江西省鄱阳湖地区地下水中SiO2的分布特征及开发评价

论证了江西省鄱阳湖地区的地质环境背景和地下水中ＳｉＯ２的背景与分布特征及其与地下水的含水介质成分,地下水的ＣＯ２的含量,地下水的酸碱度,氧化还原环境,有机物质之间的关系,结果表明,地下水的ＳｉＯ２含量与含水介质中的ＳｉＯ２和有机质的含量,氧化还原环境有关,与地下水的ｐＨ值和ＣＯ２含量相关性非常显著,相关系数分别为－０．２８（Ｐ〈０．００１）,０．２９（Ｐ〈０．００１）,偏硅酸矿泉水资源丰富,有较好     

川东地区二叠系结核状、条带状及团块状硅岩成因

川东地区二叠系结核状、条带状和团块状硅岩发育,主要分布于茅口组上段及吴家坪组,夹于石灰岩层间或层内。通过野外露头观察、室内薄片鉴定以及主量元素、微量元素和稀土元素分析,对广元长江沟、旺苍双汇、宣汉立石河和巫溪尖山的二叠系硅岩进行了岩石学及地球化学研究,重点分析了硅质来源,并对其成因机制进行了探讨。结果表明,研究区硅岩形态多样、分布不均,硅岩中见残余的石灰岩;硅质成分主要为玉髓及微晶石英、灰质硅岩中玉髓"侵入"方解石、相邻石灰岩中少量生屑被硅化。硅岩的化学成分以SiO2为主(52.79%～99.21%,平均为85.18%),Fe/Ti值、(Fe+Mn)/Ti值及Al/(Al+Fe+Mn)值反映其形成与热水活动有关;硅岩的部分微量元素含量与地壳中该元素的平均含量差异明显,Co/Ni值与Th/U值较低;稀土元素总量低,Ce负异常,LREE/HREE值低,δEu值相对较高。综合分析认为研究区二叠系硅岩为交代成因,硅质以热水来源为主,玄武岩淋滤及上升流提供了部分硅质。复合来源的硅质通过同生断裂、表层淋滤及上升流进入碳酸盐沉积物中,在不同的成岩阶段交代碳酸盐沉积物(岩),形成了顺层面或层内分布的结核状、条带状及团块状硅岩。     

铬天青S光度法及非线性拟合测定高纯硅中微量铝

铬天青S光度法是硅中铝含量的测定方法之一,该方法的标准曲线大多采用不过零点的线性拟合,导致低铝含量测定误差大。为提高方法准确度并降低方法检出限,研究了铝标准曲线低浓度部分的拟合问题,探讨了不同拟合模型对检测结果准确度的影响。实验结果表明,不同浓度铝标准液的吸光度在0~0.3 μg/mL范围内并不满足一次函数线性关系,采用三次函数关系y=-17.45230x³+10.42883x²+1.04047x (y为扣空白的吸光度,x为铝的质量浓度)拟合能获得良好结果,其相关系数R²为0.99975。利用已知铝含量的硅试液检验该公式,其相对标准偏差(RSD)为2.55%。样品中铝的测定值与电感耦合等离子体发射光谱法测定值吻合。该法可以显著提高低浓度的铝测定的准确性,可用于测定高纯硅中含量在0.55 μg/g以上的铝杂质。     

黄河水及其悬浮物硅同位素组成的变化特征及其地质环境意义

2005年7月沿黄河干流及4条主要支流系统采集了28个水样,对水及悬浮物的化学组成、矿物组成、水化学成分和硅同位素组成进行了综合分析.黄河水中悬浮物在不同站点的浓度差异悬殊,由8.8～302120mg/L不等,与黄河两岸人类活动(水库、牧场、农田)和自然环境变化(流域岩性、植被覆盖程度)关系密切.悬浮物中SiO2含量介...     

电感耦合等离子体发射光谱法测定锌精矿中的二氧化硅

采用碱熔酸化方法处理样品,选用金为内标元素,电感耦合等离子体发射光谱法测定锌精矿中的二氧化硅。研究了熔融试样时引入的基体元素钠对被测元素的干扰情况,结果表明基体效应明显存在,且随着钠量的增加,基体效应显著增强,仪器稳定性严重降低,影响测定结果的准确度。内标校正法有效克服了基体效应及仪器波动产生的影响。研究结果表明,二氧化硅的检出限为0.006 3 mg/L,测定范围为0.02%~10%,对矿石标准物质进行测定,结果与标准值一致,方法精密度(RSD,n=5)小于2%。     

辽宁白云金矿床地质特征及深部找矿的新认识

白云金矿区总体构造为EW走向的线性褶皱构造,金矿体受EW向展布的脆-韧性剪切带控制;辽河群地层是矿源层,矿体赋存于辽河群大石桥组三段及盖县组地层和燕山期的岩脉中,矿化对岩石无明显选择性,矿床具有明显的韧性剪切带特征;硅、钾蚀变带加上黄铁矿化是找金矿的最显著标志;深部矿化连续,具较好的找矿前景.     

