全新世岱海流域化学风化及其对气候事件的响应

通过对岱海 12.08 m沉积岩芯 210Pb和 AMS- 14C精确定年及地球化学、物理指标的综合分析,重建了包括 8.2 ka冷期、中世纪暖期 (MWP)和小冰期 (LIA)等典型气候事件在内的全新世以来所经历的化学风化及其环境演化过程.全新世早-中期 (9.0～ 3.5 ka),岱海流域处于温暖湿润气候环境,主要环境特征表现为流域化学风化显著增强、生物生产力逐步提高、湖泊水位大幅度抬升.在 7.90～ 8.25 ka期间存在一次冷气候事件,其发生时间与来自湖沼、海洋、生物组合和极地冰芯等在内的全球环境记录基本一致,具体表现为流域化学风化减弱、湖泊生产力降低以及湖泊水位下降. 2.5 ka以来,岱海沉积物中环境指标的显著变化,表明进入气候波动更频繁的新冰期.岱海沉积物中的指标变化也展示了本世纪以来的气候增暖过程,但其化学风化强度还没有达到 MWP的程度.     

Constraints from Thorium/Lanthanum on Sediment Recycling at Subduction Zones and the Evolution of the Continents

Arc magmas and the continental crust share many chemical features,but a major question remains as to whether these features arecreated by subduction or are recycled from subducting sediment.This question is explored here using Th/La, which is low inoceanic basalts (<0·2), elevated in the continents(>0·25) and varies in arc basalts and marine sediments(0·09–0·34). Volcanic arcs form linear mixingarrays between mantle and sediment in plots of Th/La vs Sm/La.The mantle end-member for different arcs varies between highlydepleted and enriched compositions. The sedimentary end-memberis typically the same as local trench sediment. Thus, arc magmasinherit their Th/La from subducting sediment and high Th/Lais not newly created during subduction (or by intraplate, adakiteor Archaean magmatism). Instead, there is a large fractionationin Th/La within the continental crust, caused by the preferentialpartitioning of La over Th in mafic and accessory minerals.These observations suggest a mechanism of ‘fractionation& foundering’, whereby continents differentiate intoa granitic upper crust and restite-cumulate lower crust, whichperiodically founders into the mantle. The bulk continentalcrust can reach its current elevated Th/La if arc crust differentiatesand loses 25–60% of its mafic residues to foundering. KEY WORDS: arc magmatism; continental crust; delamination; thorium; sediment subduction     

喀斯特山区溪流上覆水—孔隙水—沉积物中不同形态氮的赋存特征及其迁移——以麦西河为例

选取贵州百花湖入湖支流麦西河为对象,研究了上覆水—孔隙水—沉积物体系氮的形态差异,结果表明:麦西河上覆水中,以硝态氮(NO-3-N)为主,氨态氮(NH+4-N)次之,亚硝态氮(NO-2-N)最低;孔隙水中,溶解无机氮中以NH+4-N为主, NO-3-N次之, NO-2-N最低;沉积物中,总氮(TN)的含量为1110.67～4413.16mg/kg;固定态铵含量为34.56～170.05mg/kg,占TN的1.47%～6.25%;可交换态氮以NH+4-N为主, NO-3-N次之, NO-2-N最低。孔隙水NH+4-N是上覆水NH+4-N的2.65～19.51倍,上覆水NO-3-N是孔隙水NO-3-N的7.14～20.43倍。沉积物TN与孔隙溶解水无机氮(DIN)、孔隙水NH+4-N、沉积物可交换态氮和沉积物可交换性NH+4-N呈显著正相关;在沉积物中,可交换性NO-3-N与可交换性NH+4-N及可交换态氮呈显著正相关,可交换性NH+4-N与可交换态氮呈极显著正相关;孔隙水溶解无机氮与孔隙水NH+4-N呈极显著正相关。麦西河不同介质中氮的迁移关系则表现为:由于浓度梯度,上覆水中的NO-3-N扩散到孔隙水中,进而累积到沉积物中;沉积物的可交换性NH+4-N,进入孔隙水,最终扩散到上覆水中。      

开心岭二叠纪地层中铁矿化沉积凝灰岩的发现及找矿意义

开心岭地区位于青藏高原腹地北羌塘构造区,在该地区二叠纪地层中新发现含砾晶屑岩屑铁矿化沉积凝灰岩,对该地层完整采样,并对采集的样品进行专门的实验测试分析。样品显微镜薄片鉴定,具玄武质岩屑,凝灰质岩屑,晶屑主要为石英和长石;化学分析结果TFe为13.80%;X射线衍射分析结果,赤铁矿6%,针铁矿17%,石英16%,斜长石47%,伊利石3%,方解石6%,闪石2%,绿泥石2%。光谱半定量检测分析结果,Ti为0.7%;电子探针检测分析结果,赤铁矿:形态为完整或不完整的几何体和沿其它矿物边部成封闭与局部的丝带,钛铁矿为相对规则的棒状,磷灰石为规则的六边形和已经磨圆的半圆形。激光拉曼光谱分析结果,针铁矿,含磁铁矿。对上述分析结果研究认为,二叠纪开心岭地区可能存在重要的岩浆喷发作用,原始岩浆含铁较高,这可能是该地区金属矿床的物质来源,下一步宜加强该地区的找矿工作。     

三峡工程大江截流水文泥沙监测规划

鉴于三峡工程大江截流是一项复杂的系统工程,具有水深大,流量大,抛投量大和截流期不断航等显著特点。水文泥沙监测作为其重要的组成部分,监测导流与截流过程中水流泥沙和水下地形的变化,为截流设计优化,调整施工方案与措施等提供科学的决策依据,同时也为导流明渠分流与通航,围堰度汛,截流水力学试验研究及水文预报,水文分析计算等提供水文原型观测资料。本文介绍了水文泥沙监测的目的、任务和水文数据采集,传输,处理与信     

Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.     

