Probing molecular-level transformations of dissolved organic matter: insights on photochemical degradation and protozoan modification of DOM from electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems.     

Community Structure and Dynamics of Phytoplankton in the Western Subarctic Pacific Ocean: A Synthesis

The phytoplankton community in the western subarctic Pacific (WSP) is composed mostly of pico- and nanophytoplankton. Chlorophyll a (Chl a) in the <2 μm size fraction accounted for more than half of the total Chl a in all seasons, with higher contributions of up to 75% of the total Chl a in summer and fall. The exception is the western boundary along the Kamchatka Peninsula and Kuril Islands and the Oyashio region where diatoms make up the majority of total Chl a during the spring bloom. Among the picophytoplankton, picoeukaryotes and Synechococcus are approximately equally abundant, but the former is more important in term of carbon biomass. Despite the lack of a clear seasonal variation in Chl a concentration, primary productivity showed a large seasonal variation, and was lowest in winter and highest in spring. Seasonal succession in the phytoplankton community is also evident with the abundance of diatoms peaking in May, followed by picoeukaryotes and Synechococcus in summer. The growth of phytoplankton (especially >10 μm cell size) in the western subarctic Pacific is often limited by iron bioavailability, and microzooplankton grazing keeps the standing stock of pico- and nano-phytoplankton low. Compared to the other HNLC regions (the eastern equatorial Pacific, the Southern Ocean, and the eastern subarctic Pacific), iron limitation in the Western Subarctic Gyre (WSG) may be less severe probably due to higher iron concentrations. The Oyashio region has similar physical condition, macronutrient supply and phytoplankton species compositions to the WSG, but much higher phytoplankton biomass and primary productivity. The difference between the Oyashio region and the WSG is also believed to be the results of difference in iron bioavailability in both regions. This revised version was published online in July 2006 with corrections to the Cover Date.     

Biokarst on Limestone Coasts, Morphogenesis and Sediment Production

Abstract. Biokarst-forms on limestone coasts are developed and arranged according to the bionomic zonation. The development of biokarst is the result of bioerosion, a synergistic effect of biological corrosion by endoliths and biological abrasion by grazers.
The cumulative effect of biogenic carbonate destruction leads to coastal destruction with a resulting highly profiled morphology on the limestone surfaces along the coastal profile. Under the influence of environmental factors a zonation of organisms develops which brings in turn a zonation of erosion rates (0.1-1.1 mm a^-1) resulting in biokarst-forms such as rock holes, rock pools and notches.
Products of bioerosion on limestone coasts are dissolved carbonate (by biological corrosion, 10–30% of the decomposed limestone) and particulate carbonate (by biological abrasion, 70–90% of the decomposed limestone) both of which contribute directly or indirectly to nearshore sedimentation. Size and shape of the bioerosional grains are determined by the boring pattern of the endoliths. The fine-grained sediments (maximum within the fraction 20–63 μm) contribute 3–25 % to the nearshore sediments.
Drastic changes in the biological zonation (like the mass invasion of the sea urchin Paracentrotus lividus in the Northern Adriatic since 1972 which eliminated nearly the entire macrophyte zone) due to unknown factors or pollution can have a profound effect on the bioerosion rates, altering them by as much as a factor of ten.     

重力辅助惯性导航中重力归算的垂直梯度计算

重力辅助惯性导航技术是利用地球物理特征信息数据—重力来完成水下运动载体的辅助导航与定位。为了实现水下运动载体上重力传感器输出的实测重力信息与重力数据库中存储的重力信息之间的匹配,首先必须将这两类数据归算到一个平面。本文研究分析了重力归算中重力垂直梯度求解的各种方法;探讨了不同数值积分区域对扰动重力垂直梯度精度的影响;并通过计算分析,提出了可以直接以重力异常垂直梯度代替扰动重力垂直梯度来求取重力垂直梯度。     

低渗透储层水平井—直井联合布井极限注采井距研究

低渗透储层水平井—直井联合布井技术具有广泛的应用前景,其布井方式至关重要。首先利用劈分流场的方法直观地给出常规储层水平井—直井联合布井的产能评价方法;然后针对低渗透储层的渗流特点,在考虑启动压力梯度条件下建立新的井网渗流物理模型并求解得到产能评价公式;最后经分析计算给出启动压力梯度影响的面积井网极限注采井距关系曲线。研究结果为低渗透储层部署水平井—直井联合井网提供理论依据。     

利用钻芯孔检测灌注桩钢筋笼长度的方法

根据充电法原理,结合模型桩试验,分析了钢筋笼周围的充电电场特征,结果表明钢筋笼的底端对应于电位梯度曲线的极小值点及电位曲线的拐点。以此研究结果为基础,提出了利用钻芯孔来检测成桩后钢筋笼长度的方法。某桥的应用表明,该方法简便、实用、可靠。     

电离层电子浓度总含量梯度对GPS差分定位精度的影响

针对GPS定位测量的信号传播路径误差,分析了电离层电子浓度总含量梯度对差分定位精度的影响,利用L1载波重点讨论了1999年-2000年太阳活动期间低纬度赤道异常地区GPS差分定位精度的问题,同时验证对于长基线采用GPS广域差分技术可以使电离层定位误差得到明显提高。     

Study on Recovering the Earth＇s Potential Field Based on GOCE Gradiometry

Given the second radial derivative Vrr（P） ｜δs of the Earth＇s gravitational potential V（P） on the surface δS corresponding to the satellite altitude, by using the fictitious compress recovery method, a fictitious regular harmonic field rrVrr（P）^＊ and a fictitious second radial gradient field V：（P） in the domain outside an inner sphere Ki can be determined, which coincides with the real field V（P） in the domain outside the Earth. Vrr^＊（P）could be further expressed as a uniformly convergent expansion series in the domain outside the inner sphere, because rrV（P）^＊ could be expressed as a uniformly convergent spherical harmonic expansion series due to its regularity and harmony in that domain. In another aspect, the fictitious field V^＊（P） defined in the domain outside the inner sphere, which coincides with the real field V（P） in the domain outside the Earth, could be also expressed as a spherical harmonic expansion series. Then, the harmonic coefficients contained in the series expressing V^＊（P） can be determined, and consequently the real field V（P） is recovered. Preliminary simulation calculations show that the second radial gradient field Vrr（P） could be recovered based only on the second radial derivative V（P）｜δs given on the satellite boundary. Concerning the final recovery of the potential field V（P） based only on the boundary value Vrr （P）｜δs, the simulation tests are still in process.