有机柱撑粘土(蒙脱石)的研究进展

有机柱撑蒙脱石是近年来受到广泛关注的一类有机-无机粘土复合材料，其优异的性能使其在许多领域都有巨大的应用潜力。本综述了有机柱撑蒙脱石的起源、发展、主要类型，探讨了有机柱撑蒙脱石的研究方向。     

有机质在MVT铅锌矿床形成中的作用

MVT铅锌矿床与有机质密切相关。本以有机质生成世代为序，讨论了有机质低、中、高成熟阶段的产物在MVT铅锌矿床成矿过程中的作用。腐殖酸在矿床形成的早期阶段配合、吸附Pb、Zn等金属离子，起到促进成矿源层形成的作用。油田卤水可能成为铅锌多金属元素迁移的主要载体和成矿流体的重要组成部分，甚至就是形成密西西比河谷型矿床的一种很重要的潜在成矿流体。甲烷在矿床形成晚期充当还原剂。     

论有机质与金属成矿和勘查

有机质与金属成矿是一个处于初级研究阶段的地球化学领域。本文对其研究历史进行了回顾，指出了有机质在金属成矿中的主要作用以及有机烃气测量在金属矿产勘查中的初步应用成果。认为该领域的深入研究，可促进成矿作用、成矿过程、成矿规律、气体运移规律和成矿预测的全面认识，对有机地球化学和无机地球化学、固体地球化学与气体地球化学、勘查地球化学与矿床学等不同学科之间的连接和相互渗透将起重要的纽带作用。     

Extraterrestrial Organic Compounds in Meteorites

Many organic compounds or their precursorsfound in meteorites originated in the interstellar or circumstellarmedium and were later incorporated intoplanetesimals during the formation of thesolar system. There they either survivedintact or underwent further processing tosynthesize secondary products on themeteorite parent body.The most distinct feature of CI and CM carbonaceouschondrites, two typesof stony meteorites, is their high carbon content(up to 3% of weight), either in theform of carbonates or of organic compounds. The bulkof the organic carbon consistsof an insoluble macromolecular material with a complexstructure. Also present is asoluble organic fraction, which has been analyzedby several separation and analyticalprocedures. Low detection limits can be achievedby derivatization of the organicmolecules with reagents that allow for analysisby gas chromatography/massspectroscopy and high performance liquidchromatography. The CM meteoriteMurchison has been found to contain more than70 extraterrestrial amino acids andseveral other classes of compounds includingcarboxylic acids, hydroxy carboxylicacids, sulphonic and phosphonic acids, aliphatic,aromatic and polar hydrocarbons,fullerenes, heterocycles as well as carbonylcompounds, alcohols, amines and amides.The organic matter was found to be enriched indeuterium, and distinct organiccompounds show isotopic enrichments of carbon andnitrogen relative to terrestrialmatter.     

Surface tension and friction coefficients in shallow,laminar overland flows through organic litter

This study investigates the contribution of surface tension forces to friction coefficients in shallow, laminar interrill flows. Friction coefficients in these flows are known to be increased greatly by organic litter and by stems. Fine litter provides extensive edges along which surface tension menisci can be drawn up, and evaluating the significance of this in the frictional retardation of flow was the primary objective of the experiments reported here. Using both standardized ‘litter particles’ (small wooden blocks of fixed dimensions) and natural plant litter, meniscus behaviour and the Darcy–Weisbach friction coefficient were evaluated in shallow flows on a laboratory sand board. For some tests, the surface tension of ordinary water was reduced by 40 per cent by the addition of a surfactant, and the friction coefficient redetermined. Results show that the presence of surface tension menisci flanking litter particles provides areas of deeper flow that are up to 7 mm in width and which can increase flow depths by 100–300 per cent. These zones support significantly higher flow speeds. Increased water depths within menisci are additionally associated with reduced depths beyond the menisci, so that an increase in the spatial variability of flow depths is a second consequence of meniscus formation. These modifications of flow depth by surface tension menisci are shown to reduce rather than increase the overall friction coefficient applicable to the flow. Consequently, additional frictional retardation does not arise within the menisci flanking litter particles and so cannot account for the greater drag arising from litter than from other surface features. Different factors, possibly the direct obstruction of flow paths, must therefore underlie the frictional drag. Copyright © 2002 John Wiley & Sons, Ltd.     

