试论西部大开发与国防建设

根据我国国土形状呈三叶螺旋浆形的特征，指出了我国经济建设，国防建设和行政管理均应实行中心辐射型结构模式，述了我国经济建设与国防建设相结合的措施，将经济区以国防功能区分为核心经济区，纽带经济区，支撑经济区，有序建成这三类经济区，以适应形势发展的需要，扩大我国的战略防御向纵深发展。     

塔里木盆地东部地区天然气地球化学特征及成因探讨(之二)

天然气的组分和碳、氢同位素组成特征研究表明塔里木盆地已发现的天然气均为热解气。通过气源对比可知,该盆地东部地区的天然气主要有两种类型 :1)是来自震旦纪到下古生界海相腐泥型母质的油型气,其甲烷、乙烷、丙烷δ13C值,分别为-44.5‰～-33.8‰、- 42‰～-2 8.1‰和-35.4‰～-2 8.4‰,其甲烷的氢同位素组成大于- 2 0 0‰;2 )是产自中生代陆相腐殖型源岩的煤型气,其甲烷、乙烷、丙烷的δ13C值分别为-40.5‰～-33.1‰、- 2 9.7‰～-2 1.3‰和-2 6.3‰～-2 0.3‰,其甲烷的氢同位素组成小于-2 0 0‰。将天然气的地化特征与地质背景相结合判断可知,在塔北隆起地区一些天然气藏是由成熟 (高成熟 )阶段的油型气与过成熟阶段的油型气混合形成,另一些天然气藏是由成熟阶段的油型气和成熟阶段的煤型气混合形成.     

Experimental diffusion of hydrogen into synthetic fluid inclusions in quartz

Abstract Quartz-hosted, synthetic CO₂-H₂O fluid inclusions behave as open systems with respect to diffusional transfer of hydrogen during laboratory-simulated metamorphic re-equilibration at 650, 750 and 825°C and 1.5 kbar total pressure with f_O2 defined by the C-CH₄ buffer. Microthermometry and Raman spectroscopy show that the initial CO₂-H₂O inclusions become CO₂-CH₄-H₂-H_2O
inclusions after diffusive influx of hydrogen from the reducing confining medium. Measurable changes are observed in inclusion compositions after only 15 days of re-equilibration, implying significant hydrogen mobility at still lower temperatures over geological time spans. Results of synthetic inclusion re-equilibrium experiments have profound implications for the interpretation of natural fluid-inclusion data; failure to account for potential hydrogen migration in inclusions from high-temperature geological environments may lead to erroneous estimates of P-T, and/or the compositions of metamorphic fluids.     

Studies on the Tolerating Mechanism for Sulfide in Urechis Unicinctus (Echiura:Urechidae)-cytological observation on Urechis Unicinctus in Different Hydrogen Sulfide Environment

This study on the cytological changes of the body wall ,aspiratory intestine and crissal bursa in Urechis unicincuts by light microscope(LM) and transmission electron microscope(TEM) showed that the difference between the body wall and the natural environment rich in H2S was not obvious,that the wall color of the aspiratory intestine in H2S rich environment changed from normal semitransparency to dark brown.that its epithelia were disassembled and the electron density of its cytoplasm matrix was lower;and that in H2S rich environment many basoplhilic granules occurred in the epithelia of the crissal bursa.Granules with single membrane and myelinefingure were found with TEM.     

微生物降解有机物的碳氢同位素分馏研究进展

微生物降解使有机化合物的稳定碳、氢同位素发生不同程度分馏的研究在有机污染物来源和微生物环境修复等领域取得了长足进展,并对原油和天然气微生物降解研究有借鉴意义。微生物作用下的同位素分馏为动力同位素分馏,导致重同位素在残余物中富集。影响微生物降解有机物同位素分馏的主要因素有微生物的降解代谢途径、辅酶作用、降解类型与程度、同位素质量差异和有机物碳数等。不同的微生物代谢途径代表不同的生物化学反应,造成了同位素分馏的显著差异;辅酶对反应的催化作用使微生物作用造成的同位素分馏更加复杂。低碳数正构烷烃遭受微生物降解程度越高,碳、氢同位素的分馏也越大,同位素变重与降解程度之间有明显的相关性。但对于复杂化合物,由于降解的多级反应,同位素分馏与降解程度间的相关性并不明显。在同样降解程度下,氢同位素分馏大于碳同位素分馏,低碳数正构烷烃的同位素分馏大于高碳数正构烷烃的同位素分馏。     

