微波消解-电感耦合等离子体质谱法测定土壤中稀土元素条件优化

稀土元素因其用途广泛,已经得到了越来越多的关注,被应用于各个行业。研究表明,稀土元素对作物的光合作用、产量、抗逆、品质、发育和养分吸收等具有重要作用。作物中的稀土元素主要来自对土壤中稀土元素的吸收,因此,有效分解并快速测定土壤中的稀土元素,可以合理指导稀土元素的施用,对作物的生长和土壤的营养状况具有重要作用。本文比较了敞口酸溶、密闭消解、微波消解和碱熔等4种消解样品前处理方法,最终确定采用微波消解-电感耦合等离子体质谱法(ICP-MS)快速测定土壤中的稀土元素,并通过优化微波消解的条件,选择合适的试剂用量、消解温度、消解时间,对方法的检出限、精密度、准确度、回收率进行了实验,结果显示其测定均值与标准值基本吻合,相对误差(RE)绝对值为0.16%～3.39%,精密度为0.27%～5.09%,均小于10%,加标回收率为93.1%～106.0%。该方法准确度高、稳定性好,可以有效地应用于土壤中稀土元素的分析测定。     

Latitudinal and Scan-dependent Biases of Microwave Humidity Sounder Measurements and Their Dependences on Cloud Ice Water Path

The relationship between differences in microwave humidity sounder(MHS)–channel biases which represent measured brightness temperatures and model-simulated brightness temperatures, and cloud ice water path(IWP) as well as the influence of the cloud liquid water path(LWP) on the relationship is examined. Seven years(2011–17) of NOAA-18 MHS-derived measured brightness temperatures and IWP/LWP data generated by the NOAA Comprehensive Large Array-data Stewardship System Microwave Surface and Precipitation Products System are used. The Community Radiative Transfer Model, version2.2.4, is used to simulate model-simulated brightness temperatures using European Center for Medium-Range Weather Forecasts reanalysis data as background fields. Scan-angle deviations of the MHS window channel biases range from-1.7 K to1.0 K. The relationships between channels 2, 4, and 5 biases and scan angle are symmetrical about the nadir. The latitudedependent deviations of MHS window channel biases are positive and range from 0–7 K. For MHS non-window channels,the latitudinal deviations between measured brightness temperatures and model-simulated brightness temperatures are larger when the detection height is higher. No systematic warm or cold deviations are found in the global spatial distribution of difference between measured brightness temperatures and model-simulated brightness temperatures over oceans after removing scan-angle and latitudinal deviations. The corrected biases of five different MHS channels decrease differently with respect to the increase in IWP. This decrease is stronger when LWP values are higher.     

Passive microwave remote sensing of the historic February 2010 snowstorms in the Middle Atlantic region of the USA

The snowfall in the Baltimore/Washington metropolitan area during the winter of 2009/2010 was unprecedented and caused serious snow‐related disruptions. In February 2010, snowfall totals approached 2 m, and because maximum temperatures were consistently below normal, snow remained on the ground the entire month. One of the biggest contributing factors to the unusually severe winter weather in 2009/2010, throughout much of the middle latitudes, was the Arctic Oscillation. Unusually high pressure at high latitudes and low pressure at middle latitudes forced a persistent exchange of mass from north to south. In this investigation, a concerted effort was made to link remotely sensed falling snow observations to remotely sensed snow cover and snowpack observations in the Baltimore/Washington area. Specifically, the Advanced Microwave Scanning Radiometer onboard the Aqua satellite was used to assess snow water equivalent, and the Advanced Microwave Sounding Unit‐B and Microwave Humidity Sounder were employed to detect falling snow. Advanced Microwave Scanning Radiometer passive microwave signatures in this study are related to both snow on the ground and surface ice layers. In regard to falling snow, signatures indicative of snowfall can be observed in high frequency brightness temperatures of Advanced Microwave Sounding Unit‐B and Microwave Humidity Sounder. Indeed, retrievals show an increase in snow water equivalent after the detection of falling snow. Yet, this work also shows that falling snow intensity and/or the presence of liquid water clouds impacts the ability to reliably detect snow water equivalent. Moreover, changes in the condition of the snowpack, especially in the surface features, negatively affect retrieval performance. Copyright © 2011. This article is a U.S. Government work and is in the public domain in the USA.     

