Hydrogeochemical controls on surface and groundwater chemistry in naturally acidic, porphyry-related mineralized areas, southern Rocky Mountains

In southern Rocky Mountains, catchments characterized by acidic, metalliferous waters that are relatively unaffected by human activity usually occur within areas that have active or historical mining activity. The US Geological Survey has utilized these mineralized but unmined catchments to constrain geochemical processes that control the surface- and ground-water chemistry associated with near surface acid weathering as well as to estimate premining conditions. Study areas include the upper Animas River watershed, Lake City, Mt. Emmons, and Montezuma in Colorado and Questa in New Mexico. Although host-rock lithologies range from Precambrian gneisses to Cretaceous sedimentary units to Tertiary volcanic complexes, mineralization is Tertiary in age and associated with intermediate to felsic composition, porphyritic plutons. Pyrite is ubiquitous. Variability of metal concentrations in water is caused by two main factors： mineralogy and hydrology. Parameters that potentially affect water chemistry include： host-rock lithology, intensity of hydrothermal alteration, sulfide mineralogy and chemistry, gangue mineralogy, length of flow path, precipitation, evaporation, and redox conditions. Springs and headwater streams have pH values as low as 2.5, sulfate up to 3700 mg/L and high dissolved metal concentrations （for example： Al up to 170 mg/L; Fe up to 250 mg/L; Cu up to 3.5 mg/L and Zn up to 14 mg/L）. With the exception of evaporative waters, the lowest pH values and highest Fe and Al concentrations occur in water draining the most intense hydrothermally altered areas consisting of the mineral assemblage quartz-sericite-pyrite. Stream beds tend to be coated with iron floc, and some reaches are underlain by ferricrete. When iron-rich ground water interacts with oxygenated waters in the stream or hyporheic zone, ferrous iron is oxidized to ferric iron, which is less soluble, leading to the precipitation of iron oxyhydroxides.     

Site Effects Study in the Serravalle Village (NE Italy) by Means of Spectral Ratios Analyses Relatively to Multiple Reference Sites

The area of Serravalle, sited in the northern part of the town of Vittorio Veneto (TV), NE Italy, has been the target of a seismic microzonation campaign. 10 seismic stations have been deployed for a 7 months period to record in continuous mode. Three stations were installed on bedrock outcrops and seven on sedimentary sites with variable cover thickness. Spectral analyses have been performed on the collected data-set using the Generalized Inversion Technique (GIT, e.g. Andrews, 1986). In particular, spectral ratios have been calculated for each station relatively to the average of the three reference, bedrock sites. The spectral ratios provide quantitative estimates of the seismic motion amplifications which occur in each of the monitored sites. Two sites show high values of amplification, 5 times larger than signal amplitude at the reference sites, in correspondence of well discernible peak frequencies of 5 Hz. Results for the other stations show smaller amounts of site amplification spreading over a broad range of frequencies. Sites where the highest amplifications were recorded all lie on the left bank of the Meschio River and in areas farther away from its outlet into the plain correlating with the presence of thick layers of Quaternary deposits.     

Ultra-rapid landscape response and sediment yield following glacier retreat, Icy Bay, southern Alaska

The páramo is a neotropical alpine ecosystem that covers more than 75,000 km² of the northern Andes of Colombia, Ecuador, Venezuela, and Peru. It provides important environmental services: more than 10 million people in the Andean highlands benefit from the water supply and regulation function, which is attributed to the volcanic soils that underlie the ecosystem. The soils are also major carbon sinks of global significance. Severe land use changes and soil degradation threaten both the hydrology and carbon sink function. Nevertheless, soil genesis and properties in the páramo is rather poorly understood, nor are their ecological functions well documented. The impact of the geomorphology of the páramo on soil genesis was studied in the rio Paute basin, south Ecuador. Two toposequences were described and analysed. In each toposequence, four pedons were selected representing summit, backslope, undrained plain situation, and valley bottom positions in the landscape. The soils are classified as Hydric Andosols in the World Reference Base for Soil Resources and Epiaquands or Hydrudands in Soil Taxonomy. They are very acidic and have a high organic matter content, high P deficiency, and Al toxicity. Their water content ranges from 2.64 g g^− 1 at saturation, down to 1.24 g g^− 1 at wilting point, resulting in a large water storage capacity. Two major soil forming processes are identified: (1) volcanic ash deposition and (2) accumulation of organic carbon. Volcanic ash deposits may vary in depth as a result of regional geomorphological factors such as parent material, orientation, slope, and altitude. Organic carbon accumulation is an interaction of both waterlogging, which depends on the position in the landscape, and the formation of organometallic complexes with Al and Fe released during volcanic ash breakdown. Despite the high variability in parent material and topography, the soil is characterised by a notable homogeneity in physico-chemical properties. Statistical analysis reveals that only topographic location has a slight but significant influence on soil pH as well as the organic matter content, saturated conductivity and water retention at high pressure. Finally, the exceptional properties of these soils provide useful insights to improve classification of the Andosols reference group of the FAO World reference Base for Soil Resources.     

