Is there a significant diffusive “salt-pump mechanism” for the transport of organic contaminants from the marine environment into fresh water aquifers? A discussion contribution

We analyse recent claims of an additional risk of diffusive intrusion by marine organic contamination (OC) into coastal aquifers, and discuss the activity-driven “salt-pump mechanism” which is claimed to accelerate this diffusion. The reported accelerations of transport of OC out of saltwater are far too large to be due to activity effects on simple diffusion. There probably is a small acceleration of diffusion out of saltwater, but there is no direct experimental evidence for this. Possible experimental artefacts are suggested. Larger effects on diffusion in the literature are shown to be not relevant to this problem. Diffusion of suspended OC, present in the experiments, is too slow to be significant; however, this suspended material is shown to have serious implications for the proposed interpretation of the results. Until these results are better understood, no conclusions about any possible environmental implications can be drawn from them.

Validation of an intrinsic groundwater pollution vulnerability methodology using a national nitrate database

The importance of groundwater for potable supply, and the many sources of anthropogenic contamination, has led to the development of intrinsic groundwater vulnerability mapping. An Analysis of Co-Variance and Analysis of Variance are used to validate the extensively applied UK methodology, based upon nitrate concentrations from 1,108 boreholes throughout England and Wales. These largely confirm the current aquifer and soil leaching potential classifications and demonstrate the benefits of combining soil and low permeability drift information. European legislation such as the Water Framework Directive will require more dynamic assessments of pollutant risk to groundwater. These results demonstrate that a number of improvements are required to future intrinsic groundwater vulnerability methodologies. The vertical succession of geological units must be included, so that non-aquifers can be zoned in the same way as aquifers for water supply purposes, while at the same time recognising their role in influencing the quality of groundwater in deeper aquifers. Classifications within intrinsic vulnerability methodologies should be based upon defined diagnostic properties rather than expert judgement. Finally the incorporation into groundwater vulnerability methodologies of preferential flow in relation to geological deposits, soil type and land management practices represents a significant, but important, future challenge.

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Resumen La importancia de las aguas subterráneas en el abastecimiento de agua potable, y las muchas fuentes de contaminación antropogénica, ha llevado al desarrollo del mapeo de vulnerabilidad a la contaminación intrínseca de aguas subterráneas. Se han utilizado un análisis de co-varianza y análisis de varianza para validar la metodología que se ha aplicado extensamente en UK basada en concentraciones de nitrato de 1108 pozos a través de Inglaterra y Gales. Se confirma ampliamente las clasificaciones actuales de acuíferos y potencial de lixiviación del suelo y se demuestra los beneficios de combinar la información de suelos y derrubios de baja permeabilidad. La legislación europea tal como el Marco Directivo del Agua requerirá evaluaciones más dinámicas del riesgo a la contaminación de agua subterránea. Estos resultados demuestran que se requieren varias mejoras en las metodologías futuras de vulnerabilidad intrínseca a la contaminación de agua subterránea. Tiene que incluirse la secuencia vertical de las unidades geológicas de modo que las unidades que no son acuíferos puedan zonificarse de la misma manera que los acuíferos con fines de abastecimiento de agua, mientras que al mismo tiempo se reconozca el papel que tienen en la influencia de la calidad de agua subterránea en acuíferos profundos. Las clasificaciones de las metodologías de vulnerabilidad intrínseca deberían basarse en las propiedades diagnósticas características más que en el juicio experto. Finalmente la incorporación de flujo preferencial en las metodologías de vulnerabilidad de agua subterránea en relación a las formaciones geológicas, tipo de suelo y prácticas de manejo de la tierra representa un desafío futuro no solo significativo sino que importante.

