内蒙古集宁地区变质岩系的特征、原岩恢复及找矿方向

集宁地区位于内蒙古中部,阴山山脉东段,隶属华北地台北缘内蒙台隆凉城断隆.基底主要出露太古宙中深变质岩系,以大土城隐伏深断裂为界,断裂以南为集宁岩群分布区,以北为乌拉山岩群分布区.集宁岩群变质岩系的原岩主要由泥质长石砂岩、泥质粉砂岩及碳酸盐岩组成,伴有基性岩体侵入;乌拉山岩群变质岩系的原岩是由长石砂岩、泥质长石砂岩、泥质砂岩、泥质粉砂岩夹安山岩、安山质凝灰岩及碳酸盐岩等组成的一套巨厚的火山-沉积建造.通过1：5万袁家房子等四幅矿调,对集宁地区的变质岩系的地球化学特征及含矿性进行了调查研究,综合分析认为变质岩系为本区的主要赋矿岩层,为本区找矿指出了方向.     

冀北赤城红旗营子群黑云斜长片麻岩的岩石学、地球化学及原岩特征

冀北赤城红旗营子群黑云斜长片麻岩具斑状变晶结构,变基质为中、细粒鳞片粒状变晶结构,片麻状构造,局部保留有变余砂状结构。岩石主要由斜长石(28%~32%)、石英(35%~40%)、黑云母(18%~25%)及少量石榴石(2%~8%)和石墨(1%~4%)等组成,其变质演化可能是一个降温、降压的过程。黑云斜长片麻岩样品具有较宽的常量元素变化范围,稀土元素含量不是很高且变化较大,ΣREE介于49.45×10-6~140.10×10-6之间,具有轻稀土富集、重稀土平坦的球粒陨石标准化稀土配分模式,轻、重稀土元素比值为5.23~9.16,(La/Yb)CN值为5.07~8.70。大多数样品具中等程度的负Eu异常和不太明显的负Ce异常,(Eu/Eu*)CN和(Ce/Ce*)CN值分别为0.63~0.81和0.82~1.01。岩石中Rb、Sr、Cs、Ba、Zr、Hf、Nb、Ta、Th和U等微量元素含量均低于上地壳的平均含量,但Sr/Ba和Th/U值高于上地壳的平均值。红旗营子群黑云斜长片麻岩的地球化学特征表明其原岩应为泥质(或含泥质)砂岩,可能形成于大陆岛弧环境。     

浙闽地区华夏地块新元古代变沉积岩地球化学特征及其地质意义

浙闽地区华夏地块前寒武纪基底上部主要由新元古代龙泉群、马面山群和万全群组成.上述3个岩群的变沉积岩具有相似的岩石组合及主、微量元素地球化学特征, 它们是华夏地块统一基底的重要组成部分.它们主要由片岩类、变粒岩类、石英岩类和大理岩类组成, 其中片岩类和变粒岩类的SiO₂变化于52.89~75.03, TiO₂为0.48~1.05, Al₂O₃为9.19~20.3, ∑REE为(149~323)×10-6, δEu为0.34~0.80, (La/Yb)_N为7.96~15.6, 具中等-强烈铕负异常, 轻、重稀土分异明显; 石英岩类的SiO₂变化于95.49~97.44, ∑REE很低, 在(8.89~15.1)×10-6, δEu=0.63~0.81.原岩性质及构造环境分析表明, 片岩类和变粒岩类的原岩主要是杂砂岩和粘土岩等, 石英岩的原岩为硅铁质沉积岩.所有变沉积岩的原岩均以长英质成分为主, 具有上地壳岩石的地球化学特征, 部分样品显示有古老沉积物的加入; 它们形成于岛弧-活动陆缘环境, 成熟度不高, 属于近源沉积, 与本地区华夏地块基底下部变质岩系岩石(古元古代的天井坪组、八都群、陈蔡群、麻源群)具有相似的物源.      

