全文获取类型
收费全文 | 1279篇 |
免费 | 95篇 |
国内免费 | 140篇 |
专业分类
测绘学 | 707篇 |
大气科学 | 45篇 |
地球物理 | 120篇 |
地质学 | 375篇 |
海洋学 | 95篇 |
天文学 | 65篇 |
综合类 | 85篇 |
自然地理 | 22篇 |
出版年
2024年 | 2篇 |
2023年 | 12篇 |
2022年 | 37篇 |
2021年 | 77篇 |
2020年 | 91篇 |
2019年 | 59篇 |
2018年 | 32篇 |
2017年 | 97篇 |
2016年 | 66篇 |
2015年 | 80篇 |
2014年 | 86篇 |
2013年 | 86篇 |
2012年 | 71篇 |
2011年 | 67篇 |
2010年 | 68篇 |
2009年 | 56篇 |
2008年 | 56篇 |
2007年 | 67篇 |
2006年 | 67篇 |
2005年 | 47篇 |
2004年 | 32篇 |
2003年 | 38篇 |
2002年 | 39篇 |
2001年 | 51篇 |
2000年 | 25篇 |
1999年 | 18篇 |
1998年 | 23篇 |
1997年 | 13篇 |
1996年 | 10篇 |
1995年 | 5篇 |
1994年 | 11篇 |
1993年 | 7篇 |
1992年 | 6篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1988年 | 2篇 |
1981年 | 1篇 |
1954年 | 1篇 |
排序方式: 共有1514条查询结果,搜索用时 31 毫秒
31.
William J. Chazey III Clive R. Neal Jinesh C. Jain William S. Kinman 《Geostandards and Geoanalytical Research》2003,27(2):181-192
The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1). 相似文献
32.
A multi-layer deposited ice film was prepared through water vapor deposition on a Ni plate in a vacuum chamber at 90 K, and was used as it was or after annealing at 140 K. NO2 was adsorbed as N2O4 approximately 90 K on the ice film prepared as above, and irradiated by 193 nm excimer laser light. The time-of-flight (TOF) spectra of the desorbed species, i.e., NO2, NO, O2 and O, were measured by a quadrupole mass spectrometer. The photochemical process obeyed an one-photon process. The relative yields of the products and their TOF spectra were dependent on the preparation condition of the ice film and also varied with the continuation of the laser irradiation. From the ice film annealed at 140 K, NO2, NO and O2 were desorbed with an approximate ratio of 1:1:0.01. From the non-annealed film, the relative yield of NO2 was much smaller than that of NO. The TOF spectrum of NO from the non-annealed ice film consisted of distinctly different two components corresponding to the 1700 and 100 K translational temperature, respectively. The fast component was lost when additional ice was deposited on the adsorbed N2O4. NO was supposed to be a predissociation product from the electronically excited NO2 prepared through the photodissociation of N2O4. 相似文献
33.
航空物探数据具有较高的保存开发价值,由于磁带保存的有效年限较短,航空物探勘查所获资料存在着丢失的危险。航空物探数据光盘转录将解决这些难题,为航空物探资料的二次开发和利用创造条件。本光盘数据从任一与RICOHRS-5060E型光盘机兼容的光盘机上均可读出。 相似文献
34.
35.
吐哈盆地及二连盆地侏罗系煤微类脂组分的共聚焦激光扫描显微镜(CLSM)研究及油气意义 总被引:7,自引:1,他引:7
吐哈盆地产出有比较丰富的侏罗系煤成油气田,本文用共聚焦激光扫描显微镜和热解分析等手段研究了煤中类脂组及微类脂组的类型、含量、分布与煤成烃性能和产出的关系。观察分析结果表明:在一般煤岩组分观测中主要含煤的西山窑组和八道湾组煤层类脂组含量很少超过10%,但是一些煤样的热解分析中S_1可高达5-23mg/g,S_2可达150─200mg/g,HI(烃/有机碳)可高达150─350mg/g生烃、含烃性能较好。进一步用共聚焦激光显微镜观测结果表明:本区一些薄层状、条带状煤层的基质镜质体和叶结构镜质体中微类脂组含量比较丰富,微区定量统计含量在3%─18%左右。这种富含微类脂组的基质镜质体和结构镜质体在煤成油气中有重要意义,而且由于多数微类脂体在煤中常成点线状、似层状、充填状、网络状分布,可能有利于煤成油气的运移和聚集。 相似文献
36.
37.
利用激光粒度仪测试超细煤粉的粒度。对测试超细煤粉试样粒度时的试样浓度、测试温度、分散时间、分散剂的种类及浓度等方面的影响进行了实验研究,给出了激光粒度仪测试超细煤粉粒度的最佳实验条件。 相似文献
38.
Accurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry 总被引:190,自引:0,他引:190
Honglin Yuan Shan Gao Xiaoming Liu Huiming Li Detlef Günther Fuyuan Wu 《Geostandards and Geoanalytical Research》2004,28(3):353-370
Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and 29 Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 μm, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2 s ). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2 s ). Other examples for older zircons are also given. 相似文献
39.
40.
Paul J. Sylvester 《Geostandards and Geoanalytical Research》2005,29(1):41-52
This annual review of laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) covers the year 2003. Significant advances were made in understanding laser-sample interactions. In particular, research defined the distribution of particle sizes produced by the interplay of laser wavelength, laser pulse width and the gas environment of ablation. A link between particle sizes and elemental and isotopic fractionation at both the ablation site and in the ICP was established. Experimental 15 7 nm and femtosecond laser systems were tested with promising results. The number of applications of LA-ICP-MS in geology and environmental Earth science continued to grow with particular interest in element concentration and isotope ratio profiling of materials, linking composition to time scales. In situ isotopic ratio measurements were increasingly made using multicollector magnetic sector ICP-MS instruments. Other applications of wide interest included bulk sampling of rocks and ores prepared as lithium borate glasses; low level analysis of platinum-group elements, rhenium and gold in sulfides, metal and silicates; in situ uranium-lead zircon geochronology; and melt and fluid inclusion analysis. 相似文献