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101.
C18固相膜萃取-气相色谱法测定饮用水中12种有机氯农药 总被引:13,自引:10,他引:13
利用C18固相萃取膜提取水样,气相色谱法(电子捕获检测器)测定饮用水中12种有机氯农药。对洗脱液、水样pH值、萃取压力等条件进行了优化选择,并与液-液萃取做了比较。结果表明,与液-液萃取相比,固相膜萃取具有操作简单、富集倍数高、节省溶剂和耗时短等优点,是萃取水中有机氯农药的有效方法。12种有机氯农药的回收率为85.97%~127.7%,相对标准偏差(RSD,n=5)为4.74%~12.2%,方法检出限为0.014~0.047μg/L。 相似文献
102.
Limo TANG Shanghong ZHANG Mingzhong YU Xingkui WANG 《国际泥沙研究》2006,21(4):272-280
1 INTRODUCTION The mechanism of particle movement in the flow is one of basic problems of sediment transport research. The conventional measurement approaches usually disturb the structure of the flow, consequently inducing errors. With the development of… 相似文献
103.
Temporal-spatial variations of euphotic depth of typical lake regions in Lake Taihu and its ecological environmental significance 总被引:5,自引:0,他引:5
ZHANG Yunlin QIN Boqiang HU Weiping WANG Sumin CHEN Yuwei CHEN Weimin 《中国科学D辑(英文版)》2006,49(4):431-442
Euphotic depth can be defined as the portion of wa- ter column that supports the net primary productivity. Its lower end is the critical depth, namely, the depth measured when the daily net primary productivity is zero[1]. In the ecosystems of oceans, lakes and rivers, phytoplankton live in the euphotic depth and euphotic depth is usually taken as the lower boundary, when studying the primary productivity and biomass of phytoplankton; therefore the corresponding depth is sometimes called the t… 相似文献
104.
Correlation of atmospheric visibility with chemical composition of Kaohsiung aerosols 总被引:2,自引:0,他引:2
Chung-Shin Yuan Chang-Gai Lee San-Ho Liu Jui-cheng Chang Ching Yuan Horng-Yu Yang 《Atmospheric Research》2006,82(3-4):663
The objective of this study was to investigate the correlation of visibility with chemical composition of Kaohsiung aerosols. Daytime visibility was observed around noon at two observation sites in metropolitan Kaohsiung, Taiwan in the years of 1999 and 2000. Both seasonal and diurnal variation patterns of visibility were observed in the region. Ambient aerosols were sampled and analyzed for 11 constituents, including water-soluble ionic species (Cl−, NO3−, SO4−2, NH4+, K+, Na+, Ca+2, and Mg+2) and carbonaceous contents (OC, EC, and TC), to characterize the chemical composition of Kaohsiung aerosols. Furthermore, a stepwise multiple linear regression model was developed to elucidate the influence of aerosol species on visibility impairments. The results showed that sulfate was the dominant species that affected both light scattering coefficient and visibility. On average, the percentage contributions of visibility degrading species to light scattering coefficient were 29% for sulfate, 28% for nitrate, 22% for total carbon, and 21% for PM2.5-remainder. An empirical regression model of visibility based on sulfate, nitrate, and relative humidity was also developed. The model showed that sulfate in PM2.5 was the most sensitive species to visibility variation, suggesting that the reduction of sulfate in PM2.5 could effectively improve the visibility of metropolitan Kaohsiung. During the investigation period, an event of Asian dusts intruded metropolitan Kaohsiung and dramatically increased the aerosol loadings, especially in the coarse particles. However, local visual air quality did not degrade accordingly during the Asian dust event because both visibility and light scattering coefficient are affected mainly by the fine particles. The results are discussed in detail in the paper. 相似文献
105.
