THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.     

蒸发皿中水面蒸发氢氧同位素分馏的实验研究

气象要素与蒸发密切相关,通过室内外不同气象条件下的器皿水蒸发实验,获得了水面蒸发氢氧稳定同位素分馏因子与气象要素的关系。实验结果表明,随着蒸发的进行,剩余水体中逐渐富集重同位素;自由水体蒸发同位素分馏在垂线上有分层现象,表层水体同位素值比垂线平均的同位素值略富集;不同温度条件下的室内蒸发实验中,温度越高,液-气间分馏系数越小,相应于同一剩余水体体积比,剩余水体稳定同位素值则越低。室外器皿水自由蒸发实验中得出的蒸发线方程斜率较大地偏离了当地降水线,表明实验期间水体蒸发分馏作用较明显。该研究为进一步揭示水体蒸发分馏规律提供了可靠的实验依据。     

利用GPS组合观测值探测与修复周跳算法实现

本文在目前常用的周跳探测和修复方法的基础上,根据相位减伪距组合,Melbourne-Wübbena组合,电离层残差组合三种GPS组合观测值优缺点互补,将这三种组合观测值有机结合产生可靠的探测与修复周跳算法并用程序实现,通过实例分析证明此算法能够探测和修复任意大小的周跳。     

根据多卫星高度计海面高数据推算南中国海及菲律宾海域重力异常(英文)

t Gravity anomalies on a2.5 ×2.5 arc-minute grid in a non-tidal system were derived over the South China and Philippine Seas from multi-satellite altimetry data. North and east components of deflections of the vertical were computed from altimeter-derived sea surface heights at crossover locations, and gridded onto a 2.5 × 2.5 arc-minute resolution grid. EGM96-derived components of deflections of the vertical and gravity anomalies gridded into 2.5 × 2.5 arc-minute resolutions were then used as reference global geopotential model quantities in a remove-restore procedure to implement the Inverse Vening Meinesz formula via the 1D-FFT technique to predict the gravity anomalies over the South China and Philippine Seas from the gridded altimeter-derived components of deflections of the vertical. Statistical comparisons between the altimeter-derived and the shipboard gravity anomalies showed that there is a root-mean-square agreement of 5.7 mgals between them.     

新疆阿尔泰山南部富蕴右旋走滑断裂带晚第四纪错断水系的遥感分析研究

富蕴断裂带位于阿尔泰山南侧,横切阿尔泰山褶皱带南缘及额尔齐斯深断裂,是一条呈北北西向展布的右旋走滑断裂带。沿断裂带发育一系列错断水系、错断冲积扇、挤压脊、走滑拉分盆地等反映右旋走滑活动的典型构造地貌标志。本研究在高分辨率遥感图像和数字高程模型分析的基础上,结合野外实地构造地貌测量,对沿富蕴断裂带发育的系统错断水系特征进行了详细分析研究。研究结果表明,沿富蕴断裂带发育不同级别的错断水系,大致可划分为6级:1931年地震形成的冲沟;90m左右断距的错断水系;150m左右断距的错断水系;500m左右断距的错断水系;1500m左右断距的错断水系;2000m以上断距的错断水系。同时,结合研究区及邻区的第四纪冰川资料讨论了不同级别水系可能形成时间:恰尔沟三级支流可能形成时间为末次冰期Ⅲ阶段末期,约20ka;恰尔沟二级支流可能形成时间为末次冰期Ⅰ阶段末期,约120ka;恰尔沟一级支流可能形成于该地区冰川广泛消融的倒数第2次冰期的Ⅱ阶段末期,约为250ka;恰尔沟、水磨沟、白杨沟、乌铁布拉克河、卡布尔特河等可能形成于倒数第3次冰期Ⅱ阶段末期,约为360ka。最后,我们估算出富蕴断裂带晚第四纪以来的平均右旋走滑速率为1.46～4.99mm/a。     

