基于元素Mn、Co、Cd、Mo的海相沉积岩有机质 富集因素判别指标在四川盆地北缘的应用

基于金属元素Mn、Co、Cd、Mo的海洋富有机质沉积岩沉积环境和有机质富集主控因素判别指标Al—Co·Mn和Co·Mn—Cd/Mo,能够有效地区分促进有机碳埋藏的两种海洋端元沉积环境:大陆边缘开放/上升洋流环境和滞留的边缘海盆环境。利用这种方法研究了四川盆地北缘城口县月亮坪剖面五峰组和龙马溪组页岩沉积时期的水体环境和有机质富集的主控因素。研究表明五峰组Mn、Co富集程度低,Mo富集程度自下而上明显增大;龙马溪组Mn整体亏损,Co富集程度低,Mo富集程度自下而上明显减小。Al—Co·Mn方法的使用发现滞留环境主要出现在五峰组早期和龙马溪组晚期,以及观音桥段附近,而五峰组中晚期和龙马溪组早—中期水体主要处于开放/上升洋流区。剖面[w(Co)/(μg/g)]·[w(Mn)/(%)]值均小于平均页岩值1.615;五峰组Cd/Mo值整体大于正常海水值0.006,全部小于平均页岩值0.308,龙马溪组整体小于正常海水值。Co·Mn—Cd/Mo联合图版的使用发现月亮坪剖面五峰组和龙马溪组有机质富集主要受到保存条件控制,与使用U/Th、V/Cr、P/Ti、Ba/Al与TOC相关性分析得出的结论一致。基于金属元素Mn、Co、Cd、Mo的判别指标对于判断古生代大陆边缘地区富有机质页岩沉积环境及有机质富集主控因素有较好的效果。     

科马提岩与苦橄岩的区别及对若干晚古生代“科马提岩”的质疑

以往学术界更多的关注科马提岩和苦橄岩的相似性,忽略其差异。通过全数据模式,采集数据库内全球的太古宙科马提岩、后太古宙低/高钛苦橄岩数据,对比三者之间的差异发现,科马提岩更富MgO、Cr、Ni、Cs、Pb、Co和Zn,其次为低钛苦橄岩(除Co和Zn),其余主量、微量元素的含量由高至低依次为高钛苦橄岩、低钛苦橄岩、科马提岩。依据元素间的差异(如Cr/Ga、MgO/Ga、MnO/Zr、Cr/Zr等),采用密度分布函数(Density Distribution)在Matlab软件中绘制出可有效区分3类岩石的等密度判别图,并用该图对若干晚古生代"科马提岩"的岩性重新厘定。结合岩相学和地球化学特征研究表明,晚古生代"科马提岩"中,印度东部为高钛苦橄岩,越南为化学成分与科马提岩类似的低钛苦橄岩,印度拉达克地区为低钛苦橄岩。     

基于稀疏判别分析的高光谱影像特征提取

针对当前特征提取方法不能充分挖掘高光谱影像稀疏特性的问题,提出一种基于稀疏判别分析的高光谱影像特征提取方法。首先,在线性判别分析的系数向量中引入稀疏正则项来捕获具有更强判别能力的特征,将高光谱影像映射至低维稀疏的子空间;然后,利用迭代优化方法对模型进行求解。利用Salinas和Pavia University高光谱影像进行对比实验,所提方法与分类方法结合用于影像分类时,其分类精度优于其他方法,总体分类精度分别达到97.42%和97.64%。     

面向高光谱图像分类的半监督空谱判别分析

为充分利用高光谱图像蕴藏的空间信息提升分类精度,提出了面向高光谱图像分类的半监督空谱判别分析(S3 DA)算法。考虑高光谱图像数据集的空间一致性,首先利用少量标记样本定义类内散度矩阵,保存数据集同类像元的光谱近邻结构;再利用无标记样本定义空间近邻像元散度矩阵,揭示像元间的空间近邻结构和地物的空间分布结构信息。S3 DA既保持数据集在光谱域的可分性,又保存了无标记样本蕴藏的空间域近邻结构,增强了同类像元和空间近邻像元在投影子空间的聚集性,从而提升分类性能。在PaviaU和Indian Pines数据集的试验表明,总体分类精度分别达到81.50%和71.77%。与传统的光谱方法比较,该算法能有效提升高光谱图像数据集的地物分类精度。     