微波等离子体炬原子发射光谱法测定铁和铝的研究

研究了低功率微波等离子体炬原子发射光谱法（ＭＰＴ－ＡＥＳ）对Ｆｅ，Ａｌ的测定。样品经气动雾化后，分别以流动注射与连续式两种方式引入ＭＰＴ。考察了用这两种进样方式时ＭＰＴ－ＡＥＳ的分析性能，证明低功率ＭＰＴ－ＡＥＳ具有良好的分析特性。     

Recent advances in solar radio physics

We review high spatial resolution microwave observations of solar active regions, coronal loops and flares. Observations of preflare active regions are presented; in particular we discuss the interpretations of reversal of polarization at the flare site and the role of newly emerging flux in triggering the onset of flares. We discuss the spatial locations of microwave burst emitting regions; loops or arcades of loops appear to be the sites of flare energy release in microwave bursts. We provide direct observational evidence of magnetic reconnection as the primary cause of acceleration of electrons in microwave bursts.     

植被覆盖地表主动微波遥感反演土壤水分算法研究

主动微波遥感监测土壤水分具有全天时、全天候并对地物有一定的穿透能力等特点,突破了传统测量方法和光学遥感获取土壤水分的局限。文中在分析植被对微波信号影响的基础上,总结了当前国内外基于主动微波遥感监测植被覆盖地表土壤水分的原理和方法,指出利用，宋朝景“水-云模型”从总的极化雷达后向散射中去除植被影响后,能够改进后向散射系数和土壤含水量之间的关系。最后利用ENVISAT ASAR数据,结合实地采样获得的土壤含水量数据拟合两者之间的关系,结果表明农作物覆盖地表土壤水分变化的估算算法还需要进一步发展和改进以提高反演精度。     

Exfoliation of kaolinite by urea-intercalation precursor and microwave irradiation assistance process

A type of exfoliated kaolinite was produced by urea-intercalation and original microwave irradiation assisted method. The product was investigated by Fourier transformation infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electronic microscopy (SEM), Brunauer-Emmett-Teller (BET) and laser particle analysis techniques. FT-IR spectra show that NHCO molecule exists in the intercalated kaolinite. XRD analyses indicate that the kaolinite sheet-like structure was disordered after microwave irradiation. The urea decomposition process and explosion effect between the sheet-like structures of kaolinite under microwave irradiation were discussed. The SEM and BET analyses reveal that the end product is exfoliated kaolinite with thin particles and increased surface area. Size and zeta potential analyses show that the particle size distribution is between 250 nm and 550 nm with normal distribution and the particle is negatively charged. In comparison with the conventional grind method, the process adopted appears to be economic and the exfoliated kaolinite end product may display a significantly enhanced performance in industrial applications.     

双线偏振双波段（X／Ka）主被动微波遥感系统的研制与初步试验

为拓展主波，动生波探测系统遥感降水云雨的功能，使系统的原理先进性能有进一步的体现，将一套主被动双波段（X／Ka)微波遥感系统研制升级为双线偏振双波段主被动微波遥感系统。对新系统及主要部件的工作原理，技术指标及研制改造方法作了介绍，还给出了一些初步的观测结果。     

基于被动微波遥感的青藏高原雪深反演及其结果评价

采用修正的张氏雪深反演算法，用ＳＳＭ／Ｉ３７ＧＨz和19GHz水平极化亮温值计算了青藏高原及其毗邻地区的积雪深度，对其精度进行了评价，并对误差来源进行了分析，结果显示，此算法能够较好地反映研究区的雪深分布，但局部地区误差较大，总体上雪深被高估，其误差主要来源于冻土，深霜层，植被以及雪层中液态水含量，雪粒的形状和粒径的变化带来的影响，SSM／I数据较低的分辨率和研究区复杂的地形使反演的雪深与观测的雪深缺少可比性，给精度的评价带来影响。     

利用地基双通道微波辐射计遥感青藏高原大气云水特征

利用1997年春季西宁市地基双通道（22．235和35．3GHz)微波辐射计观测的资料，分析了不同月份、不同天气条件下的大气总含水量（V）和云中液态水积分含量（L）的分布规律。结果表明，在相同天气条件下，L值3－5月均呈逐渐递增的趋势，增加幅度一般为20％－40％，V值变化幅度很小；春季高原L值大约只有V的1%。与河北省的资料进行对比后发现，L值基本相当，而V值高原只有平原地区的30％－50％。