高灵敏度机载L波段微波辐射计探测海表盐度

海水盐度是研究大洋环流和全球气候变化的重要参数,L波段(1400-1427MHz)微波辐射计是进行海水盐度遥感的最有效工具.在该频段内,微波辐射亮度温度对海水盐度变化的灵敏度为0.5K/psu,而用于海洋研究的盐度分辨率为0.1-0.2psu,要求微波辐射计的灵敏度优于0.1K.高灵敏度机载L波段微波辐射计,应用数字增益波动自动补偿和温度补偿技术,保证了系统的稳定性,并采用高效的滤波技术有效地抑制了全球定位信号(GPS)对接收机的干扰,灵敏度达到0.08K.进行了多次航空和海上对比遥感试验,获得了分辨率优于0.2psu、误差精度0.42psu的测量结果.     

黄河内蒙古段上覆水、悬浮物和底泥重金属特征及生态风险研究

系统地采集黄河内蒙古段上覆水、悬浮物和底泥样品,分析其中重金属元素的含量。采用地质累积指数法和潜在生态危害系数法,研究了黄河干流内蒙古段的上覆水、悬浮物和底泥的重金属沿程分布特征、污染程度和生态风险。分析结果显示:除了As元素,悬浮物中重金属元素含量总体上高于底泥中的含量。地质累积指数法评价结果表明:悬浮物和底泥属于无污染—中度污染,悬浮物总体上比底泥污染严重;潜在生态危害系数法评价结果表明:底泥和悬浮物中重金属的生态危害总体上属轻微状态;因此,生态风险指数法和地质累积指数评价结果基本一致。     

浅层SH反射波法和多道瞬态面波法 进行联合工程勘察的讨论

针对目前单一工程物探方法调查浅部地质结构的局限性,提出采用弹性波法勘察中研究浅部地质结构的SH波反射勘察和多道瞬态面波法勘察这2种有效手段进行联合勘探,提高其可靠性和精度,并给出了3个实例,指出了在数据采集和处理时应注意的问题。     

基于传统吸附烃概念的烃类检测新技术

烃类是地表油气地球化学勘查地下油气藏的直接指标.目前我国油气化探中常用的酸解烃法检测出的烃类,不应定义为"吸附烃",它是介质吸收的产物,属结合态烃类,应定义为"吸收烃".地表酸解烃异常十分稳定,重现性好,能够很好地证明地质历史上曾经有过的烃类运移过程,但在反映目前深部油气信息方面具有多解性.针对酸解烃法的弱点,依据烃类垂向运移理论和物质吸附作用原理,自行设计开发、研制了一套吸附烃脱气装置,建立了土壤吸附烃提取新技术和检测方法.该方法有利于在近地表获取油气系统的动态信息,强化烃类测量法对其信息源的探测,可以提高地表油气化探预测油气分布的成功率.     

A sub-pixel analysis of urbanization effect on land surface temperature and its interplay with impervious surface and vegetation coverage in Indianapolis,United States

This study developed an analytical procedure based upon a spectral unmixing model for characterizing and quantifying urban landscape changes in Indianapolis, Indiana, the United States, and for examining the environmental impact of such changes on land surface temperatures (LST). Three dates of Landsat TM/ETM+ images, acquired in 1991, 1995, and 2000, respectively, were utilized to document the historical morphological changes in impervious surface and vegetation coverage and to analyze the relationship between these changes and those occurred in LST. Three fraction endmembers, i.e., impervious surface, green vegetation, and shade, were derived with an unconstrained least-squares solution. A hybrid classification procedure, which combined maximum-likelihood and decision-tree algorithms, was developed to classify the fraction images into land use and land cover classes. Correlation analyses were conducted to investigate the changing relationships of LST with impervious surface and vegetation coverage. Results indicate that multi-temporal fraction images were effective for quantifying the dynamics of urban morphology and for deriving a reliable measurement of environmental variables such as vegetation abundance and impervious surface coverage. Urbanization created an evolved inverse relationship between impervious and vegetation coverage, and brought about new LST patterns because of LST's correlations with both impervious and vegetation coverage. Further researches should be directed to refine spectral mixture modeling by stratification, and by the use of multiple endmembers and hyperspectral imagery.