河北丰宁隐爆角砾岩型银多金属矿床地质特征

河北丰宁银多金属矿床赋存于隐爆角砾岩体中,发育一组典型低温热液矿物组合的围岩蚀变,矿化为典型低温热液成因的黄铁矿-闪锌矿-方铅矿-黄铜矿硫化物组合;控矿隐爆角砾岩划分为震裂花岗岩相、震碎花岗岩相、熔浆角砾岩相和气爆角砾岩相4类;宏观、微观研究认为其中的硅质角砾由4次喷发作用形成;气爆形成的萤石化可确定赋矿空间的分布规律.     

An Overview of CCD Development at Lawrence Berkeley National Laboratory

Fully depleted, back-illuminated charge-coupled devices fabricated at Lawrence Berkeley National Laboratory on high-resistivity silicon are described. Device operation and technology are discussed, as well as the results on telescopes and future plans. This revised version was published online in July 2006 with corrections to the Cover Date.     

The behavior of iron,manganese and silicon in the Peconic River estuary,New York

The behavior of dissolved and particulate iron and manganese and dissolved silicon has been studied as a function of chlorinity in the Peconic River estuary, New York. This study sought to identify important geochemical processes in a relatively pristine estuary facing increasing anthropogenic impact.Dissolved iron behaved in the classical non-conservative manner exhibiting removal of nearly 80% at very low chlorinities, while particulate iron increased by a corresponding amount over the same chlorinity range. Dissolved manganese was enriched by up to 200% over its predicted concentration at low and intermediate chlorinities by desorption from suspended particulates and by a probable benthic flux. Dissolved silicon was enriched by up to 100% at low and intermediate chlorinities also from a probable benthic flux. These fluxes were estimated to be 5 μg cm^?2 day^?1 for dissolved manganese and 70 μg cm^?2 day^?1 for dissolved silicon.The quantity of both particulate iron and manganese increased at high chlorinities due to an influx of suspended inorganic particulates. In the intermediate to high chlorinity region, oxidation of sediment-derived manganese is believed to contribute to the observed increase in particulate manganese.Total iron was essentially conservative throughout most of the estuary, while total manganese was non-conservative presumably due to extensive remobilization of dissolved manganese from the sediments.     

Precise Determination of Silicon Isotopes in Silicate Rock Reference Materials by MC‐ICP‐MS

A HF‐free sample preparation method was used to purify silicon in twelve geological RMs. Silicon isotope compositions were determined using a Neptune instrument multi‐collector‐ICP‐MS in high‐resolution mode, which allowed separation of the silicon isotope plateaus from their interferences. A 1 μg g^‐1 Mg spike was added to each sample and standard solution for online mass bias drift correction. δ³⁰Si and δ²⁹Si values are expressed in per mil (‰), relative to the NIST SRM 8546 (NBS‐28) international isotopic RM. The total variation of δ³⁰Si in the geological reference samples analysed in this study ranged from ‐0.13‰ to ‐0.29‰. Comparison with δ²⁹Si values shows that these isotopic fractionations were mass dependent. IRMM‐17 yielded a δ³⁰Si value of ‐1.41 ± 0.07‰ (2s, n = 12) in agreement with previous data. The long‐term reproducibility for natural samples obtained on BHVO‐2 yielded δ³⁰Si = ‐0.27 ± 0.08‰ (2s, n = 42) on a 12 month time scale. An in‐house Si reference sample was produced to check for the long‐term reproducibility of a mono‐elemental sample solution; this yielded a comparable uncertainty of ± 0.07‰ (2s, n = 24) over 5 months.     

The teleconnection between marine silicon supply and desertification in China

Desertification has been notably expanding in China in the recent decade, especially in North China where dust/sand storm (DSS) frequently assaulted local communities. Analyses in marine ecology found that the earth ecosystem could be able to complement nutrient silicon for keeping sustain- able development of marine ecosystem, and decreasing CO2 concentration in the atmosphere; as a result, the area of desertification would be enlarged. Modern human being activities have resulted in constant changes in the amount of silicon transport from land into sea, leading to oversupply of nitrogen and phosphorus but silicon in seawater. The proportion of nitrogen, phosphorus and silicon was seriously im- balanced and the limitation of silicon for phytoplankton growth has become more serious. The silicon de- ficiency has damaged the marine ecosystem in coastal regions and slowed down the carbon sedimentation in the atmosphere of the world. The authors believe that the continual discharge of CO2 into the atmos- phere is the cause for the global warming including marine water temperature rise. Consequently, the earth ecosystem would have to trigger its complementary action to resume to the silicon balance by algae bloom in seawater for reducing air and water temperatures. In order to complement nutrient silicon into the sea, the ecosystem would transport silicon via the atmosphere; therefore, the desertification in the in- ner land is a natural reaction. As marine phytoplankton booming can reduce the CO2 concentration in the atmosphere and further ease the green-house effect, during this process, a large amount of silicon are de- manded by the ecosystem, which human being are unable to stop desertification from happening but slow down the progress and ease the risk. Therefore, as an important role in earth ecosystem, people should reduce the CO2 discharge into the atmosphere first; then, the normal function of river transporting silicon must be restored. In this way, the CO2 in the atmosphere can be kept in balance, the global warming slowed down, marine ecosystem development sustained, the drought in inner land eased, and the desert gradually under-controlled.     