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Résumé Limportance des eaux-souterraines pour lalimentation en eau potable, et les multiples sources de contaminations anthropiques, ont conduit au développement de cartes de vulnérabilité intrinsèque des eaux souterraines aux pollutions. Une analyse de la co-variance et lanalyse de la variance sont utilisées pour valider la méthodologie extensive utilisée en UK, basée sur les concentration en nitrates de 1108 forages en Angleterre et en Ecosse. Ceci confirme les classifications courantes basées sur la nature des aquifères et le potentiel de lessivage des sols, et démontre le bénéfice que lon peut tirer à combiner linformation dérivant des sols et des faibles perméabilités. La législation européenne telle la Directive Cadre Européenne demandera des évaluations plus dynamiques des risques de pollution affectant les eaux souterraines. Ces résultats démontrent quun certain nombre daméliorations sont nécessaires aux futures méthodes de vulnérabilité intrinsèque des eaux souterraines. La succession verticale dunités géologiques doit être pris en compte, de telle manière que les parties non-aquifères puissent être zonées de la même manière que les aquifères pour lapprovisionnement en eaux potables, et reconnaître par la même occasion leur influence sur la qualité des eaux souterraines dans les aquifères profonds. Les classifications utilisées dans les méthodes de vulnérabilité intrinsèque devraient être basées sur les propriétés dun diagnostique défini plutôt que sur un jugement expert. Finalement lincorporation, dans les méthodes de vulnérabilité intrinsèque, des écoulements préférentiels en relation avec les formations géologiques, les types de sol et les pratiques daménagement du territoire représentent un challenge futur significatif et ortant.

     

A reactive flow model of the geothermal reservoir Waiwera, New Zealand

A numerical model of the complex interaction between fluid flow, heat transfer, and chemical reactions of the shallow, coastal, hydrothermal system of Waiwera (New Zealand) is used to test the proposed conceptual model of the field.Due to declining water levels, resulting from over-exploitation during the 1970s, the objective here was to set up a coupled fluid flow and heat transfer model to help in enabling a predictive and sustainable use of the resource. The presented conceptual model of the area is based on hydraulic, thermal, and chemical field observations, which date back as far as 1863. The numerical simulations were carried out with the reactive transport code SHEMAT.The inflow of geothermal water at the bottom of the reservoir prevents seawater from entering the aquifer. If seawater intrusion occurs, it is due to over-exploitation and happens in the upper parts of the aquifer. This is in contrast to common seawater-freshwater interfaces where seawater intrudes at the bottom. The numerical investigations emphasize that, after modifications of the production regime in the late 1980s, the system is recovering again.Additionally, geochemical calculations have been conducted to answer the question if dissolution or precipitation reactions might change the hydraulic properties of the geothermal aquifer. Mixing of fresh, geothermal, and seawater, although each of them in thermodynamic equilibrium with calcite, lead to calcite precipitation or dissolution. Nevertheless, the simulations show that the hydraulic properties of the aquifer are not significantly affected by dissolution or precipitation.

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Resumen Se ha utilizado un modelo numérico de la interacción compleja entre el flujo de fluidos, la transferencia de calor y las reacciones químicas del sistema hidrotermal costero poco profundo de Waiwera (Nueva Zelanda) con el objeto de probar el modelo conceptual del área propuesto. Debido a los niveles de agua decrecientes, el objetivo de este trabajo es establecer un modelo pareado del flujo de aguas y de la transferencia de calor para colaborar en el uso predecible y sostenible del recurso. El modelo conceptual del área presentado está basado en observaciones de terreno hidráulicas, termales y químicas que datan de 1863. Las simulaciones se llevaron a cabo con el código de transporte reactivo SHEMAT. El influjo de agua geotermal al fondo del reservorio impide que el agua de mar entre en el acuífero. Si la intrusión de agua de mar se presenta, esto sucede a causa de la sobreexplotación y ocurre en las partes superiores del acuífero. Esto contrasta con las interfaces comunes de agua de mar-agua dulce donde la intrusión del agua de mar se da al fondo. Las investigaciones numéricas enfatizan que el sistema se está recuperando de nuevo luego de las modificaciones al regimen de producción a fines de los 80. Adicionalmente, los cálculos geoquímicos están dirigidos a contestar si las reacciones de disolución o precipitación pueden cambiar las propiedades hidráulicas del acuífero geotérmico. La mezcla de agua dulce, geotermal y de mar causa precipitación o disolución de calcita a pesar de que cada una de ellas se encuentra en equilibrio termodinámicao con la calcita. Sin embargo, las simulaciones muestran que las propiedades hidráulicas del acuífero no son afectadas siginificativamente por la disolución o precipitación.

