下扬子地区幕府山组陆缘海-台地黑色细粒沉积岩系沉积学和孔隙结构特征

黑色细粒沉积岩系沉积学和孔隙结构研究对于沉积环境恢复、页岩气储层评价和有利储层预测具有重要意义.利用下扬子地区最新完钻的XYZ-1钻井资料,综合钻井岩心、岩石薄片、XRD分析、氩离子-场扫描电镜等手段,开展幕府山组细粒沉积岩系的沉积学和孔隙结构研究.结果表明,幕府山组岩性组成以块状、纹层状深色（碳质）泥岩、浅灰色纹层状泥质灰岩、泥晶灰岩为主,夹泥灰岩、云灰岩、陆屑灰岩和白云岩、安山岩、角砾岩等,以含硅质粘土质混合页岩相和含硅质粘土质页岩相为主,属于下扬子海盆的陆架浅海碳酸盐岩台地-深水海湾-潮坪环境.幕府山组黑色细粒沉积岩孔隙类型多样,有机孔为2~200 nm,面孔率为2.86%~15.90%,孔隙分布较均匀,但总体连通性较差,部分与脆性矿物或粘土矿物共生的有机孔分布不均匀.无机孔以粒内孔、粒间孔、溶蚀孔为主,部分为晶间孔和矿物层间孔.除黄铁矿晶间孔外,大部分无机孔均大于2 μm,最大可达50 μm.细粒沉积岩中的微裂缝广泛发育,构造微裂缝形态复杂,缝宽一般20~500 μm,常常被方解石和石英充填.成岩微裂缝长度一般大10μm,缝宽50~200 nm.幕府山组顶部深水海湾相和底部泥坪-蒸发台地相黑色细粒沉积岩TOC含量为2.66%~21.27%,平均值为6.30%,有机孔、无机孔和微裂缝发育,粘土矿物和脆性矿物含量较高,具备优质页岩气储层发育的有利条件.      

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.     

基于连续消光特征分析的岩石薄片分析系统

连续消光是指在正交偏光显微镜下,岩石薄片随载物台旋转而发生消光强弱连续变化的现象。作为人工鉴定岩石薄片的重要依据,提取后的连续消光特征可以用于实现岩石薄片的自动分析。结合数字图像处理技术与聚类划分算法,开发出一套能够分割出孔隙、颗粒轮廓,实现颗粒类别划分,并对结果做定量分析的岩石薄片分析系统。从矿物的消光特征本质出发,连续消光特征提取精确与否是能否有效划分颗粒类别的关键环节。因此,针对系统在连续消光特征提取过程中的消光位对齐与消光基值去除操作分别设置了对照组。以鄂尔多斯盆地某区长6段砂岩薄片在正交偏光镜下的角度域序列图像进行实验,结果表明,所开发的基于岩石薄片分析系统能够提取到更为精确的连续消光特征,且该系统定量分析结果与专业人员鉴定结果基本一致。     

一次暴雨过程受不同系统影响的动力热力场结构特征

本文使用常规观测资料、卫星云图、自动气象站降水量以及0.25°×0.25°的NCEP/NCAR再分析资料,对出现在东北地区北部受不同系统影响的连续2d暴雨过程的热力和动力场结构特征展开研究。结果表明:24日为暖锋锋生暴雨,暴雨范围大;25日为台风暴雨,暴雨出现在台风移动路径上,为狭长带状。暴雨是由MCS活动造成的,每次短时强降水均与TBB低值中心相对应,台风倒槽内的MCS强度比暖锋云系内的MCS弱,但是降水强度却更大。台风安比携带大量暖湿空气,其东侧的低空急流向北输送热量和水汽,水汽辐合集中在边界层内,台风暴雨的水汽辐合强度比暖锋暴雨更强烈,所造成的雨强更大。暖锋暴雨期间,小兴安岭迎风坡地形的辐合抬升作用明显;高层强辐散及地形辐合抬升作用对暴雨有较大贡献。台风暴雨期间,低空辐合,特别是水汽辐合作用对暴雨有较大贡献;辐合区位于台风倒槽附近,倒槽表现为冷锋性质。     

现代黄河三角洲沉积层压实下沉的计算分析

1855年以来形成的厚度为15 m的现代黄河三角洲分流叶瓣在遭废弃后的最近30 a内的沉积压实幅度为2.28～3.87 m,年平均压实量达0.1 m,其中黏土质粉砂被压实了25.8%,粉砂沉积地层被压实了15.2%,黏土质粉砂的沉积压实量是粉砂沉积压实量的1.7倍,在此期间基本上完成了三角洲压实下沉过程。下伏沉积地层的压缩量有限,不同沉积年代的沉积压实下沉量相差小,如厚度为20～30 m的沉积压实量仅有0.2～0.28 m,其中黏土质粉砂被压实了0.91%,粉砂被压实了1.19%,沉积地层平均被压实了1%。无论是黏土质粉砂还是粉砂,孔隙度与沉积地层深度呈负指数函数关系,黏粒含量愈高,孔隙水则愈难以排出,覆盖在下伏沉积地层上面的表层沉积物对压实下沉贡献愈大。     