氮、磷、铁、硅对简单双眉藻生长的影响

用单因子对比实验和正交实验的方法研究了氮、磷、铁和硅对简单双眉藻生长的影响。结果表明:简单双眉藻对于硝酸钠和尿素均能很好地利用,其相对生长常数无显著差异,对柠檬酸铁和三氯化铁的利用亦无显著差异,FeC6H5O7-Fe的适宜浓度为0.1～0.5mg/L;Na2SiO3-Si的适宜浓度为0.8～1.6mg/L。正交实验表明,简单双眉藻氮、磷、铁、硅的最佳浓度(mg/L)配比为6.6∶0.66∶0.1∶0.4。     

EXAMINATION OF SILICATE LIMITATION OF PRIMARY PRODUCTION IN JIAOZHOU BAY, CHINA I. SILICATE BEING A LIMITING FACTOR OF PHYTOPLANKTON PRIMARY PRODUCTION

ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｐｒｏｄｕｃｔｉｏｎｏｆｐｈｙｔｏｐｌａｎｋｔｏｎｉｓｔｈｅｆｉｒｓｔｔａｃｈｅｉｎｔｈｅｐｒｏｄｕｃｔｉｏｎｂｙｍａｒｉｎｅｏｒｇａｎｉｓｍｓａｎｄｉｎｔｈｅｍａｒｉｎｅｆｏｏｄｃｈａｉｎ .Ｋｎｏｗｌｅｄｇｅｏｆｐｒｉｍａｒｙｐｒｏｄｕｃｔｉｏｎｉｎｍａｒｉｎｅｗａｔｅｒｓｉｓｐｒｅｒｅｑｕｉｓｉｔｅｆｏｒｅｘｐｌｏｉｔａｔｉｏｎａｎｄｍａｎａｇｅｍｅｎｔｏｆｔｈｅｏｃｅａｎ’ｓｌｉｖｉｎｇｒｅｓｏｕｒｃｅｓ.Ｔｈｅｐｒｉｍａｒｙｐｒｏｄｕｃｔｉｏｎｉｎｍａｒｉｎ…     

微波消解-电感耦合等离子体发射光谱法测定高碳铬铁中硅锰磷

高碳铬铁需要用强氧化性酸或混合酸在高温条件下才能分解或采用碱熔法处理样品,但操作比较繁琐并引入大量的钠离子,干扰待测元素的检测。微波消解技术与电感耦合等离子体光谱（ICP-AES）结合用于测定高碳铬中的铁已有报道。本文在文献方法的基础上,建立了ICP-AES同时测定高碳铬铁样品中Si、Mn、P的方法。采用硝酸消解高碳铬铁中易分解部分,再用高氯酸和氢氟酸消解碳化物和硅化物,减少了高氯酸的用量,消解过程平稳安全。利用高碳铬铁标准物质建立标准曲线,Y和In作内标,Si、Mn、P的检出限分别为0.0017%、0.0025%和0.0033%。用高碳铬铁标准物质GSB 03-1562—2003、GSB 03-1058—1999和GSB 03-1059—1999验证方法的精密度及准确度,11次测定的相对标准偏差（RSD）在0.8%~6.0%之间,不同含量标准物质测定结果与标准值吻合。本方法微波消解样品完全,操作安全简单,准确度高,适用于高碳铬铁样品的多元素同时分析。     

电感耦合等离子体发射光谱法测定铬矿石中的二氧化硅

以过氧化钠为熔剂,经高温熔融-热水提取-盐酸酸化前处理样品,选用金为内标元素,电感耦合等离子体发射光谱法测定铬矿石中的二氧化硅。试验了熔融试样时引入的基体元素钠对被测元素的干扰情况,结果表明,钠含量高于300 mg/L时,二氧化硅的回收率均低于92.5%。采用金内标法有效克服了基体效应及仪器波动产生的影响,改善和提高了准确度和精密度。二氧化硅的检出限为0.0075 mg/L,测定范围为0.025%～10.0%。对铬矿石标准物质进行测定,结果与标准值一致,方法精密度(RSD,n=9)小于2%。与常规化学分析法进行比对试验,二氧化硅的测定值吻合较好,但克服了常规化学分析方法步骤繁琐、耗时长、工作量大的不足,提高了工作效率。本方法也可用于同时测定铬矿石中铝、铁、钙、镁、磷等主次量成分。     

广西4大海湾红树林区硅含量的变化特征及其影响因素

利用2007年12月至2008年11月对广西沿海4个海湾红树林区进行系统调查的数据资料,分析不同海湾红树林区Si含量的变化特征及其与环境因素的关系。结果表明,广西海湾红树林区Si含量较高,年平均值高达52.26μmol·dm-3,明显高于20世纪80年代河口区的30.83μmol·dm-3;在季节上主要依赖于径流的变化而呈夏高、冬低,春、秋季适中的特征,区域分布亦具有随S下降而增加,随硅藻占浮游植物比例上升而下降的良好规律,依次排列为廉州湾>钦州湾>珍珠湾>铁山港红树林区。相关分析显示,影响研究海区Si含量变化的主要因素是陆源径流与海水的物理混合过程,其次是生物作用,有机体分解的化学过程影响相对较小。Si与N、P营养盐的关系极为密切,其中Si与N的同源性极好,4个季节均达到了非常显著(p值<0.01)的正相关水平;而Si与P含量之间却出现明显分区现象,海湾特征尤为突出。