基于HJ-1遥感数据的矿区水体污染监测与分析——以龙岩紫金山金铜矿为例

矿产资源的持续开采与加工利用使得矿区周边水资源受到的污染日趋严重,急需采用先进技术对水污染进行监测分析,遥感技术是水环境监测最为有效的技术之一。利用国产环境一号小卫星多光谱遥感影像数据,针对福建省龙岩市紫金山矿区不同时相的数据进行水质遥感监测。利用近红外单波段阈值分割法提取悬浮物浓度信息,基于矿区酸碱性水体光谱曲线特性采用342波段假彩色合成影像,采用SVM分类方法进行分类,判别矿区水体酸碱性以及分析水体受污染程度变化和污染源。结果表明,研究区汀江水体2008年呈现碱性,2010年呈现弱碱性,水质在研究时段内得到一定的改善,但在选矿厂与矿区附近的水体中仍含有大量重金属沉积物。     

城市河道黑臭底泥对挺水植物光合荧光特性的影响

城市河道黑臭现象日益严重,探讨常见湿地植物在黑臭底泥中的生长,有利于为河道修复物种选择提供科学依据.研究黑臭底泥对3种常见湿地植物——菖蒲(Acorus calamus)、美人蕉(Canna indica)及慈姑(Sagittaria sagittifolia)生长状况和叶片叶绿素荧光参数的影响.结果表明:菖蒲和美人蕉在第30~40 d时生物量增量明显降低,慈姑的生物量增量在整个实验中持续增加;通过比较3种湿地植物的荧光参数可知,菖蒲和美人蕉的光化学淬灭系数(q P)、相对光合电子传递速率(r ETR)值在第10 d时达到最大,分别为41.33μmol/(m2·s)和68.60μmol/(m2·s),后30 d一直下降;慈姑q P、r ETR值在第30 d时增加;在第40 d时,美人蕉q P值下降,非光化学淬灭系数(q N)值上升,叶片有较强的热耗散能力,而菖蒲的q P、q N值同时下降,黑臭底泥对菖蒲叶片的光合系统PSⅡ造成伤害.这说明黑臭底泥对菖蒲和美人蕉的光合能力产生较长期抑制,而慈姑可较快适应黑臭底泥的胁迫.因此利用湿地植物修复黑臭河道时,可优先选择慈姑,其次是美人蕉,最后是菖蒲.     

西藏普莫雍错不同岩芯环境指标的对比研究及其反映的近200年来环境变化

在西藏南部普莫雍错不同位置处采集了四支岩芯沉积物,对其中一支利用~(210)pb和~(137)Cs方法建立了沉积物的年代序列,并对其他三支岩芯的上部沉积物进行了总有机碳、无机碳、粒度及化学元素含量的分析.结合沉积物年代,对不同岩芯的环境代用指标进行对比,讨论了该地区近200年来的环境变化状况.结果表明,不同位置处采集的岩芯其环境指标变化趋势在整体上具有一定的可比性,但在细节变化与环境指标的数值上仍具有明显的差异,显示了湖泊内部沉积状况的空间差异性,这可能是由于采样点水深、水下地形以及与主要补给河流距离的不同而造成的.PY04岩芯环境指标显示普莫雍错湖区环境在约1900AD之前较为稳定;在约1900-1940AD之间湖区环境波动加剧,地表侵蚀增强,沉积速率加快;湖区环境在1940AD左右发生了明显的变化,温度显著升高,沉积物粒度增大,湖泊处于退缩状态,表明湖泊环境向暖干化方向发展.     

湖泊疏浚堆场淤泥污染及潜在生态风险评价

疏浚淤泥内通常含有不同类型的有毒有害物质,在堆场直接堆放过程中可能会对周围环境产生有害影响.本文针对太湖及巢湖相应疏浚堆场内淤泥进行研究,探讨淤泥中重金属、多环芳烃以及多氯联苯等污染物含量及潜在生态风险;根据重金属的风险指数法和持久性有机污染物的风险商法,对各污染物的潜在生态风险进行定量分析.研究结果表明,太湖白旄堆场以及孔湾堆场淤泥内重金属及多环芳烃含量较小,潜在生态风险较低;巢湖南庄堆场淤泥内各类有害物质含量较大,种类较多,对于周围环境具有较高的潜在生态威胁.多氯联苯则在各个疏浚堆场淤泥中具有很高的积累量,潜在生态风险较高,应引起管理者的重视.