荣成大疃刘家铍矿矿物赋存状态

大疃刘家铍矿铍元素主要以羟硅铍石单矿物赋存在矿石中。以羟硅铍石单矿物存在的BeO占79.45%;少部分分散在其他矿物中,以赤铁矿、褐铁矿中BeO含量较高,其次是绢云母、重晶石等。BeO呈分散状态占20.55%,主要集中在绢云母中,这是由于矿石中绢云母含量高所致,分散状态的BeO无法回收。根据矿石中有用矿物和脉石矿物组合,矿石类型为羟硅铍石-绢云母-碳酸盐岩-长石-石英型铍矿石。     

EXAMINATION OF SILICATE LIMITATION OF PRIMARY PRODUCTION IN JIAOZHOU BAY, CHINA——I. SILICATE BEING A LIMITING FACTOR OF PHYTOPLANKTON PRIMARY PRODUCTION

Jiaozhou Bay data collected from May 1991 to February 1994, in 12 seasonal investigations, and provided the authors by the Ecological Station of Jiaozhou Bay, were analyzed to determine the spatiotemporal variations in temperature, light, nutrients (NO3^--N, NO2^--N, NH4^ -N, SIO3^2--Si, PO4^3--P), phytoplankton, and primary production in Jiaozhou Bay. The results indicated that only silicate correlated well in time and space with, and had important effects on, the characteristics, dynamic cycles and trends of, primary production in Jiaozhou Bay. The authors developed a corresponding dynamic model of primary production and silicate and water temperature. Eq. ( 1 ) of the model shows that the primary production variation is controlled by the nutrient Si and affected by water temperature; that the main factor controlling the primary production is Si; that water temperature affects the composition of the structure of phytoplankton assemblage; that the different populations of the phytoplankton assemblage occupy different ecological niches for C, the apparent ratio of conversion of silicate in seawater into phytoplankton biomas and D, the coefficient of water temperature‘s effect on phytoplankton biomass. The authors researched the silicon source of Jiaozhou Bay, the biogeochemical sediment process of the silicon, the phytoplankton predominant species and the phytoplankton structure. The authors considered silicate a limiting factor of primary production in Jiaozhou Bay, whose decreasing concentration of silicate from terrestrial source is supposedly due to dilution by current and uptake by phytoplankton; quantified the silicate assimilated by phytoplankton, the intrinsic ratio of conversion of silicon into phytoplankton biomass, the proportion of silicate uptaken by phytoplankton and diluted by current; and found that the primary production of the phytoplankton is determined by the quantity of the silicate assimilated by them. The phenomenon of apparently high plant-nutrient concentTations but low phytoplankton biomass in some waters is reasonably explained in this paper.     

Potentially mobile pools of phosphorus and silicon in sediment from the Bay of Brest: Interactions and implications for phosphorus dynamics

Competitive interactions between silicate and phosphate at ligand exchange sites in the sediment surface layer may increase the release of phosphorus (P) from the sediment into the water column. In this study, the role of silicon (Si) in the release of P from the sediment surface layer was studied in a marine estuarine environment, the Bay of Brest, with the aid of a sequential sediment fractionation procedure developed for P, and the addition of inorganic or diatom-bound Si to surface sediment samples in vitro. The potentially mobile pools of P in the surface sediment (loosely bound P + Fe/Al-bound-P) amounted to 5.0 μmol g⁻¹ dry sed., 42% of the total extractable and 33% of the total amount of P in the sediment, while the similarly extracted pools of Si were bigger (ca. 20 μmol g⁻¹ dry sed., 50% of the total extractable Si). Additions of inorganic Si increased the concentration of dissolved P in the sediment interstitial water in a bottle experiment, and the addition of both inorganic Si and cultivated diatoms to intact sediment cores increased the outward flux of dissolved P. Model calculations based on the regression equation from the bottle experiment and Si and P water column data showed that the sedimentation of spring diatoms could cause Si pulses to the sediment which would produce a P flux to the water column of ca. 44 μmol m⁻² d⁻¹. Field data from the bay show that in spring, decreases in P and Si and an increase in chl a due to diatom production are often followed by a small separate P peak which may be caused by Si-induced P fluxes from the sediment surface.