U–Pb zircon geochronology of coesite‐bearing eclogites from the southern Dulan area of the North Qaidam UHP terrane,northwestern China: spatially and temporally extensive UHP metamorphism during continental subduction

Coesite‐bearing eclogites from >100 km² in the southern Dulan area, North Qaidam Mountains (NQM) of western China, contain zircon that records protolith crystallization and ultra high pressure (UHP) metamorphism. Sensitive High‐Resolution Ion Microprobe (Mass Spectrometer) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry U–Pb analyses from cathodoluminescence (CL)‐dark zircon cores in a coesite‐bearing eclogite yield an upper intercept age of 838 ± 50 Ma, and oscillatory zoned cores in a kyanite‐bearing eclogite gave a weighted mean ²⁰⁶Pb/²³⁸U age of 832 ± 20 Ma. These zircon cores yield steep heavy rare earth element (HREE) slopes and negative Eu anomalies that suggest a magmatic origin. Thus, c. 835 Ma is interpreted as the eclogite protolith age. Unzoned CL‐grey or ‐bright zircon and zircon rims from four samples yield weighted mean ages of 430 ± 4, 438 ± 2, 446 ± 10 and 446 ± 3 Ma, flat HREE patterns without Eu anomalies, and contain inclusions of garnet, omphacite, rutile, phengite and rare coesite. These ages are interpreted to record 16 ± 5 Myr of UHP metamorphism. These new UHP ages overlap the age range of both eclogite and paragneiss from the northern Dulan area, suggesting that all UHP rock types in the Dulan area belong to the same tectonic unit. Our results are consistent with slow continental subduction, but do not match oceanic subduction and diapiric exhumation UHP model predictions. These new data suggest that, similar to eclogites in other HP/UHP units of the NQM and South Altyn Tagh, protoliths of the eclogites in the Dulan area formed in a continental setting during the Neoproterozoic, and then subducted to mantle depth together with continental materials during the Early Palaeozoic.     

相山铀矿田基底变质岩原岩恢复及构造环境判别

文章通过对相山铀矿田深部变质岩开展岩石学、矿物学及地球化学等方面的研究,以探讨相山基底变质岩原岩的属性和形成环境等特征。根据铀矿科学钻孔岩心样品地球化学分析显示,基底变质岩成熟度较高,显示高镁铁、富硅、富铝,低钠钾的特征,原岩总体呈中酸性。变质岩整体表现出相对富集Ba、U、Rb、K、Th等元素,亏损Nb、Sr、P、Ti等元素;轻、重稀土元素分馏较为明显,且轻稀土相对富集、重稀土相对亏损;δEu为0.6～1.1,平均为0.7,小于1,表现为负异常;δCe为2.9～3.9,平均为3.4,表现为正异常。根据变质岩稀土元素北美页岩标准化(NASC)蛛网图显示,样品稀土元素含量与北美页岩(NASC)含量相近,推测原岩具有沉积岩的特征。主量元素分布特征表明相山铀矿田基底变质岩原岩成分复杂,推测其原岩主要为一套陆源海相沉积泥质岩、砂岩及粉砂岩系列的浅变质作用类型的陆源碎屑岩,主要有岩屑砂岩、富镁沉积岩、泥质碳质硅质岩,可能有部分火山凝灰岩。根据主微量构造判别图,推测相山基底变质岩其原岩为大陆岛弧构造环境下形成的沉积碎屑岩。     

一种刚玉夕线钾长片麻岩的岩石学矿物学特征及形成环境

刚玉夕线钾长片麻岩是产于新太古代迭布斯格岩群中的一种低Si、高Al、高K的特殊岩石，主要包括刚玉钾长金红石片麻岩、黑云夕线钾长金红石片麻岩2种岩石组合，呈互层状产出。刚玉、夕线石和钾长石是通过白云母的变质分解和白云母 SiO2的变质反应而生成的。形成温度约为720—760℃，压力约为0．6-0．8GPa。由于温度和压力稍高，岩石中已开始出现重熔钾长石细脉。环带状次生白云母的出现属退变质反应。变质程度为区域中高温变质作用，达高角闪岩相，与围岩的变质程度一致。其原岩是在较短的稳定条件下由富K、富Al的花岗质岩石经强烈风化搬运进入大陆边缘沉积盆地，再经化学分解和沉积作用而形成的不同的原岩组合。     

北祁连山东段海原一带海原群变质岩原岩恢复及其构造背景

对海原群的岩石组成、原岩性质和构造环境的研究表明,海原群中云母片岩、石英片岩的原岩是泥质岩、杂砂岩等,大理岩、石英岩的原岩为白云岩-灰岩、石英砂岩或硅质岩,绿片岩和角闪岩的原岩为基性火山岩或次火山岩,蛇纹岩的原岩为超镁铁质岩.变质沉积岩的形成构造环境判别结果表明,它们形成于活动大陆边缘,介于岛弧与稳定陆缘之间.变质基性火山岩主要亦介于岛弧拉斑玄武岩与板内玄武岩之间,部分显示洋脊玄武岩的特征.认为海原群形成于岛弧-弧后盆地的构造环境.     