高浓度有机废水化学和物理法处理技术综述

介绍国内外高浓度有机废水应用化学和物理方法处理技术进展 ,通过比较各种化学和物理方法的优缺点 ,得出探讨性结论 ,即采用一种方法难以完全处理高浓度有机废水 ,需经二段或三段处理方法处理后 ,才能达到排污标准。     

A Database for Volatile Organic Compounds

The database for volatile organic compounds (VOC data base) was created with the aim of providing an overview of tropospheric hydrocarbon measurements. The data base contains 202 substances, for which atmospheric and useful kinetic data such as rate coefficients, photolysis frequencies, mixing ratios, emission data and ozone formation potentials are compiled from available literature. The database file can be downloaded without charge from http://www.physchem.uni-wuppertal.de/voc-database. Registered users will be informed about the appearance of updates.     

Verification of the Contribution of Vehicular Traffic to the Total NMVOC Emissions in Germany and the Importance of the NO3 Chemistry in the City Air

In 1997 and 1998 several field campaigns for monitoring non-methane volatile organic compounds (NMVOCs) and nitrogen oxides (NO_x) were carried out in a road traffic tunnel and in the city center of Wuppertal, Germany. C₂–C₁₀ aliphatic and aromatic hydrocarbons were monitored using a compact GC instrument. DOAS White and long path systems were used to measure aromatic hydrocarbons and oxygenated aromatic compounds. A formaldehyde monitor was used to measure formaldehyde. Chemiluminescence NO analysers with NO₂ converter were used for measuring NO and NO₂. The high mixing ratios of the NMVOCs observed in the road traffic tunnel, especially 2.9 ppbv phenol, 1.5ppbv para-cresol and 4.4 ppbv benzaldehyde, in comparison with themeasured background concentration clearly indicate that these compounds were directly emitted from road traffic. Para-Cresol was for the first timeselectively detected as primary pollutant from traffic. From the measured data a NMVOC profile of the tunnel air and the city air, normalised to benzene (ppbC/ppbC), was derived. For most compounds the observed city air NMVOC profile is almost identical with that obtained in the traffic tunnel. Since benzene originates mainly from road traffic emission, the comparison of the normalised emission ratios indicate that the road traffic emissions in Wuppertal have still the largest impact on the city air composition, which is in contrast to the German emission inventory. In both NMVOC profiles, aromatic compounds have remarkably large contributions of more than 40 ppbC%. In addtion, total NMVOC/NO_x ratios from 0.6 up to 3.0ppbC/ppb in the traffic tunnel air and 3.4± 0.5 in the city air of Wuppertal were obtained. From the observed para-cresol/toluene and ortho-cresol/toluene ratios in the city air, evidence was found thatalso during daytime NO₃ radical reactions play an important role in urban air.     

Environmental records of carbon in recent lake sediments

Based on careful sampling and accurate analysis of recent sediments in Lake Chenghai, this paper discusses the staggered positive/negative correlation between organic carbon (OC) concentration and inorganic carbon (IC) concentration. The result indicates that temperature change, and its induced relative changes are the main factors affecting the relationship between IC concentration, δ¹³C of carbonate and OC concentration. When temperature and its induced photosynthesis strength change control autochthonous calcite precipitation, OC concentration is positively correlated with IC concentration and δ¹³C of carbonate. When temperature and its induced physical/chemical changes dominate, OC concentration displays negative correlation with IC concentration and δ¹³C of carbonate. IC concentration and δ¹³C of carbonate in sediments of Lake Chenghai are good proxies for climatic warm/cold changes.     

Study on Paleoenvironment since Late GlacialEpoch in Lanzhou Area, China

The Hongzuisi Section in Lanzhou area is used to infer the paleoclimate since the late glacial epoch. Through combined analysis of organic carbon isotope and CaCO3 content, paleoenvironment evolution of Hongzuisi Section since the late glacial epoch is discussed. There were changes in both dry-moist and warm-cold. Especially the climate changes can be compared with synchronous sections of other areas, which provides useful information for our future forecast.