β-1, 4-半乳糖基转移酶抑制剂的研究进展

β-1,4-半乳糖基转移酶(β-1,4-GalT)抑制剂的研究是当今糖化学和糖生物学的前沿研究领域之一。本文就β-1,4-GalT抑制剂(包括供体类似物、受体类似物、过渡态类似物)的设计、合成及活性评价诸方面予以综述。     

光测力学方法在薄壁钢-混凝土组合结构节点试验中的应用

应用光测力学中的数字散斑图像处理技术和网格法对对称荷载下的薄壁钢-混凝土组合结构节点的试验进行了监测,得到了节点的一些相关位移,并与百分表法测量的结果进行了比较。结果表明,两种方法用于轻钢组合结构构件的位移测量是足够精确的,可以根据试验的不同要求选择测量方法。     

辽北-吉西南地区早白垩世富碱花岗岩地质特征

辽北-吉西南地区早白垩世富碱质花岗岩主要由碱长花岗岩、石英二长岩组成,同位素年龄为125 Ma左右,岩石化学以富碱、富硅为特征,具A型花岗岩特点,但铝质偏高,又具过铝质花岗岩的特点,应属于后造山期之PA型花岗岩。其构造背景为晚印支期-早燕山期滨太平洋造山带造山晚期坍塌阶段的产物。     

喀什凹陷中生代以来的构造事件对中-下侏罗统铀矿化的影响

喀什凹陷是我国西部重要的含铀区,自中生代以来主要发生过5次重大构造事件,对该地区中-下侏罗统铀矿成矿及保矿具有重要意义,即晚三叠世有利的构造背景,早-中侏罗世有利的构造-沉积环境形成的有利岩性-岩相建造,晚侏罗世构造掀斜与古层间氧化带及铀矿化的形成,白垩纪-古近纪的保矿作用及新近纪以来的构造破坏与局部层间氧化带的形成与叠加,从而很可能在中-下侏罗统中形成一定规模受层间氧化带控制的砂岩型铀矿床。指出主要找矿靶区为库孜贡苏断陷以西的南天山山前,同时还有托云盆地。     

黄土高原西部白草塬剖面L1 和S1 记录的古地磁场特征

文章详细介绍了黄土高原西部白草塬剖面L1和S1的高精度岩石磁学和古地磁学结果,讨论了白草塬剖面记录古地磁场的特征,从古地磁学角度探讨白草塬剖面黄土沉积的连续性.白草塬剖面黄土沉积物中,磁铁矿和磁赤铁矿是主要的亚铁磁性矿物,粗粒的碎屑磁铁矿是其天然剩磁和特征剩磁的主要载体.白草塬剖面L1和S1没有记录任何地磁漂移.其中,L1没有记录Mono Lake或Laschamp地磁漂移的原因可归结于黄土沉积物堆积过程的不连续性和/或粗颗粒载磁矿物的重磁化,但前者是主要原因,而堆积过程的不连续性是导致S1没有记录Blake地磁漂移的主要原因.因此,白草塬剖面的L1和S1分别存在约2000年和 4000～6000年的沉积不连续.     

海南岭壳铜(银-金)矿床地质特征及找矿方向

岭壳铜(银-金)矿床赋存于白垩纪岭壳村组流纹质角砾凝灰熔岩和早白垩世花岗闪长岩中.目前已发现11条铜(银-金)矿(化)体,矿体的产出严格受断裂破碎带控制,与成矿关系密切的围岩蚀变呈现出自东(20线)向西的钾化→绢云母化→强高岭石化、绿泥石化蚀变分带,矿化相应呈现从铜(金)向铜(银)的过渡.根据其对称性的蚀变分带,应加强20线以东的地质找矿;根据成矿元素分形和统计研究发现,Au,Ag矿化具有专属性,即在流纹质凝灰熔岩中寻找Cu,Ag矿,而在花岗闪长岩中以寻找Cu,Au矿为主.     

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters     

Isotopes and Geochronology of the Meixian-type Pb-Zn-(Ag)Deposits,Central Fujian Rift,South China:Implications for Geological Events

Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the 834S ranging from -3.5‰ to ＋5.6‰ averaging at ＋2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character （206pb/204pb〉18.140, 207Pb/204pb〉15.584, 208pb/204pb〉38.569） and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metailogenesis （The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore- hosted wall rocks are calculated to be among 933-1788 Ma.） and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis （intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127-154 Ma）.     

鄂尔多斯地块早白垩世构造-热事件:杭锦旗玄武岩的Ar-Ar年代学证据

在鄂尔多斯地块北部杭锦旗黑石头沟,于下白垩统砂岩之上发现了一层玄武岩。其SiO2(46.93%)较低而碱含量(K2O+Na2O=6.21%)较高,组合指数σ=8.0,含标准矿物Ne,属于碱性橄榄玄武岩。Ar-Ar激光阶段加热定年结果表明,该玄武岩具有126.2±0.4Ma的Ar-Ar年龄。年龄数据表明杭锦旗黑石头沟玄武岩形成于早白垩世,反映鄂尔多斯地块在早白垩世发生了一次构造-岩浆-热事件,这与华北、乃至整个中国东部在早白垩世发生了较普遍的构造-岩浆-热事件具有一致性。这次构造-岩浆-热事件可能引起深部流体自地下深部上涌及在地块内部运移,为各种成矿元素的迁移、沉淀、富集和成矿创造了合适条件。     

南海北部深水盆地沉积-构造的差异性及其油气意义

南海北部深水区自西向东依次分布着琼东南盆地、珠江口盆地、台西南盆地等新生代被动陆缘盆地,这些盆地经历了大致相当的从裂陷到坳陷的构造演化史,但在张裂活动过程中存在着明显的沉积-构造的差异性。构造沉降特征分析显示:在同一构造带上自西向东有盆地主要构造沉降发生的时段逐步变晚的趋势;在不同构造带上自北向南有盆地主要构造沉降发生的时段逐步变晚的趋势。这种沉积-构造的差异性对烃源岩的发育类型、分布及生储盖组合等方面有明显的控制作用,表现为:裂谷期构造沉降幅度大的盆地,陆相烃源岩发育,以陆生陆储陆盖型成藏组合为主;裂后期构造沉降幅度大的盆地,海相烃源岩发育规模较大,海生海储海盖型成藏组合及混生海储海盖型生储盖组合所占分量逐渐增多。推测渐新统湖相-湖沼相及海陆过渡相源岩和中新统海相烃源岩应是南海北部深水区油气的主要来源,陆生海储海盖型、海生海储海盖型及混生海储海盖型生储盖组合应是深水区基本生储盖组合类型。