Fog and rain water chemistry at Mt. Fuji: A case study during the September 2002 campaign 总被引:2,自引:0,他引:2
Koichi Watanabe Yusaku Takebe Nobuhiro Sode Yasuhito Igarashi Hiroshi Takahashi Yukiko Dokiya 《Atmospheric Research》2006,82(3-4):652
Measurements of fog and rain water chemistry at the summit of Mt. Fuji, the highest peak in Japan, as well as at Tarobo, the ESE slope of Mt. Fuji in September 2002. The pH of fog and rain water sampled at Mt. Fuji varied over a range of 4.0–6.8. Acidic fogs (pH < 5.0) were observed at the summit when the air mass came from the industrial regions on the Asian continent. The ratio of [SO42−]/[NO3−] in the fog water was lower at Tarobo than at the summit. High concentrations of Na+ and Cl− were determined in the rain water sampled at the summit, possibly because of the long-range transport of sea-salt particles raised by a typhoon through the middle troposphere. The vertical transport of sea-salt particles would influence the cloud microphysical properties in the middle troposphere. Significant loss of Mg2+ was seen in the rain water at the summit. The concentrations of peroxides in the fog and rain water were relatively large (10–105 μM). The potential capacity for SO2 oxidation seems to be strong from summer to early autumn at Mt. Fuji. The fog water peroxide concentrations displayed diurnal variability. The peroxide concentrations in the nighttime were significantly higher than those in the daytime. 相似文献
106.
辽宁深井承压水位潮汐响应函数的初步研究 总被引:1,自引:0,他引:1
介绍了辽宁省地震水动态监测网19口井固体潮汐响应函数的计算结果,基于M2波潮汐因子及其月离散相对误差,分析了各观测井潮汐响应函数对地壳应变的响应灵敏度、潮汐因子的动态稳定性和监测效能。结果表明:在所列19口观测井中,如果以M2波潮汐因子0.2m/10-9作为潮汐响应幅值的下限,则除甘沟子以外的18口井可用于潮汐响应函数的研究;如果以M2波潮汐因子的月离散相对误差20%作为选择观测井的上限,则除瓦房店楼房井、岫岩1井、周家井、丹东变电所井、牛四井、容2井和阜新市甘沟子等井以外的12口井可用于潮汐参数的动态特征研究。 相似文献
107.
宁波地震台数字垂直摆倾斜仪记录的EW、NS向固体潮在同一数量级,与理论固体潮有较大的差异,且与浙江省其它地区地震台的记录迥然不同。该台倾斜资料与海水潮汐关系密切,用其分钟值绘出的矢量图日规律性较强。本文对此作了初步分析与探讨。 相似文献
108.
A Large-Eddy Simulation and Lagrangian Stochastic Study of Heavy Particle Dispersion in the Convective Boundary Layer 总被引:4,自引:1,他引:4
Large-eddy simulation and Lagrangian stochastic dispersion models were used to study heavy particle dispersion in the convective boundary layer (CBL). The effects of various geostrophic winds, particle diameters, and subgrid-scale (SGS) turbulence were investigated. Results showed an obvious depression in the vertical dispersion of heavy particles in the CBL and major vertical stratification in the distribution of particle concentrations, relative to the passive dispersion. Stronger geostrophic winds tended to increase the dispersion of heavy particles in the lower CBL. The SGS turbulence, particularly near the surface, markedly influenced the dispersion of heavy particles in the CBL. For reference, simulations using passive particles were also conducted; these simulation results agreed well with results from previous convective tank experiments and numerical simulations. 相似文献
109.
龙门山国家地质公园飞来峰成因的新证据 总被引:1,自引:0,他引:1
近来发现四川彭州(原称彭县)、什邡一带的飞来峰是第四纪冰川作用形成的。笔者等在塘坝子、葛仙山等飞来峰的底界及周边,多次发现飞来峰是压在早更新世的冰水堆积层之上。葛仙山北寨门、丁家湾,什邡大垭口等剖面的地质现象,充分说明塘坝子、葛仙山等飞来峰是第四纪中更新世时“飞”来,压盖上去的。同时可见飞来峰与第四系之间是“冷接触”,找不到确切的断层证据。笔者等还用现有的区域地质调查资料及新的地质成果,编制了1:10万更新世时的彭县至汶川的地质剖面图,并设想了冰雪层掩盖情况。那时岷江尚未剥蚀下切,按现在标高计的5000m处,即在光光山、太子城之上约1000m的“天”上。当时应在该处出露的石炭系-二叠系石灰岩,就是塘坝子、葛仙山飞来峰的根部。塘坝子、葛仙山就是从那里被冰川作用剪切、从母体分离的石灰岩,滑动、随冰川固体流,滑移到彭县来的。笔者还从理论上阐述了塘坝子、尖峰顶、天台山等如此巨大的山体,能被冰川作用拔起、挖掉、推走的原因和根据。从而解释了飞来峰“飞”行的过程。顺理成章,合乎自然,揭开了飞来峰之迷。 相似文献
110.