析认为负载塌陷和断控塌陷发育有效的储集空间,可作为油气开发有利的潜力目标区。