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Résumé Un modèle numérique de linteraction complexe entre lécoulement de leau, le transfert de chaleur et les réactions chimiques du système hydrothermal côtier peu profond de Waiwera (Nouvelle-Zélande) est utilisé afin de tester le modèle conceptuel. Lobjectif est de bâtir un modèle couplé découlement et de transfert de chaleur afin dencourager une approche prévisioniste et une utilisation durable de la ressource en réponse à des niveaux deau en déclin qui résultent dune surexploitation depuis les années 1970. Le modèle conceptuel présenté est basé sur des observations de terrain concernant lhydraulique, la température et la composition chimique de laquifère, des observations qui peuvent dater daussi loin que 1863. Les simulations numériques ont été réalisées avec le modèle de transport SHEMAT. Lentrée deau géothermale à la base du réservoir préviens lintrusion deau de mer dans laquifère. Si lintrusion deau de mer a lieu, elle est due à la surexploitation qui a lieu dans la partie supérieure de laquifère. Cette situation est lopposée des interfaces eau de mer - eau douce traditionnelles où leau de mer pénètre par la base. Les simulations numériques suggèrent que suite aux modifications du régime de production à la fin des années 1980, le système récupère. De plus, des calculs géochimiques ont été effectués afin de répondre à la question à savoir si les réactions de dissolution et de précipitation changent les propriétés hydrauliques de laquifère géothermal. Le mélange de leau douce, leau géothermale et leau de mer, même si elle sont tous en équilibre thermodynamique avec la calcite, provoque la dissolution ou précipitation de la calcite. Néanmoins, les simulations montrent que les propriétés hydrauliques de laquifère ne sont pas significativement affectées par la dissolution ou la précipitation.

     

Geoarchaeological evidence for dredging in Tyre's ancient harbour, Levant

Chrono-stratigraphic data from Tyre's ancient northern harbour delineate extensive dredging practices during the Greco-Roman and Byzantine periods. Radiocarbon dates from four cores consistently cluster between ca. 500 B.C. and 1000 A.D. and indicate rapid rates of sedimentation in the basin, namely ∼10 mm/yr during the Greco-Roman and Byzantine periods, compared to 0.5-1 mm/yr for the period 6000-4000 B.C. Absence of strata between 4000 B.C. and 500 B.C. is not consistent with a natural base-level sediment sink and cannot be interpreted as a depositional hiatus in the high-stand systems tract. Ancient dredging is further corroborated by persistent age-depth inversions within the fine-grained harbour facies. These data support removal of Middle Bronze Age to Persian period sediment strata, with deliberate overdeepening of the harbour bottom by Greco-Roman and Byzantine societies.     

Prediction of in-situ block size distributions with reference to armourstone for breakwaters

Understanding a quarry in terms of its potential for breakwater construction materials presents a special challenge for the engineering geologist. Unlike blasting in aggregates and mining operations, optimisation of the extraction process has a focus on the potential for production of large blocks for armourstone. These blocks weighing many tonnes are used for cover layers to resist wave action. The quarry-run is used for breakwater core. If the quarry has been developed as a source of materials dedicated to a breakwater construction project, the success of the project depends greatly on the blasting and production of rock sizes that are required and the avoidance of leaving a massive quantity of unused materials behind in the quarry after project completion. Prediction of in-situ block sizes such as from joint spacing data, provides the most critical input for the prediction of the blast pile block size distribution (BBSD), which in turn is a vital early design input if the constructed breakwater is to be economical as well as effective.This paper is part of a series of papers that introduces the coastal engineering motivation for this work on engineering geology, giving reasons why the prediction of the fragmentation curve of the blast products in a dedicated quarry is of such economic importance for breakwater projects. The first step towards blasted block size distribution (BBSD) prediction is the prediction of the in-situ block sized distribution (IBSD), the main subject of this paper. Drawing together research methods from the 1990s and the rock mechanics principles of discontinuity analysis, a practical step by step methodology for IBSD assessment that includes approaches that are not reliant on specialised computer software is presented. Continuing on the practical theme, a new extension of the volumetric joint count approach is suggested for IBSD prediction for the case when sparse borehole data is all that is available. A case study of IBSD assessment and the associated BBSD and blast assessment is presented from a Carboniferous limestone quarry. For clarity, details of blast design and yield curve prediction that are recommended for use in the context of armourstone production, have been presented in a companion paper. The Rosin-Rammler equation is used as an example form for the BBSD prediction of a dedicated quarry and the potential for breakwater project optimisation is illustrated. The final section sets out a method for directly comparing yield curves together with the demand for materials set by the breakwater design. On the same plot, sizes where there is a relative shortfall in production can be identified. The dependence of effective breakwater design on accurate quarry yield prediction and quarry blasting performance is discussed.     

