花垣县李梅地区早寒武世清虚洞期碳酸盐岩中的风暴沉积

扬子地台东南缘的花垣李梅地区,早寒武世晚期清虚洞组钙质风暴岩分布广泛,表现为层数众多,剖面类型丰富,识别标志清楚,颇具特色。风暴作用强度和侵蚀力按地层层序自下而上有由弱到强的规律性变化,与本区清虚洞期陆棚浅滩化演变过程相对应。早寒武世晚期的风暴事件与本区岩相、岩性的分布,均有密切联系。     

Absorption and desorption of dichloromethane vapor by water drops in air. An experimental test of scavenging theory

An experimental study of the scavenging of dichloromethane vapor by water drops falling at terminal velocity, has been carried out in the UCLA precipitation shaft, in order to test the predictions of theoretical washout models. Whereas good agreement between theory and experiment was found for drops of radius 0.332 mm, computed gas uptake rates for 1.253 and 2.21 mm radius drops were much slower than those measured, just as reported previously for the washout of both sulfur dioxide and acetaldehyde. An analysis shows that theory can be reconciled with all of the experimental data by replacing the compound specific aqueous phase Fickian molecular diffusion coefficient used in the theory, by an effective diffusivity, having a constant value, (3×10^-4 cm² s^-1), independent of the physical and chemical nature of the absorbed species, for all drops of equivalent radii greater than 0.9 mm.     

我国多雨季和少雨季的一些统计特征

通过对我国31年124季降水距平图的分析发现1.全国性的特多(少)雨季中,在高原东侧(95—105°E间)总有一少(多)雨带出现。2.多(少)雨季之后仍为多(少)雨季的持续性以春一夏最好,秋冬最差。3.一年中出现多雨季的次数与黑潮海温和西太平洋副高强度呈正相关。     

Wet deposition of excess sulfate at Macquarie Island, 54° S

Annual wet deposition of excess sulfate at Macquarie Island has been estimated from 5 months of rainwater composition data covering the Austral summer of 1985/86. The resulting figure of 2.1±0.6 mmol/m²/yr is at the low end of previous estimates of maritime excess sulfate deposition by precipitation. Within estimated uncertainty limits this figure is consistent with the DMS emission flux which would be predicted for latitude 50°–60° S, based solely on available Northern Hemispheric DMS measurements.Temporarily at the International Meteorological Institute, Stockholm University, S-106 91, Stockholm, Sweden.     

一个高分辨对流层物质交换模式

在区域酸沉积模式(RADM)基础上,设计了一个高分辨对流层(TL)物质交换模式(EM3)。EM3在以下五个方面明显不同于RADM:第一,增加行星边界层(PBL)的垂直网格层次;第二、TL内考虑分层的垂直涡旋扩散系数型;第三,使用TL内分层的水平涡旋扩散系数型;第四,采用包含有植物冠层垂直结构影响的新干沉积速度型;第五,使用数值扩散小的二阶矩守恒平流格式.用EM3和RADM对OSCAR Ⅳ实例作对比模拟,结果表明EM3能更好地预测出TL内的三维物质分布规律,在同样条件下,两模式预测的PBL低层中心浓度比值均大于1.8,最大值可大于3。     

中国东部近百年的雨量变化

本文用279个气象测站的年雨量资料得到中国东部(100°E以东)1891—1988年大范围平均雨量资料序列.对代表性进行了检验表明:序列在1921年以后能较好地反映大范围气候旱涝状况,而1920年以前则代表性较差.从雨量变化看中国东部的气候在近百年期间是干湿交替出现的,可以分成六个时段.在近四五十年中雨量有减少的趋势,前期雨量偏多,后期从60年代中期以来雨量持续偏少.而且这种变化与北半球副热带其他地区有同相变化的关系.在50年代以前副热带地区雨量的变化却没有明显的同相关系.     

Interpretation of210Pb profiles and verification of the CRS dating model in PIRLA project lake sediment cores

This paper reports results and analysis of²¹⁰Pb-activity measurements in 51 lake-sediment cores from 32 lakes in the four PIRLA (Paleoecological Investigations of Recent Lake Acidification) project regions (Adirondack Mountains [New York], Northern New England, Northern Florida, and the Northern Great Lakes States). General application of the Constant Rate of Supply (Constant Flux) model for²¹⁰Pb dating is valid for lakes in the PIRLA study, although application of the model is equivocal in a few lakes.²¹⁰Pb inventories and profiles are replicable among closely spaced cores within a lake. Specific²¹⁰Pb activity in surface sediments is negatively correlated with bulk sediment accumulation rate in seepage lakes, but not in drainage lakes. Drainage lakes with lower pH have lower unsupported²¹⁰Pb inventories in sediments, but the relationship does not occur in seepage lakes.²¹⁰Pb profiles in only seven of the cores, all from either the Adirondacks or the northern Great Lakes states, exhibit exponential decay curves. Deviations from an exponential profile include a flattening of the profile in the top few cm or excursions of one or a few measurements away from an exponential curve.²¹⁰Pb dates typically agree with other chronostratigraphic markers, most of which are subject to greater uncertainty. Several hypotheses, including sediment mixing, hydrologic regime, sediment focusing, and acidification, are proposed to explain variation of²¹⁰Pb distribution among lakes and regions. Hydrologic factors exert control on unsupported²¹⁰Pb inventories in PIRLA lakes, and there is a strong focusing effect in drainage lakes but a weak focusing effect in seepage lakes.This is the third of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

SEDIMENT TRANSPORT OF LOW CONCENTRATION IN PIPES

The study of Sediment transport of low concentration in pipes bas been applied in the design of a self-cleansing storm sewer. An alternative criterion is suggested as op- posed to the widely used single flow velocity approach. A conceptual model which simu- lates the condition in a storm sewer is developed and tested against experimental data. The results proved that the volumetric sediment concentration, pipe diameter and sedi- ment size have to be taken into consideration to produce a self-cleansing storm sewer. It also shows that the slope obtained by this alternative criterion is lower than the single flow velocity approach.     

The effect of gas-phase chemistry on aqueous-phase sulfur dioxide oxidation rates

The rates and mechanisms of both gas and liquid phase reactions for the oxidation of sulfur dioxide play an important role in the production of atmospheric acids and aerosol particles. Rhodeet al. (1981) concluded that sulfate production rates were highly non-linear functions of sulfur dioxide emission rates. Their modelling study used an HO _x termination mechanism for the HO—SO₂ reaction in the gas-phase. Stockwell and Calvert (1983) determined that one of the products of the overall reaction of HO with sulfur dioxide was an HO₂ radical. The National Research Council (1983) using a version of the Rhodeet al. (1981) model modified to include HO₂ production from the HO—SO₂ reaction concluded that sulfate production becomes much more linear with respect to reductions in sulfur dioxide emissions. However, the cause of this increased linearity was not explained by the National Research Council report. It is demonstrated that the increased linearity is due to the coupling of gas-phases and aqueous phase chemistry. The gas-phase sulfur dioxide oxidation mechanism has a very significant effect on hydrogen perodide production rates.