山东齐河—禹城矿集区矽卡岩型铁矿成矿规律

山东西北部齐河—禹城矿集区矽卡岩型铁矿找矿工作取得了重大突破。该矿集区发育明显的航磁和重力异常,二者具有同源特征。地球物理异常查证工作显示,该区深部发育矽卡岩型铁矿床,成矿时代为早白垩世,铁矿物质主要来源于闪长岩体。铁矿体为地层、侵入岩和构造三者控矿,即铁矿体赋存于奥陶系（石炭系、二叠系）地层、闪长岩体、地层与岩体接触带附近。勘查表明,总体表现为布格重力异常梯度较陡处、剩余重力异常高值处、磁异常较高处、化极磁异常高值处以及高低电阻率转换带是该矿集区矽卡岩型铁矿的找矿有利地段。     

安徽泥河铁矿矿坑充水因素研究

安徽泥河铁矿矿区水文地质条件较复杂,矿体埋深大,在综合分析矿区水文地质条件、地表水、地下水相互水力联系的基础上,从岩层性质、地下水赋存及补给条件,确定了影响矿床充水的各因素,结果可知:泥河铁矿矿体埋藏深度大,顶底板围岩为隔水层,次生石英岩含水层为矿坑充水的主要间接补给源,其多位于矿体顶板之上50 m,受矿体上部导水性极弱的闪长玢岩层的限制,补给量微弱,对矿区大部分矿坑充水影响不大。但在矿区东北部和中部地段,受开采时冒落带以及导水裂隙带的影响,对该区域矿坑充水的影响较大。此次研究填补了该矿区深层地下水含水系统研究的空白,为准确预测矿坑涌水量提供理论依据,具有重要的参考价值和现实意义。     

辽东大台沟沉积变质型铁矿床形成时代、地球化学特征及其地质意义

辽东大台沟铁矿大地构造单元属中朝准地台胶辽台隆太子河-浑江台陷、辽阳-本溪凹陷,是近年来发现最大的“鞍山式铁矿”。利用LA-ICPMS将含铁层围岩中碎屑锆石年龄限制在2.52~2.56Ga,可推测大台沟铁矿床沉积时代约为2.54Ga左右。全岩分析结果显示SiO2、Fe2O3、FeO的含量占矿石组成的绝大部分,其它组分含量很低,说明矿石极少或者几乎没有受到陆源碎屑物质的混染。Na2O/K2O<1、ω(Sr)/ω(Ba)远远大于1,说明其为海水沉积物。Eu、Y、La具有强烈的正异常,说明形成时有热液参与。赤铁矿石中镜铁矿的发现也说明矿石为后期热液成因的产物。微量元素含量均较低,ΣREE含量较低,LREE亏损,HREE富集,稀土元素La、Eu、Y显示正异常、很高的Y/Ho比,这些特征与其它地区沉积变质型铁矿床非常相似。综合分析认为大台沟沉积变质型铁矿床成矿物质来源海底火山喷发和洋壳,火山活动活跃的部位不利于物质大量沉积,Si、Fe物质依次沉积的同时也陆续的被搬运至适合沉积成矿的位置,形成矿层,经后期区域变质变形作用、变质分异作用形成大台沟沉积变质型铁矿床。     

西藏措勤尼雄矿田滚纠铁矿磁铁矿元素地球化学特征及对成矿作用的制约

尼雄矿田滚纠铁矿地处拉萨地块隆格尔-工布江达岩浆弧,是冈底斯成矿带中生代铁铜多金属成矿作用的典型代表。在详细的野外地质调查和室内研究基础上,分析了滚纠铁矿床磁铁矿的成因矿物学特征。电子探针测试和ICP-MS分析表明,磁铁矿主量元素具有富SiO_2,贫TiO_2、V_2O_5的特征;微量元素Ba、Ti相对亏损,Cs、U相对富集,Eu、Lu、Tb、Ho、Tm强烈亏损。磁铁矿的Ti-(V+Cr)和(Ti+V)-(Al+Mn)协变图显示氧逸度、温度对矿物元素含量有明显制约作用,同时w(TiO_2)与w(CaO+MgO)、w(Na_2O+K_2O)表现出明显正相关关系,指示矽卡岩系统中流体-岩石相互作用是磁铁矿地球化学元素变化的主要控制因素。通过研究矿床中矿物生成顺序和磁铁矿中Ti、V元素特征并结合前人流体包裹体测温资料,认为矿区铁矿化阶段为高氧逸度的中高温环境,初步限定磁铁矿成矿温度为300～450℃。矿物的w(Ni)均值为8.98×10~(-6),Ni/Co比值1(变化范围0.15～0.59),Ti/V比值为6.71～25.52,从矿物化学角度进一步印证滚纠铁矿的成矿物质来源于矿区中酸性岩浆流体系统。TiO_2-Al_2O_3-(MgO+MnO)和(Ca+Al+Mn)-(Ti+V)等成因判别图解在矿区具有良好适用性,说明磁铁矿是矽卡岩矿床成矿过程的重要指示矿物。     

