临安大气气溶胶理化特性季节变化

分别利用碳成分分析仪、离子色谱仪和原子吸收光谱仪等获取浙江省临安地区大气气溶胶在春、夏、秋、冬四季的质量浓度、离子与碳成分特性，并对不同粒径气溶胶成分分布特点作了较详细分析。结果表明:气溶胶质量浓度、可溶性离子浓度以及碳成分浓度具有明显的季节变化趋势。整个尺度范围内，气溶胶质量浓度季节变化特点为春季浓度最高，达到534 μg/m3；冬季次之，质量浓度为117.21 μg/m3；夏季浓度最低，平均为65.7 μg/m3；秋季质量浓度98.6 μg/m3。可溶性离子成分在气溶胶中所占比例具有明显的季节性，其中夏季最高为49.4%，春季最低为11.3%。硫酸根离子SO₄2-和氨根离子NH₄+和硝酸根离子NO₃- 3种离子浓度之和约占离子总量的75%~83%。受温度影响，硝酸根离子NO₃-浓度随季节变化幅度较大，夏季平均浓度为1.7 μg/m3, 冬季平均浓度为11.5 μg/m3，是夏季浓度的6.8倍。碳浓度分布特点显示，气溶胶中元素碳浓度春季最高，夏季最低。有机碳浓度春季最高，冬季最低。气溶胶粒度分布特点也非常明显。四季中粒径小于11 μm（PM₁₁）的气溶胶均占气溶胶总量的90%以上，粒径小于2.1 μm（PM_2.1）的气溶胶占到气溶胶总量的53%以上。可溶性离子在粒径小于2.1 μm气溶胶颗粒中，以硫酸根离子、氨根离子和硝酸根离子为主。碳成分尺度分布特征为颗粒越小，有机碳及元素碳浓度越高。     

用储层岩石抽提物的饱和烃色谱指纹识别油气层

利用储层岩石抽提物的饱和烃色 质总离子图的指纹特征判识储层的流体（油、气）类型。油层或油饱和的储层,饱和烃色 质总离子流图的特征是正构烷烃碳数分布宽,碳数分布在C₁₅～C₃₈之间,与原油样品的正构烷烃碳数分布相似;凝析气层的正构烷烃碳数分布略窄一些,碳数分布在C₁₅～C₃₅之间,低碳数（小于C₂₁）的正构烷烃相对于油层富集,高碳数（大于C₂₁）的正构烷烃丰度明显低于油层;干气层的正构烷烃碳数分布最窄,碳数分布在C₁₅～ C₂₈之间,只有低碳数的正构烷烃,高碳数的正构烷烃丰度极低。据此可用来识别油层、凝析气层和干气层,也可用于一些测井资料不全或测井质量差的老井的油气层复查、测井难以识别的火成岩油气层的识别,还可用于地层评价,为油气酸化层位的优选提供科学依据。     

Analytical perspective on trace element species of interest in exploration

Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH₂OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH₂OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.     

Substorm associated radar auroral surges: a statistical study and possible generation model

Substorm-associated radar auroral surges (SARAS) are a short lived (15–90 minutes) and spatially localised (5° of latitude) perturbation of the plasma convection pattern observed within the auroral E-region. The understanding of such phenomena has important ramifications for the investigation of the larger scale plasma convection and ultimately the coupling of the solar wind, magnetosphere and ionosphere system. A statistical investigation is undertaken of SARAS, observed by the Sweden And Britain Radar Experiment (SABRE), in order to provide a more extensive examination of the local time occurrence and propagation characteristics of the events. The statistical analysis has determined a local time occurrence of observations between 1420 MLT and 2200 MLT with a maximum occurrence centred around 1700 MLT. The propagation velocity of the SARAS feature through the SABRE field of view was found to be predominately L-shell aligned with a velocity centred around 1750 ms^–1 and within the range 500 m s^–1 and 3500 m s^–1. This comprehensive examination of the SARAS provides the opportunity to discuss, qualitatively, a possible generation mechanism for SARAS based on a proposed model for the production of a similar phenomenon referred to as sub-auroral ion drifts (SAIDs). The results of the comparison suggests that SARAS may result from a similar geophysical mechanism to that which produces SAID events, but probably occurs at a different time in the evolution of the event.     