湖南省油菜春季涝渍过程灾变判别指标

以湖南省油菜为研究对象,综合洪涝与连阴雨的致灾因子,利用历史灾情数据反演涝渍过程样本,构建临灾、受灾状态样本,采用均值t检验方法,定量分析不同降水累积衰减系数w情况下,降水因子差异的显著性,构建有效累积降水量P_E。基于Fisher判别准则,计算涝渍灾害临灾与受灾的临界线,构建逐日动态的油菜春季涝渍过程灾变判别指标y,并进行涝渍过程样本反演及独立样本验证。分析春季涝渍受灾频率与相对气象产量的关系,构建灾害影响评价模型。结果表明:当w=0.899时,受灾与临灾样本P_E的差异最显著。灾变判别指标y可逐日动态监测涝渍灾变过程及灾害后续影响,为动态监测区域油菜涝渍过程提供了数据支撑;指标指示的灾变范围与实际受灾情况基本一致,为区域防灾减灾提供了科学参考。开花期及结荚期湖南油菜涝渍受灾频率较高,成熟期较低。湖南省油菜春季涝渍灾害影响指数呈东南高西北低,长沙东部、株洲中部及北部、湘潭、永州及郴州中部油菜产量受涝渍灾害影响最重。     

判别分析在岩石可钻性分级中的应用

介绍了采用判别分析根据已知岩石级别判别未知岩石级别,或者对已经认定的岩石级别进行检验的方法。此法不仅快速简便,准确性高,而且易于在地质勘探单位推广使用。      

Integrated evaluation of urban groundwater hydrogeochemistry in context of fractal behaviour of groundwater level fluctuations

The present study was carried out as part of a complex survey of urban groundwater quality and quantity in Szeged, southeast Hungary. The concentrations of 12 inorganic contaminants in 28 shallow groundwater monitoring wells were determined over a 2-year period (2010–2012). The evaluation of concentrations indicates remarkable contamination all over the city. Discriminant analysis (DA) was used to evaluate the spatial changes of groundwater quality. The groundwater levels were measured over a 14-year period (2000–2013). The fractal properties of water level fluctuations time series characterizing the groundwater system and Tisza River were investigated using rescaled range (R/S) analysis. The resulting Hurst exponents clearly showed the persistency and thus long memory effects of both the groundwater and the river flow. Comparison of the results of DA with the results of R/S analysis thus implies that the geological conditions and the changing groundwater quantities are not related to groundwater quality.

EDITOR A. Castellarin

ASSOCIATE EDITOR A. Fiori     

Provenance discrimination of fine sediments by mid-infrared spectroscopy: Calibration and application to fluvial palaeo-environmental reconstruction

Determining sediment provenance allows a better understanding of fluvial palaeo-dynamics, and identifying involved watersheds, at broad spatio-temporal scales. Conventional approaches for source identification are usually based on the physical, mineralogical, geochemical, magnetic or isotopic properties of sediments. Rapid, non-destructive and, in well-established contexts, highly accurate, mid-infrared spectroscopy is an alternative method for investigating sediment sources. The present research objectives are: (i) to use the mid-infrared spectroscopy method to discriminate the provenance of fine sediments, by applying discriminant analysis on a large set of reference samples from three different watersheds in the Upper Rhine area (associated with the Rhine, Ill and Vosges tributaries); (ii) to clarify whether the provenance spectra signatures are influenced by riverine depositional contexts (bars versus banks) and, to some extent, by grain size and/or high organic matter content; and (iii) to apply the mid-infrared spectroscopy – discriminant analysis method to a study of fluvial palaeo-dynamics and determine the provenance of palaeo-channel infillings. Three main sedimentary sources, divided into eight sub-categories, have been characterized by 196 modern reference samples from 78 collecting sites. Discriminant analysis displayed a strong separating power by classifying correctly the origin of samples without any inter-group overlap, independently from the geomorphological context (bar or bank) and associated slight changes in organic matter contents or grain size. Mid-infrared spectroscopy – discriminant analysis investigations of the palaeo-channel infill, complemented by radiocarbon dates and mineralogical data, allowed reconstructing general trends for the local morpho-sedimentary dynamics over the last ca 12 millennia.     

基于权重反分析方法的加权距离判别法及应用

距离判别分析法在应用过程中常将各评价指标的重要性视为一致,实际上各指标重要性是不同的,故需对各指标进行加权处理。权重的合理取值对最终的评判结果有着很大的影响,目前尽管确定权重的方法有很多,但都有其不足之处。鉴于此,在马氏距离的基础上,推导了加权马氏距离的求解公式,并采用一对多的分类方法建立了多总体加权马氏距离判别准则。在确定各指标权重时采用了基于优化理论权重反分析的新思路,把直接给权重问题转化为通过实际工程样本反求各影响因素权重问题,该方法不需先知经验,求解过程完全由实际样本驱动,具有很强的可操作性。将改进后的加权距离判别分析方法应用于实际工程中的围岩分类问题,结果表明,该方法的判别结果是可靠的。距离加权的方法完善了距离判别分析法理论,权重反分析方法是一种通用方法,可用于任何求解权重的问题,为权重的求解提供了一种新思路。