用王水分解含金矿物的机理探讨

本文从理论上对王水分解含金矿物的机理进行了探讨。在非标准状态下,温度、压力不变,改变体系中物质的浓度、酸度条件,用能斯特公式求解体系中HNO_3和Au的电极电位值,而后用EMF(电池电动势)根据规则判断反应是否可以进行。经理论计算,结论是可行的。另外由于Au~(3 )和Cl~-大量存在时,生成稳定的[AuCl_4]~-,经过络合作用,促使了HNO_3和Au的氧化还原反应,最终使含金矿物溶解完全。作者认为王水同含金矿物反应的机理是:氧化和络合的双重作用。     

方差分量估计理论及其在边角网平差中的应用

本文从理论上阐明了MINQE(I,U)(最小范数二次不变无偏估计)方差分量估计出现负方差的原因;论述了存在MINQE(U,NND)估计量的充要条件;对边角网平羞问题而言,MINQE(I,U)估计法不可能同时准确地求出边长误差模型中的m_a~2和m_b~2。文章从边角网误差模型的特点出发,提出了一种新的方差分量估计模型(改进的方差分量估计模型),该模型能合理地确定方向和边长的方差分量,从而较好地解决了边角网平差中的定权问题。     

我国多雨季和少雨季的一些统计特征

通过对我国31年124季降水距平图的分析发现1.全国性的特多(少)雨季中,在高原东侧(95—105°E间)总有一少(多)雨带出现。2.多(少)雨季之后仍为多(少)雨季的持续性以春一夏最好,秋冬最差。3.一年中出现多雨季的次数与黑潮海温和西太平洋副高强度呈正相关。     

唐山震区深反射剖面分析

为了进一步研究唐山地区深部地壳构造与唐山大地震孕育及发生的关系,国家地震局地球物理研究所在石油部物探局的协助下,于1985年1月在唐山震区完成了64km长的深反射剖面野外观测,获得了高分辨率的整个地壳结构的详细资料。分析结果表明,唐山震区内深度500m以上的沉积层十分破碎;结晶基底为前震旦纪地层,埋深2-7km不等,覆盖地层倾斜,且断层发育,其中陡河断裂为正断层,延深至6-7km,推断该断层为1976年唐山发震的重要构造之一。测线上大约21km深处普遍存在一反射层;莫霍面深度在31-32km左右,与该地区折射剖面得到的结果相当一致。     

砂岩风化晕厚度在广东晚更新世测年中的应用

广东地区河流阶地和冲积扇沉积物中砂岩砾石风化晕随时间增厚。风化晕生长速度呈指数衰减,并拟合于下列公式:T 1485D4.13这里T=时间,以年表示,D=沉积物表部约50块砾石风化晕厚度的加权平均值,以毫米表示。利用风化晕厚度确定出广东地区河流第一和第二级阶地分别为1000—13300年和8600—26500年,肇庆盆地北部山前地带第Ⅰ和第Ⅱ级冲积扇分别为51500年和24400年。同时,在构造地貌变形分析的基础上,估算出本区三条主要北东向断裂带在晚更新世—中全新世的垂直断层作用速度为0.6—1.6毫米/年,中全新世甚或晚更新世晚期以来的活动速度极小     

矿山淹井中水位、水量的快速估算和预报

本文用数理统计方法,快速估算和预报矿山淹井中水住、最高水位,矿井水涌量、涌入矿区的总水量和需要排出水量。用简单易行的反推法确定淹井的涌水量,并推导出计算式,以供使用。该方法在某矿淹井中使用,效果良好。     

Niveo-aeolian deposits and denivation forms,with special reference to the great Kobuk Sand Dunes,Northwestern Alaska

The geomorphology, lithology and chronostratigraphy of extensive, late Pleistocene inland and river dune sands, aeolian sand sheets (‘cover sands’) and loess deposits of periglacial origin in northwestern Europe are well known. However, the idea that some of these aeolian sediments result from niveo-aeolian processes is still an open question, as no diagnostic sedimentary features have yet been reported. Moreover, actual niveo-aeolian sediments and related denivation forms, reported from various cold-climate regions, are not suitable analogues. Recent observations in active dune fields in northwestern Alaska indicate that interstratification of wind-driven snow and sand preferentially occurs on slip faces of transverse, barchanoid or parabolic dune ridges. Annual denivation forms develop: e.g. snow ramparts, sinkholes, snow hummocks, snow meltwater fans and tensional cracks. The surface consists of a cracked wet sand layer with a dimpled surface and spongy structure. Although the preservation potential of these features is low in this specific case, similar features may be observed in ancient sediments elsewhere and provide useful palaeoclimatic indicators. The niveo-aeolian concept should therefore not specifically be related to late Pleistocene cover sand deposition in northwestern Europe, as previously assumed.     

Polar constituents of organic matter rich marls from evaporitic series of the Mulhouse basin

A suite of marl samples from the evaporitic series of the Mulhouse basin (France; Lower Oligocene) was studied for its biomarker content, in particular its polar constituents. Novel series of 3-carboxyalkyl steranes and 15-oxo triaromatic ketones were identified by synthesis. The 3-carboxyalkyl steranes probably originate from highly polar precursors yet unreported in living organisms. Our data suggest that micro-algae could be the major source of these compounds which seem to be indicators of high algal input rather than characteristic of evaporitic environments. The 15-oxo triaromatic ketones could be oxidation products of triaromatic steroid hydrocarbons formed during diagenesis, although their formation during work-up procedure could not be excluded.     

造盆作用及成矿盆地的历史动力综合分类建议

本文把历史分析方法与动力分析方法两种分折方法结合起来,提出了一个综合的盆地分类方案。按历史动力综合分类,造盆作用及盆地可划分为三大类:大洋壳型、雏陆壳(过渡壳)型及大陆壳型大壳型中可细分为活动区型及稳定区型。雏陆壳型包括前地槽型及地槽前期型。大陆壳型中计有地槽后期型、地台型和地洼型。