浅层地震技术在隧道勘察中的应用

论述了在深圳市东部沿海高速公路隧道勘察中,应用浅层地震勘探方法查明地下地质构造、风化带、分层等,并根据资料解释成果、钻探资料和工区地质资料,对隧道开挖过程中可能遇到的断层及塌陷等情况进行了讨论。     

Recombination rates of small ions and their attachment to aerosol particles

It could be shown by measurements of the air conductivity and using a mean profile for the ionization rate that experimental and theoretical values of the recombination rate of small ions based on a three body recombination process (Thomson) are in very good agreement up to 20 km altitude. The divergency of the experimental and theoretical curves above 20 km can be interpreted by assuming that there exists in this altitude region a crossover from the three body recombination to a two body recombination process. The value of the recombination coefficient is about 4·10^–7 cm³ s^–1 in 25 km altitude, compared with 1.4·10^–6 cm³ s^–1 at ground level. Furtheron it was possible for the first time to get some experimental data of attachment coefficients up to 13 km from simultaneous measurements of the air conductivity and Aitken nuclei concentration. These values are in good agreement with those obtained by theoretical considerations.     

金华市不同区域负氧离子浓度特征与气象环境因素相关分析

利用2019—2021年金华市空气负氧离子浓度和气象环境资料，研究不同区域（平原城区、平原公园、水边景区、山林景区）负氧离子浓度时空分布特征，分析人类活动最多的城区负氧离子浓度与气象环境因素不同时间尺度的相关性，以及不同天空状况的差异。结果表明：负氧离子浓度呈现平原低、山区高的分布特征，植被茂密、动态水流可增加负氧离子浓度和提高浓度等级。山林景区日出和日落前后负氧离子浓度较高，水边景区凌晨和午后出现高值，平原地区则在下午达到高峰。不同区域四季日变化趋势整体较一致，但不同季节负氧离子浓度峰值大小、日较差和出现峰值时刻存在差异。四季不同区域负氧离子浓度有所差异，主要表现为6—9月高，其中尤以8月山林景区为最。负氧离子浓度与气象环境因素的相关性在不同时间尺度上差异较大：时尺度上与气温、风速、雨量和O3呈显著正相关，而与PM2.5呈显著负相关。四季看，负氧离子浓度春季与风速相关性最高，夏季为气温，秋季为O3，冬季为PM2.5。日尺度上则与相对湿度、风速、雨量呈显著正相关，与PM2.5和O3呈显著负相关，且雨天负氧离子浓度明显高于其他天空状况，差异在冬季达最大。     

长江口九段沙潮沟系统分维研究

以长江口九段沙为研究区,采用2013年8月13日的Landsat-8遥感全色波段得到的九段沙潮沟分布图,利用Horton-Strahler原则将九段沙潮沟进行了分级。然后使用网格法对各个等级的潮沟进行了分维研究,计算了九段沙不同等级的每个潮沟左右两侧的维数值,并结合潮沟的宽度大小,对其维数值进行了比较和分析。研究结果表明,九段沙相同等级潮沟中,潮沟左侧维数的变化范围大于右侧,即潮沟左侧发育的复杂程度大于右侧;不同等级潮沟宽度的最小值变化幅度不大,但潮沟宽度的最大值变化幅度较大;不同等级潮沟宽度的变化和其潮沟左右两侧维数差值变化的相关性较小;不同等级潮沟,无论左侧还是右侧,潮沟维数大小随着潮沟的等级数和潮沟的平均宽度的增大而增大。     

地下水中钙和镁的离子色谱法同时测定

改进了离子色谱分析地下水中钙和镁的方法。以IonPac CS12A为分离柱,稀盐酸为淋洗液,电导检测器检测,对地下水中的锂、钾、钠、钙和镁进行同时测定。方法具有较宽的线性范围和较高的灵敏度,钙、镁的浓度分别在0～500mg/L和0～250mg/L内呈良好的线性关系;钙的检出限为1.50μg/L,镁的检出限为0.89μg/L。对不同浓度钙、镁水质标准样品进行分析测定,同时对实际样品进行不同稀释倍数分析验证,方法精密度(RSD,n=8)为0.19%～1.89%,无显著的基体效应影响。方法可满足全国地下水调查评价规范要求,适于地下水样品中锂、钾、钠、钙和镁离子的同时测定。     

电气石矿物吸附铜离子试验研究

本文研究了电气石的单晶、电气石微粉对Cu2＋的吸附作用,试验表明：电气石单晶体表面存在着以C轴为两极的静电场,该静电场对Cu2＋的吸附作用效果明显。制备的电气石微粒越细,吸附效果越好。电气石的电场效应使得它在治理污水中Cu2＋污染具有广阔的前景。