Studies of Aerosols in The Marine Boundary Layer in the Coastal Area During The EOPACE’99 Campaign

Results are presented based on measurements taken using an FLS-12 lidar system and laser particle counters only on the Atlantic coast of the U.S.A. during a campaign within the scope of the international EOPACE experiment. The objectives of the EOPACE (Electro-optical Propagation Assessment in Coastal Environments) effort, which was conducted in Duck, N.C. (U.S.A.) between 25 February and 11 March 1999, involved investigating, developing and evaluating ocean and coastal aerosol models and their effects on visibility; integrating and developing simple, realistic models for infrared propagation near the ocean surface and developing a consistent chemical/optical model for aerosol particles suitable for inclusion in navy meteorological models.     

高速公路路基边坡环境综合治理

随着我国高速公路建设的全面展开,环境保护越来越引起业内人士的高度重视。通过对综合治理思路和方法的阐述和总结,以引起业内共鸣,从而推动我国高速公路建设早日走上“生态高速”的道路。     

The Tsunami of August 17, 1999 in Izmit Bay,Turkey

The Kocaeli 1999 Earthquake with an Mw = 7.4 caused major hazards throughout the NW of Turkey from Tekirdag to Bolu. Historical data indicates that some of the earthquakes around Izmit Bay have caused tsunamis. In this study, tsunami research for the Kocaeli 1999 Earthquake has been made also taking into consideration historical data. In this research more than about 70 data at 35 localities have been used to determine the tsunami evidences in the bay. Coastal observations indicated runups which were ranging from 1 to 2.5 m along the shores. However, the wave runups are more complex along the south coast due to the presence of coastal landslides (Deirmendere, Halidere, Ulasli, Karamürsel) and subsided areas (Kavakli to Yeniköy) along the shore. West of Yalova, evidence of tsunami rapidly diminished. In addition, possible tectonic mechanism has been determined by using 33 single-channel high-resolution digital seismic reflection profiles which were acquired following the Kocaeli 1999 Earthquake. As a result it has been determined that the Kocaeli Earthquake has created tsunami in Izmit Bay.     

如何提高自动气象站数据文件质量

在环境影响评价工作中,提出合理的环境保护对策、措施,对发展生产保护环境是非常重要的,而污染治理的手段既与工程排污特征有关,也随时在发展变化,本文仅对高炉出铁场无组织排放烟气的成熟治理技术进行介绍,以便提高建设项目环境影响报告书的质量,加快建设项目环境影响报告书技术评估的速度。     

Air-sea interaction including a shallow and coastal zone

We performed special experimental and theoretical research concerning the energy--mass exchange process in shallow waters, which took into account the influence of the basin depth on the evaporation and sensible heat exchange. Data was obtained from deep water basins, as well as from shallow waters, at an open sea, as well as in its coastal zone. A new parameterization model of evaporation and friction velocity from shallow water surfaces under different wind velocities was investigated. Results of models and measurements of the energy/mass exchange intensity of a small shallow lake (LITFASS-experiments) were compared. The validation of these models with the eddy-covariance measurements of the LITFASS-98 and LITFASS-2003 experiments showed good results for the wind sector, with good fetch conditions. Therefore, the models examined may be used for calculating the evaporation of lakes where a standard data set of wind velocity, air and water temperature, air moisture and the depth of the lake is available. It should be remembered that in a coastal zone the roughness of the water surface is transformed and therefore there are additional calculation difficulties for the intensity of the energy-mass exchange. Based on our experimental data of the basin depth influence on the water-atmosphere exchange, a new model for the calculation of the energy-mass exchange in a coastal zone was developed. Our new model in combination with the empirical dependence for the calculation of the energy-mass exchange in a coastal zone allows calculation of the momentum, heat and humidity fluxes values at different distances from a shore.