Characterizing the hydraulic properties of unsaturated sand considering various porosities and drying‐wetting paths of the retention curve

Previous studies have shown that water retention curve (WRC) and the hydraulic conductivity vary because of changes of the void ratio or porosity of soil. However, limited documents pointed out the change of hydraulic properties of soil when compacted to different porosities while considering both of the drying and wetting processes of the WRC. This information is sometimes necessary for research like finger flow analysis or the occurrence of wetting and drying cycles as what would be seen in the field. Therefore, this study aims to examine the change of WRC characteristics with varied porosity considering both of the drying and wetting path in WRC by conducting a sand box experiment. Results show that the same type of sand compacted to various porosities have different hydraulic parameters. Hydraulic conductivities generally decrease with reduced porosities; shape parameter α of the van Genuchten equation (1980) linearly decreases with declining porosity and shape parameter n in a reversal manner for the sands of interest whether in the drying process or wetting process. The unsaturated properties of sand are further characterized by inspecting the variations of moisture content, matric suction and vertical displacement of soil body subject to periodic changes of the water level by another sand box experiment. The outcomes suggest that the saturated water content and residual water content are changing during the wetting–drying process, which can be an implication of the changed properties of WRC. The characteristics of volumetric deformation might be varied as well because of the observation of the dissimilar patterns of the changing vertical displacements among each wetting–drying process. Infiltration patterns of the sands also are identified through numerical modelling by introducing a constant infiltration flux from the surface followed by a no‐influx condition. Results indicate that less water accumulates in the sand near the surface for the sand compacted to higher porosity, but water can move deeper. Hydraulic conductivity is found as the prime factor dominating the evolvement of wetting fronts. However, shape parameters of water retention curves also affect the infiltration pattern to some extent. In addition, different sands with similar porosities can have quite different infiltrating characteristics. Copyright © 2012 John Wiley & Sons, Ltd.     

Transport properties of rocks from statistics and percolation

Two simplified microstructural models that account for permeability and conductivity of low-porosity rocks are compared. Both models result from statistics and percolation theory. The first model assumes that transport results from the connection of 1D objects or pipes; the second model assumes that transport results from the connection of 2D objects or cracks. In both cases, statistical methods permit calculation of permeability k and conductivity , which are dependent on three independent microvariables: average pipe (crack) length, average pipe radius (crack aperture), and average pipe (crack) spacing. The degree of connection is one aspect of percolation theory. Results show that use of the mathematical concept of percolation and use of the rock physics concept of tortuosity are equivalent. Percolation is used to discuss k and near the threshold where these parameters vanish. Relations between bulk parameters (permeability, conductivity, porosity) are calculated and discussed in terms of microvariables.     

块状硫化物矿床的地球化学找矿标志

近年来国外发现了许多大型块状硫化物矿床，而我国进展还不大。原因之一是我们对这类矿床的地质特征，成矿条件尤其是找矿标志研究还不够。这是一类成矿物质通过热液作用在海底沉积而成的特殊矿床，故在找矿勘探讨既要研究沉积矿时形成的原生晕，又要研究热液经过围岩时蚀变而产生的次生晕?Ｍｎ晕，Ｔｌ，Ｈｇ，Ｂａ，Ａｓ和Ｚｎ等元素的异常，络合剂元素的富集，微量元素的分布，铅同位素，岩石化学异指数尤其是块状硫化物Ｃｕ矿中     

双密度重叠找气新方法

本文根据岩石孔隙中的天然气引起介电测井孔隙度减小和密度测井孔隙度增大的原理,建立了双密度重叠找气新方法,消除了岩性的影响,提高了测井找气的分辨率,增加了评价气层的直观性。该方法用于寻找陕甘宁盆地低孔隙白云岩气藏,获得了明显的地质效果。这种方法还可以在其它储层岩性气藏中应用。     

四川绵阳官司河流域防护林的演替预测

选取６个样地，以“空间代替时间”法研究了官司河流域的松柏栎混交防护林的优势种群动态。结果显示：各种群在群落次生演替过程中普遍更新欠佳，林木大小级结构呈不稳定或衰退状态，据非线性演替理论，并结合防护林现状，预测防护林的可能演替趋势为：今后人为干扰若能保持较长期相对稳定，则针阔叶混交的群落类型亦将保持基本稳定；但随土壤类型的不同，而渐分化成松栋混交林和柏栎混交林．