鄱阳盆地构造—沉积特征及其演化史

 鄱阳盆地是发育在江南—九岭和怀玉—官帽基底拆离造山带上的白垩-古近纪张扭性断陷盆地,明显受近南北走向的赣江走滑断裂系和前白垩系逆冲断裂系晚期反转的双重因素控制,呈“两坳夹一隆”的区域构造格局。受赣江、进贤—石门街走滑断裂夹持的南昌凹陷,呈近南北向凹凸相间展布格局。进贤—石门街走滑断裂以东地区,“南断北超”型断陷自南而北由北东走向渐转为北北东向展布,其源于晚印支-燕山期北东向逆冲断裂在晚期的反转作用,西缘和北部受赣江断裂系东枝走滑断裂影响明显而发生转向。鄱阳盆地经历了早白垩世晚期(冷水坞组沉积期)拉分盆地、晚白垩世早-中期(周家店组—南雄组沉积早期)走滑张扭断(坳)陷盆地、晚白垩世晚期(南雄组沉积中-晚期)走滑伸展盆地和古近纪坳陷盆地等演化阶段,东南部断陷区(江埠—二甲村凹陷)由于喜马拉雅期的隆升剥蚀而只残存周家店组早期坳陷和周家店组中期—南雄组中期断陷两个发育阶段的沉积。     

河北省永久性GPS参考(网)站建立的研究与探讨

重点探讨了如何利用VRS技术在河北省区域内建立永久性参考站,如何进行数据的采集与管理,如何为GPS用户提供参考站数据等技术问题。     

云南思茅盆地二叠纪层序格架与生储盖研究

根据层序界面的特点、凝缩段的组成,思茅盆地二叠系可分为2个Ⅱ级层序、9个Ⅲ级层序.在此基础上,探讨了层序格架与油气生储盖的关系可分为2个二级层序界面为一构造侵蚀不整合层序界面,是极好的储集场所.此时西部盆地中沉积物已经变质,与生储盖关系不大;而东部地区以开阔碳酸盐台地为主,低位体系域、海侵体系域和高位体系域以形成储集层为主.第2个二级层序由海侵-高位体系域所构成.海侵体系域由龙潭组下部所组成,在普洱西部崖子以西为深水盆地（含斜坡）环境,以东为浅海环境,邻近东部古陆区为滨海环境.无论盆地或浅海,岩性以深灰-灰黑色泥岩为主,生烃性能极好.高位体系域可以分为早期高位体系域和晚期高位体系域.早期高位体系域由龙潭组上部层位组成,西为浅海相砂岩、火山岩等,可作储层;东为滨海平原,下部以深灰、灰黑色泥岩为主,是很好的生油岩,上部以砂岩为主夹火山岩,可作为储集层.晚期高位体系域西部为长兴组灰岩、白云质灰岩、白云岩,可作为储层之用.     

滇黔桂盆地及其邻区石炭纪至二叠纪层序地层格架及三级海平面变化的全球对比

属于被动大陆边缘裂谷盆地的滇黔桂盆地，自加里东运动之后，泥盆纪开始拉开，整个晚古生代延续发展。受同生断裂的控制，在深水盆地中发育大小不等的孤立碳酸盐台地，因而在滇黔桂盆地及其邻区形成特殊的“台-盆-丘-槽”的古地理格局。对不同古地理背景下的典型剖面进行三级层序划分并对其进行空间追索和对比，在滇黔桂盆地及其邻区的石炭纪和二叠纪地层中可以识别出12个三级层序，相当于晚古生代25个三级沉积层序(2-5Ma；SQ1至SQ25)中的SQ24至SQ25；以地层记录中的的两种相变面和两种穿时性为基本要素，可以建立研究区石炭系和二叠系的层序地层格架；层序地层格架反映了三级层序的基本特征：空间上相序的有序性和时间上环境变化的同步性。研究区的石炭系和二叠系，主要为一套碳酸盐岩地层，其中在连陆台地上发育3套煤系地层，它们分别组成石炭纪三级层序SQ15跨系的三级层序SQ19的HST以及二叠纪吴家坪期的三级层序SQ24；而且在连陆台地边缘和孤立台地上，于阳新世的茅口亚世以及乐平世的长兴期发育海绵生物礁，海绵生物礁分别构成了以下二叠系三级层序即阳新世的SQ22和SQ23以及长兴期的SQ25。3套煤系地层和两套海绵生物礁的发育，使研究区的石炭系和二叠系形成了一个与欧美地区完全不同的层序地层序列。在研究区石炭系和二叠系所识别出的12个三级层序中，石炭纪一二叠纪船山世地层可以划分出6个三级层序。这种划分与Busch等对北美相同层位的划分相似，也就是说该6个三级层序的形成时限大于10Ma；较长的形成时限可能反映了形成在联合古陆汇聚时期即全球构造相对稳定时期三级海平面变化的一个特性。因此，研究区的石炭系和二叠系所识别和划分出的12个三级层序，其数量比Ross和Ross(1985)对欧美地区石炭系和二叠系所划分出的50多个三级层序要少得多。     