威海地区超高压变质花岗片麻岩锆石U-Pb定年和氧同位素研究

在苏鲁超高压变质带东北端山东威海地区皂埠镇发现锆石δ18O值低至-7.8‰左右的花岗片麻岩, 与前人在苏鲁超高压变质带西南端江苏东海青龙山地区发现的锆石δ18O值为-7‰~-9‰左右的花岗片麻岩一致.对这些低δ18O值花岗片麻岩进行了锆石SHRIMP法UPb定年和系统的激光氟化法矿物氧同位素分析, 结果对低δ18O值锆石成因和花岗片麻岩的原岩性质提供了制约.研究得到: (1) 这些低δ18O值锆石以新元古代岩浆锆石为主, 但部分岩浆锆石在印支期超高压变质作用过程中发生了不同程度的重结晶作用.δ18O值为-7.08‰的岩浆核锆石UPb定年得到的花岗片麻岩原岩谐和年龄和不一致线上交点年龄分别为(760±49) Ma和(751±27) Ma, 变质谐和年龄和不一致线下交点年龄分别为(232±4) Ma和(241±33) Ma, 指示其原岩为新元古代花岗岩并经历了印支期变质作用; (2) 锆石δ18O值在局部范围内变化于-7.76‰~5.40‰之间, 低δ18O值岩浆锆石表明它们是从新元古代低δ18O值岩浆中直接结晶形成, 锆石δ18O值的局部变化表明其原岩岩浆的氧同位素组成具有不均一性, 指示低δ18O值岩浆源区物质曾经在地表与极度亏损18O的大气降水发生过不同程度的高温水岩反应; (3) 低δ18O值花岗片麻岩在印支期板块俯冲和折返过程中基本没有与外部发生显著的氧同位素交换, 在退变质作用过程中花岗片麻岩内部缓冲流体对原岩岩浆锆石的δ18O值影响不大.威海皂埠镇地区和东海青龙山地区的花岗片麻岩在原岩时代、变质时代和氧同位素组成等方面基本相同, 指示它们应具有相同的原岩性质, 并经历了相同的变质作用和水岩相互作用过程.因此, 极度亏损18O的新元古代双峰式基性-酸性岩浆岩可能分布于整个大别-苏鲁造山带.      

The Whole‐Rock Geochemical Composition of the Wudaogou Group in Eastern Yanbian,NE China–New Clues to Its Relationship with the Gold and Tungsten Mineralization and the Evolution of the Paleo‐Asian Ocean

The late Paleozoic Wudaogou Group, one of the oldest metamorphic units in the eastern Yanbian area, has important tectonic and metallogenic significance. Here, we provide new insights into their protoliths, tectonic setting of the metamorphic rocks and their relationships with the gold and tungsten mineralization, using new petrographic and whole‐rock geochemical data for various lithologies within the Wudaogou Group. The protolith of the metamorphic rocks of the Wudaogou Group was intermediate–basic volcanic rocks (e.g. basaltic andesite, trachyandesite, and basalt) and sedimentary rocks including argillaceous rocks, quartz sandstone, arkose and clayish greywacke, as well as pyroclastic sedimentary rock, covering tuffaceous sandstone. Before undergoing late Paleozoic epidote–amphibolite facies regional metamorphism, these protoliths were formed during the middle–late Permian in an island arc setting within a continental margin collage zone. Combined with the regional tectonic evolution, it can be speculated that the formation and the subsequent metamorphism of the protoliths of the metamorphic rocks from the Wudaogou Group were influenced by the change from subduction to collision of the Paleo‐Asian Ocean. Similarities of the rare earth element (REE) patterns and parameters among the metamorphic rocks within the Wudaogou Group, auriferous ores from the Xiaoxi'nancha gold (copper) deposit, and scheelites from the Yangjingou tungsten deposit, together with the favorable metallogenic element contents within the metamorphic rock series, imply that the Wudaogou Group could provide parts of metallic material for the gold and tungsten mineralization in the eastern Yanbian area, as exemplified by the Yangjingou deposit and Xiaoxi'nancha deposit, respectively. Further, the metamorphic sedimentary rocks, especially the metamorphic sandstones, quartz schists and quartz mica schists within the Wudaogou Group, have closer genetic relationships with the Yangjingou tungsten mineralization. However, the specific lithologies within this group which control the gold mineralization are still uncertain, and need further research.