兖州矿区煤中某些微量元素的赋存状态研究

微量元素的赋存状态决定其在煤的加工利用过程中释放的难易程度和毒性，弄清其在煤中的赋存状态，对准确评价元素的工艺性能、环境影响、作为副产品的可能性以及在地质意义上都是十分重要的。分析了微量元素在煤中的有机亲合性，采用数理统计方法，求得了微量元素与煤中有机显微组分、三态硫、灰分之间的相关性，并在浮沉实验的基础上，分析了微量元素的存在状态，通过研究向知，Ge、Ga、U、V、Cu、Th、Pb和Zn主要以无机态存在于煤中，F和Cl可能以有机态存在为主，As无机态和有机态存在的机率相似。     

古—中生代之交的全球变化与生物效应

古—中生代之交是显生宙以来最大的一次生物绝灭期 ,其形成机制一直是地学界长期探讨的热点课题之一。地史重大转折期是地球内、外各圈层长期作用下 ,各种量变达到阀值 ,加之可能的外因激化 ,在短时间内以连锁反应形式相继质变 ,形成了全球变化 (包括生物绝灭 )的地球突变期。文中从可能的外因 (外星体撞击事件 )及内因 (岩石圈的变化 ,地球表层的变化和生物圈的变化 )两个方面探讨了古—中生代之交的全球变化与生物效应     

青藏高原北羌塘半岛湖新生代粗面玄武岩橄榄石电子探针和激光探针分析

利用电子探针和激光探针剥蚀系统（LA-ICP-MS），对北羌塘新第三纪粗面玄武岩中的橄榄石主元素和微量、稀土元素进行了系统分析。结果表明，本区橄榄石Fo平均为88，属贵橄榄石种属。相对富集Ni、Co和重稀土，而强烈亏损轻稀土及Rb、Sr、Ba、Zr等大离子亲石元素。其稀土元素配分型配分型式与粗面玄武岩全岩稀土配分型式呈互补状态。     

西范坪斑岩铜矿钾硅酸盐化作用的地球化学研究

西范坪铜矿是我国近年来新发现的斑岩型铜矿床。伴随铜矿化发生了强烈的钾硅酸盐化。蚀变作用使成矿主岩的 Si O2 ,K2 O增加 ,Ca O,Na2 O,Fe2 O3 减少 ;大离子亲石元素含量降低 ;L REE减少 ,L a N/ Yb N 比值升高 ,δEu值降低。通过研究认为 ,西范坪铜矿成矿母岩是富钠 (Na2 O>K2 O)斑岩 ,而不是富钾 (K2 O>Na2 O)岩石 ,这说明相对富钠的斑岩也能成矿。     

Labour markets in transition. The experiences of women in two border regions of East Germany

The political turning point in the former GDR and the transformation processes that have been observed since then have significantly affected economic and social structures in the new Federal States. Gender roles, however, were subjected to even more dramatic changes. Whilst many women experienced the employment policies of the GDR era as beneficial, social researchers often designate them as the losers of unification nowadays. This is largely because the abundance of State support measures for employed women and mothers has been drastically reduced and women as a group have been hit hardest by the crisis on the East German labour market. Using two cases (Mecklenburg-Westpommerania and Thuringia), this paper aims to illustrate the impact of the transformation process on the everyday (working) lives of women. We are particularly concerned with a comparative analysis of how women experience and deal with regional disparities in East Germany. This revised version was published online in July 2006 with corrections to the Cover Date.     

The eastern Tonale fault zone: a ‘natural laboratory’ for crystal plastic deformation of quartz over a temperature range from 250 to 700 °C

Near the eastern end of the Tonale fault zone, a segment of the Periadriatic fault system in the Italian Alps, the Adamello intrusion produced a syn-kinematic contact aureole. A temperature gradient from 250 to 700 °C was determined across the Tonale fault zone using critical syn-kinematic mineral assemblages from the metasedimentary host rocks surrounding deformed quartz veins. Deformed quartz veins sampled along this temperature gradient display a transition from cataclasites to mylonites (frictional–viscous transition) at 280±30 °C. Within the mylonites, zones characterized by different dynamic recrystallization mechanisms were defined: Bulging recrystallization (BLG) was dominant between 280 and 400 °C, subgrain rotation recrystallization (SGR) in the 400–500 °C interval, and the transition to dominant grain boundary migration recrystallization (GBM) occurred at 500 °C. The microstructures associated with the three recrystallization mechanisms and the transitions between them can be correlated with experimentally derived dislocation creep regimes. Bulk texture X-ray goniometry and computer-automated analysis of preferred [c]-axis orientations of porphyroclasts and recrystallized grains are used to quantify textural differences that correspond to the observed microstructural changes. Within the BLG- and SGR zones, porphyroclasts show predominantly single [c]-axis maxima. At the transition from the SGR- to the GBM zone, the texture of recrystallized grains indicates a change from [c]-axis girdles, diagnostic of multiple slip systems, to a single maximum in Y. Within the GBM zone, above 630±30 °C, the textures also include submaxima, which are indicative of combined basal a- and prism [c] slip.     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Iron colloids/organic matter associated transport of major and trace elements in small boreal rivers and their estuaries (NW Russia)