气象用GX-2型水电解制氢设备电解电压的分析

分别从温度，压力，电解质以及电解液浓度等方面因素在水电解过程中对电解电压的影响进行分析，并在实际工作加以应用，从而达到降低能耗，节约成本的目的。     

The Atmospheric Oxidation of the HS Radical: Reaction with NO2

The atmospheric reaction between HS and NO₂ was theoretically investigated at 298 K and 1 atm of pressure. Our results show that the first reaction step will lead to the formation of HSNO₂ or HSONO, spontaneously and exothermically. HSONO easily decomposes into HSO + NO. On the other hand, HSNO₂ can hardly dissociate in the reactants, and its isomerization to other adducts is much hindered. Production of HNO + SO and SNO + OH was found to be unfavorable. Thus, the main products would be HSO + NO and HSNO₂, and new investigations focusing on the atmospheric fate of HSNO₂ are suggested. A general discussion of the fate of HS under atmospheric conditions is presented. Recent investigations indicate that NO₂, O₂ and N₂O should be the most important oxidants of HS, while the O₃ influence will not be significant.     

DEM analyses of crack propagation in flawed rock mass under uniaxial compressionEI北大核心CSCD

A contact model for rock is established and imbedded into a DEM software by summarizing the bond granule tests. DEM simulation of uniaxial compression test on the pre-cracked Lac du Bonnet granite is performed, and then stress distributions are further analyzed and compared with the theoretical results. Different fracture criteria are employed to predict the crack initiation angles that are compared with theoretical ones. The results show that the failure modes obtained from DEM simulation are similar to experimental results, and stress distributions in DEM simulation are qualitatively similar to theoretical values. When the angle of pre-crack is small, the lateral stresses are compressive and tensile. The compressive strains concentrate at two edges, resulting in the tensile strains in the up-and downward cracks. When the angle of the pre-crack is large enough, the stress concentration is unobvious, leading to a discrepancy between the DEM and theoretical results. The crack extension angle resulting from uniaxial compression measured from DEM tests are in good agreement with those acquired from experimental tests. These angles are consistent with theoretical predictions by the maximum circumferential stress criterion and the maximum energy release rate criterion.     

应用于被动氢钟的简单滤波器实现

在被动型氢原子钟数字伺服电路中,使用FPGA对误差信号进行数字信号处理。设计了一种简单的低通滤波器,与传统的FIR滤波器相比,节省了FPGA的使用资源,并且性能优于传统滤波器,能够很好地应用于被动型氢钟。     

海南福基田幔源辉石结构OH与氢氧同位素

采用IR光谱和质谱技术分析了海南福基田幔源巨晶和包体中辉石的结构羟基红外光谱和氢氧同位素。测试的所有巨晶普通辉石和包体中透辉石及顽火辉石均含结构OH,对比印证了国内外同类矿物的红外光谱特征。结构水质量分数分别是:普通辉石87×10-6~389×10-6;透辉石127×10-6~273×10-6;顽火辉石69×10-6~207×10-6。包体中结构水质量分数为1 811×10-6~5 377×10-6,平均为3 133×10-6。包体中辉石的氢氧同位素特征如下:透辉石的δ(D)为-123.17‰,顽火辉石的δ(D)为-132.04‰;透辉石的δ(18O)为5.96‰,顽火辉石的δ(18O)为5.60‰。实验和对比表明,辉石是海南福基田上地幔重要的"水储库",包体未受地壳成分污染,继承和保持了上地幔"富水贫氘"的特征。上述结果为该地区上地幔研究提供了结构水和氢氧同位素的基础资料。