西藏驱龙斑岩铜钼矿地球化学异常特征

驱龙铜矿发育多元素的岩石地球化学异常.成矿元素Cu、Mo、(Ag)异常强、规模大,异常与矿化区一致;伴生元素Au、Bi、Pb、As、Sb、Hg异常在Cu、Mo异常边部并套合产出的B Co、Ni Mn Zn的异常主要分布铜钼矿化带外侧.Na₂O在矿化区显示负异常,K₂O为正异常.从异常元素组合、水平分带性和贫Na₂O、富K₂O的成矿环境表明,矿床属典型的斑岩型铜矿地球化学特征,并受到了强烈的剥蚀.     

呼和浩特市环境地球化学特征初探

介绍了呼和浩特市环境地球化学特征,对该区土壤次生环境进行了质量分区划分,探讨该区土壤环境地球化学元素迁移概略,提出了土壤环境地球化学治理的具体意见.     

基于自然水系网信息的元素运移分析

地面上的矿物或污染物元素主要是随水系而运移的。因此，利用自然水系网信息来定量分析元素沿水系的迁移、分散，对于地质找矿和环境保护都具有重要意义。在研究应用主概率权模拟模型产生自然水系网的基础上，提出了元素在水系网中运移的计算方法，结合所模拟出的水系网，具体分析了元素在其中的迁移、扩散情况，给出了正问题和反问题的计算结果。结果表明，正、反问题的求解具有一致性，方法是有效、可行的。     

济阳坳陷稀土元素特征及其在物源对比中的应用

物源是控制沉积物中REE组成最主要的因素，济阳坳陷区岩石稀土元素特征表明：①济阳坳陷古生界与华北地台其他地区同时代地层岩石的REE分布特征具有极大的相似性，这体现了晚古生代济阳坳陷区所处的整个华北地台区为一稳定的克拉通沉积盆地，地层横向分布稳定，具有一致的物源和构造背景；②济阳坳陷古生界为中生界的物源，反映了济阳坳陷区由古生代稳定地台型沉积到中生代山间盆地沉积的转变，中生代洼陷区的沉积主要来自对附近凸起区古生代地层的剥蚀；③新生界样品与中生界样品的REE分布模式具有很大的相似性，从一个侧面反映了济阳坳陷中生代与新生代的构造格局的转变，中生代接受沉积的部分洼陷区至古近纪成为供给物源的凸起区。     

Laser Ablation ICP-MS Analysis of Geological Materials Prepared as Lithium Borate Glasses

A simple, rapid and precise method is described for determining trace elements by laser ablation (LA)-ICP-MS analysis in bulk geological materials that have been prepared as lithium borate glasses following standard procedures for XRF analysis. This approach reliably achieves complete sample digestion and provides for complementary XRF and LA-ICP-MS analysis of a full suite of major and trace elements from a single sample preparation. Highly precise analysis is enabled by rastering an ArF excimer laser (λ= 193nm) across fused samples to deliver a constant sample yield to the mass spectrometer without inter-element fractionation effects during each analysis. Capabilities of the method are demonstrated by determination of twenty five trace elements (Sc, Ti, V, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Hf, Ta, Pb, Th and U) in a diverse range of geological reference materials that includes peridotites, basalts, granites, metamorphic rocks and sediments. More than 90% of determinations are indistinguishable from published reference values at the 95% confidence level. Systematic bias greater than 5% is observed for only a handful of elements (Zr, Nb and U) and may be attributed in part to inaccurate calibration values used for the NIST SRM 612 glass in the case of Zr and Nb. Detection limits for several elements, most notably La, are compromised at ultra-trace levels by impurities in the lithium borate flux but can be corrected for by subtracting appropriate procedural blanks. Reliable Pb analysis has proved problematic due to variable degrees of contamination introduced during sample polishing prior to analysis and from Pt-crucibles previously used to fuse Pb-rich samples. Scope exists for extending the method to include internal standard element/isotope spiking, particularly where integrated XRF analysis is not available to characterise major and trace elements in the fused lithium borate glasses prior to LA-ICP-MS analysis.     

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).     

富水水库中微生物成因的显微针铁矿及其对微量元素的富集

通过对湖北省富水水库坝基渗漏水及其析出物的研究，探讨了现代沉积环境（水库）中显微铁矿物形成的机理及微生物在铁的生物矿化中的作用和意义。对析出物中微量元素的富集特征也进行了初步研究。用化学分析方法测试出坝基渗漏水中阳离子以Ca^2 、Mg^2 、K^ 、Na^ 为主，Fe^2 和Fe^3 含量极少，阴离子以HCO3^-为主。析出物的化学成分以铁的氧化物为主。采用X射线衍射、差热分析、红外光谱和穆斯堡尔谱，以及透射电镜和扫描电镜等测试手段，分析研究了析出物的物相和形貌特征。析出物的主要矿物相为针铁矿、石英、伊利石、蒙脱石和微量方解石，呈弱结晶状态。由析出物中显微针铁矿特殊的形貌特征及其特征的穆斯堡尔谱图推测出富水水库沉积环境中显微针铁矿是由铁细菌形成。ICP－MS测试测试结果表明，析出物中不仅富集了铁，还富集了Yb、Pb、Dy、Zn、Co、Be、Eu、Sm和Tb等微量元素。微量元素的富集是微生物与显微针铁矿共同作用的结果。     

黄河上游河南县地面大气冰核观测分析

用Bigg型混合云室对2001年8月黄河上游青海省河南县的地面大气冰核浓度进行了观测,分析发现(1)青海省河南县冰核浓度低于北京20世纪90年代的测值,但高于大连、西安和兰州(20世纪60年代)等地的测值,同时也高于黄河上游的玛曲(2000年)、西宁(1989年)两地的测值,高温核尤其偏高.(2)降水时大气冰核浓度减少,降水的冲刷可能是其主要原因.(3)当地冰核浓度和气压成正相关.(4)大气冰核浓度受风向的影响,无风时测值较小,偏东风时测值较大,高温核浓度增加明显.     

辽西中生代火山岩岩浆成因——稀土元素配分及同位素定量模式

本文通过对辽西及邻区中生代盆地火山岩稀土元素配分特征的研究及模拟运算，探讨了其岩浆成因及过程。结果显示南北岩区岩浆成因不同，南岩区岩源为MORB地幔和长期富集型幔熔融混合而成，北岩区为MORB和近期亏损型地幔熔融混合而成。