湘东南及湘粤赣边区中生代地质构造发展框架的厘定

湘东南及湘粤赣边区属南岭中段北部,是研究华南中生代构造背景与演化的良好窗口.通过同位素年代学和地质地球化学研究,确定了区内中生代3个时代花岗岩的时限与构造环境,并结合对区内中生代不同时代陆相盆地和火山岩的性质与形成机制,构造变形和成矿作用的期次与特征等研究,厘定出研究区中生代地质事件序列的框架.从早至晚分为早三叠世-中三叠世早期前造山阶段（Ⅰ）、中三叠世后期-中侏罗世初陆内造山阶段（Ⅱ）、中侏罗世早期-晚侏罗世后造山阶段（Ⅲ）、白垩纪板内裂谷阶段（Ⅳ）等4个大的地质发展阶段,其中陆内造山阶段（Ⅱ）进一步划分为4个亚阶段（Ⅱ1～Ⅱ4）.前造山阶段（Ⅰ）为稳定海相沉积阶段.中三叠世后期（Ⅱ1）为陆内俯冲汇聚高峰期,形成大量NNE向为主的逆冲断裂与褶皱,并使陆壳增厚.中三叠世末-晚三叠世后期（Ⅱ2）挤压相对松弛,大量壳源花岗岩浆形成并侵位（233～210Ma）.晚三叠世末-早侏罗世（Ⅱ3）为同造山上隆伸展环境,形成NNE向裂陷含煤盆地,高Na低K的拉斑玄武岩喷发.中侏罗世初期（Ⅱ4）为NNE向左旋汇聚走滑造山,发育逆冲断裂且前期裂陷盆地反转成为山前冲断收缩盆地.中侏罗世早期-晚侏罗世后造山阶段（Ⅲ）,大量后造山花岗岩侵位（174～135Ma）,同时发生大规模成矿作用;侏罗纪末期发生过短暂的挤压事件.白垩纪板内裂谷阶段（Ⅳ）形成盆-岭构造和变质核杂岩构造、双峰式火山岩和次火山岩、酸性岩脉及具有AA型花岗岩特征的上堡小型岩体等组合.文章最后就华南地区燕山早期构造环境和中生代不同阶段构造-岩浆活动特征的形成机制等问题进行了讨论.     

川西邛崃县白马庙气田上侏罗统蓬莱镇组高分辨率层序地层分析

以高分辨率层序地层学理论及其技术方法为指导,通过地表露头、岩心、测井和地震资料的综合分析,在白马庙气田上侏罗统蓬莱镇组识别出3类不同成因类型和发育规模的层序界面、3个级别的湖泛面,划分出2个长期、6个中期、38～40个短期基准面旋回层序,并对不同级次旋回层序的特征进行了详细讨论.同时,发现中期基准面旋回层序近顶部的薄层灰岩和钙质泥岩也是识别中期基准面旋回的重要标志之一.在此基础上,运用旋回等时对比法则对各级次旋回层序进行对比,建立了3个不同时间尺度的等时地层格架,认为开展高分辨率层序地层分析对深化白马庙气田蓬莱镇组气藏的勘探开发工作具有重要意义.     

A parametric study on the impact of satellite attitude errors on GOCE gravity field recovery

In the recent design of the Gravity field and steady-state Ocean Circulation Explorer (GOCE) satellite mission, the gravity gradients are defined in the gradiometer reference frame (GRF), which deviates from the actual flight direction (local orbit reference frame, LORF) by up to 3–4°. The main objective of this paper is to investigate the effect of uncertainties in the knowledge of the gradiometer orientation due to attitude reconstitution errors on the gravity field solution. In the framework of several numerical simulations, which are based on a realistic mission configuration, different scenarios are investigated, to provide the accuracy requirements of the orientation information. It turns out that orientation errors have to be seriously considered, because they may represent a significant error component of the gravity field solution. While in a realistic mission scenario (colored gradiometer noise) the gravity field solutions are quite insensitive to small orientation biases, random noise applied to the attitude information can have a considerable impact on the accuracy of the resolved gravity field models.