The chemical status of major and trace elements (TE) in various boreal small rivers and watershed has been investigated along a 1500-km transect of NW Russia. Samples were filtered in the field through a progressively decreasing pore size (5, 0.8 and 0.22 μm; 100, 10, and 1 kD) using a frontal filtration technique. All major and trace elements and organic carbon (OC) were measured in filtrates and ultrafiltrates. Most rivers exhibit high concentration of dissolved iron (0.2–4 mg/l), OC (10–30 mg/l) and significant amounts of trace elements usually considered as immobile in weathering processes (Ti, Zr, Th, Al, Ga, Y, REE, V, Pb). In (ultra)filtrates, Fe and OC are poorly correlated: iron concentration gradually decreases upon filtration from 5 μm to 1 kD whereas the major part of OC is concentrated in the <1–10 kD fraction. This reveals the presence of two pools of colloids composed of organic-rich and Fe-rich particles. According to their behavior during filtration and association with these two types of colloids, three groups of elements can be distinguished: (i) species that are not affected by ultrafiltration and are present in the form of true dissolved inorganic species (Ca, Mg, Li, Na, K, Sr, Ba, Rb, Cs, Si, B, As, Sb, Mo) or weak organic complexes (Ca, Mg, Sr, Ba), (ii) elements present in the fraction smaller than 1–10 kD prone to form inorganic or organic complexes (Mn, Co, Ni, Zn, Cu, Cd, and, for some rivers, Pb, Cr, Y, HREE, U), and (iii) elements strongly associated with colloidal iron in all ultrafiltrates (P, Al, Ga, REE, Pb, V, Cr, W, Ti, Ge, Zr, Th, U). Based on size fractionation results and taking into account the nominal pore size for membranes, an estimation of the effective surface area of Fe colloids was performed. Although the total amount of available surface sites on iron colloids (i.e., 1–10 μM) is enough to accommodate the nanomolar concentrations of dissolved trace elements, very poor correlation between TE and surface sites concentrations was observed in filtrates and ultrafiltrates. This strongly suggests a preferential transport of TE as coprecipitates with iron oxy(hydr)oxides. These colloids can be formed on redox boundaries by precipitation of Fe(III) from inflowing Fe(II)/TE-rich anoxic ground waters when they meet well-oxygenated surface waters. Dissolved organic matter stabilizes these colloids and prevents their aggregation and coagulation. Estuarine behavior of several trace elements was studied for two small iron- and organic-rich rivers. While Si, Sr, Ba, Rb, and Cs show a clear conservative behavior during mixing of freshwaters with the White sea, Al, Pb and REE are scavenged with iron during coagulation of Fe hydroxide colloids.     

Abundance and distribution of PGE and Au in the island-arc mantle: implications for sub-arc metasomatism

Ultramafic xenoliths from a veined mantle wedge beneath the Kamchatka arc have non-chondritic, fractionated chondrite-normalized platinum-group element (PGE) patterns. Depleted (e.g., low bulk-rock Al₂O₃ and CaO contents) mantle harzburgites show clear enrichment in the Pd group relative to the Ir group PGEs and, in most samples, Pt relative to Rh and Pd. These PGE signatures most likely reflect multi-stage melting which selectively concentrates Pt in Pt–Fe alloys while strongly depleting the sub-arc mantle wedge in incompatible elements. Elevated gold concentrations and enrichment of strongly incompatible enrichment (e.g., Ba and Th) in some harzburgites suggest a late-stage metasomatism by slab-derived, saline hydrous fluids. Positive Pt, Pd, and Au anomalies coupled with Ir depletions in heavily metasomatized pyroxenite xenoliths probably reflect the relative mobility of the Pd and Ir groups (especially Os) during sub-arc metasomatism which is consistent with Os systematics in arc mantle nodules. Positive correlations between Pt, Pd, and Au and various incompatible elements (Hf, U, Ta, and Sr) also suggest that both slab-derived hydrous fluids and siliceous melts were involved in the sub-arc mantle metasomatism beneath the Kamchatka arc.     

Post-mid-Cretaceous eastern North Sea evolution inferred from 3D thermo-mechanical modelling

The Late Cretaceous–Cenozoic evolution of the eastern North Sea region is investigated by 3D thermo-mechanical modelling. The model quantifies the integrated effects on basin evolution of large-scale lithospheric processes, rheology, strength heterogeneities, tectonics, eustasy, sedimentation and erosion.

The evolution of the area is influenced by a number of factors: (1) thermal subsidence centred in the central North Sea providing accommodation space for thick sediment deposits; (2) 250-m eustatic fall from the Late Cretaceous to present, which causes exhumation of the North Sea Basin margins; (3) varying sediment supply; (4) isostatic adjustments following erosion and sedimentation; (5) Late Cretaceous–early Cenozoic Alpine compressional phases causing tectonic inversion of the Sorgenfrei–Tornquist Zone (STZ) and other weak zones.

The stress field and the lateral variations in lithospheric strength control lithospheric deformation under compression. The lithosphere is relatively weak in areas where Moho is deep and the upper mantle warm and weak. In these areas the lithosphere is thickened during compression producing surface uplift and erosion (e.g., at the Ringkøbing–Fyn High and in the southern part of Sweden). Observed late Cretaceous–early Cenozoic shallow water depths at the Ringkøbing–Fyn High as well as Cenozoic surface uplift in southern Sweden (the South Swedish Dome (SSD)) are explained by this mechanism.

The STZ is a prominent crustal structural weakness zone. Under compression, this zone is inverted and its surface uplifted and eroded. Contemporaneously, marginal depositional troughs develop. Post-compressional relaxation causes a regional uplift of this zone.

The model predicts sediment distributions and paleo-water depths in accordance with observations. Sediment truncation and exhumation at the North Sea Basin margins are explained by fall in global sea level, isostatic adjustments to exhumation, and uplift of the inverted STZ. This underlines the importance of the mechanisms dealt with in this paper for the evolution of intra-cratonic sedimentary basins.