新疆若羌喀腊大湾铁矿床辉钼矿Re-Os定年及成因

喀腊大湾铁矿是近年来在阿尔金地区发现的超大型铁矿,目前控制储量近亿吨,且该铁矿具有品位高,低硫低磷等特点。由于矿床围岩的特殊性,该矿床的成因一直存在较大争议。利用Re-Os同位素定年方法,对喀腊大湾矿体中的5件辉钼矿样品进行了成矿时代测定,获得辉钼矿Re-Os同位素模式年龄为490±11Ma,等时线年龄为481.9±7.6Ma。二者在误差范围内基本一致。该年龄与成矿相关岩体的SHRIMP锆石U-Pb年龄488±5Ma及479±4Ma吻合,且发现的矿体附近都有闪长岩体出露,表明成岩和成矿关系密切。结合岩石学、矿物学及年代学特征,认为喀腊大湾铁矿为矽卡岩矿床。     

内蒙古固阳绿岩带高腰海BIF型铁矿锆石LA-ICP-MS年代学、地球化学特征及地质意义

内蒙古高腰海BIF（条带状建造）型铁矿位于华北克拉通西部陆块北缘,产于固阳绿岩带。矿体赋存于新太古代-古元古代色尔腾山群毛忽洞组斜长角闪岩中。铁矿石发育针柱状-粒状变晶结构,具条带状构造。矿物成分以磁铁矿、石英、角闪石为主。对选自赋矿围岩——斜长角闪岩中的热液锆石进行LA-ICP-MS U-Pb定年,得出了（1 933±12）Ma的加权平均年龄,其代表高腰海BIF富矿热事件。原岩恢复显示斜长角闪岩为正变质岩,Zr/Ti-Nb/Y图解显示其为亚碱性玄武岩系列。元素地球化学特征显示原岩可能为T-MORB（过渡型洋脊玄武岩）。结合T-MORB形成的构造环境及区域上BIF成矿规律,初步认为高腰海铁矿形成于岛弧叠加地幔柱的构造环境。     

雅满苏铁矿稀土元素地球化学特征

本文介绍了雅满苏铁矿区玄武岩、矽卡岩和铁矿石的稀土元素地球化学特征，并就其相似性和变异特征，探讨了成岩成矿物质来源和成矿作用过程，结合Ｓｒ、Ｓ、Ｃ等同位素资料，提出了成岩成矿物质来自下地壳或上地幔．成矿作用过程中，火山气液交代充填－矿浆贯入占重要地位．     

Iron Speciation in Precipitation in the North-Eastern Mediterranean and Its Relationship with Sahara Dust

Precipitation samples collected at Erdemli, Turkey, during February 1996–June 1997 were analysed to determine iron content and speciation. The purpose of the measurements was to examine the atmospheric abundance of iron and to quantify its solubility in the region. Spectrophotometric analyses of Fe(II) and reducible Fe(III) in precipitation samples, along with measurements of pH, conductivity, filterable iron (Fe_filt), particulate aluminium (Al_par) and particulateiron (Fe_par) were performed to determine iron solubility, which principally affects its bioavailability. Backward trajectories corresponding to the sampling dates were analysed to determine the sources of atmospheric constituents arriving at the site. Among these, the mineral dust transported from the Great Sahara to the region is considered to be a rich source of iron. The concentration of Fe(II) varied from below detection limit (0.02 M) up to 0.42 M,while the maximum concentration of total reactive Fe (referred as Fe(II) + reducible Fe(III) = Fe_reac) was found to be 1.0 M in precipitation. A strong correlation was found between particulate Fe and Al fractions, both of crustal origin. No correlation was observed between the soluble and insoluble fractions of iron. The soluble iron fraction, Fe(II) concentration varied independently from the concentrations of reducible Fe(III), Fe_filt, Fe_par, and from the pH of the precipitation. The Fe_filt fraction (size < 0.45 m), measuredby Atomic Absorption Spectrophotometer, and frequently interpreted to be the soluble iron fraction in the literature, was found to be significantly higher than the corresponding Fe_reac fraction inprecipitation samples, most likely due to the colloidal iron content of the Fe_filt fraction passing through the 0.45 m pore size filter. The volume weighted mean Fe_filt concentration of the precipitation samples collected during the episodic `red rain' events was found to be relatively higher. The geometric mean ratios of soluble Fe(II) and of Fe_reac to Total Fe (Fe_filt + Fe_par), werefound to be 1.6% and 2.1%, respectively, while the mean ratioof Fe_filt to Total Fe was 9.6%. The flux of bioavailable iron (Fe_reac)fraction in most atmospheric wet deposition events was found to be sufficient for supporting the maximum primary production rates that are typical for the Eastern Mediterranean Sea.