大别山北部蛇绿岩的地球化学制约

常量元素,微量元素,稀土元素,Ｎｄ同位素及氧同位素地球化学特征表明,太别山北部变质镁铁－超镁铁质岩带中存在变质的蛇绿岩,它主要由变质橄榄岩,辉长岩（－辉绿岩？）和基性熔岩三部分组成,其中,变质的基性熔岩的亏损地幔模式年龄ｔＤＭ／Ｍａ＝１０３６．８～１２９３．８,εＮｄ（ｔ）＝７．２～７．７,表明它可能代表１０００Ｍａ左右形成于中等扩张速率（２ｃｍ／ａｄ左右）洋盆条件下的洋壳残片。     

PTtD Path and Fluid Evolution of HighPressure Eclogites from the Dabie Mountains,Central East China

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Cr-rich magnesiochloritoid eclogites from the Monviso ophiolites (Western Alps, Italy)

Cr-rich magnesiochloritoid in the eclogitized ophiolites of the Monviso massif occurs in the least differentiated rocks of the gabbroic sequence (troctolites to melatroctolites). Chloritoid ( X _Mg=0.63–0.85; Cr≤0.55, atoms) co-exists with omphacite, talc and garnet. Minor, syn-eclogitic minerals are chromite, rutile and sometimes magnesite and Cr–Ti oxides.
Coronitic textures, indicative of a static recrystallization, characterize the analysed samples. Layers of variable mineral composition develop among igneous plagioclase, olivine, clinopyroxene and spinel. The minerals in the coronitic layers display sharp compositional zonings. The igneous minerals are commonly not preserved; their presence in the original assemblage is inferred from the mineralogical composition of the pseudomorphs.
Syn-eclogitic volatile components are indicated by the development of OH-bearing minerals (e.g. chloritoid & talc) and carbonates (e.g. magnesite), and supported by the presence of coarse-grained and fibrous mineral growths. The complex pseudomorphic replacements of igneous minerals suggest that these rocks changed their mineralogical composition prior to the eclogite facies recrystallization, most likely during ocean-floor metamorphism. It is suggested that syn-eclogitic fluids formed by breakdown reactions of pre-eclogitic volatile-bearing minerals.
Geothermobarometry indicates that the investigated rocks recrystallized at a depth corresponding to 2.4  GPa and temperatures of 620±50  °C. The attainment of high-pressure conditions is supported by the presence of magnesiochloritoid, magnesite and garnet with high pyrope content (up to 58  mol%). P–T  estimates point to a very low thermal gradient (about 9  °C km⁻¹), comparable to that deduced in the adjacent Dora-Maira ultra-high pressure unit.     

东昆仑夏日哈木退变质榴辉岩地球化学、年代学特征及其地质意义

本文对东昆仑夏日哈木退变质榴辉岩开展岩石地球化学和年代学研究,探讨其原岩性质和构造背景。岩石SiO₂含量为46.77%~49.31%,Al₂O₃含量为13.6%~14.6%,TiO₂含量为0.93%~2.29%,全碱（K₂O+Na₂O）含量为1.61%~2.66%,原岩属亚碱性玄武岩系列中的拉斑玄武岩。（La/Yb）_N=0.98~1.63,（La/Sm）_N=0.98~1.41,δEu=1.10~1.28,稀土元素球粒陨石标准化图呈弱Eu正异常的右倾型,岩石相对富集大离子亲石元素Rb、Ba和不相容元素U,相对亏损高场强元素Zr、Hf,Hf/Th=0.59~0.97,Th/Yb=0.13~0.27,显示其原岩具E-MORB特征。退变质榴辉岩的锆石Th/U比值为0.002~0.091,为变质成因锆石,其锆石SIMS U-Pb年龄为414.2 ±7.3 Ma,代表了退变质榴辉岩的峰变质年龄,结合区域地质背景,认为该岩石形成于早泥盆世早期由碰撞作用向碰撞后伸展作用转换的构造环境。     

Water in garnet of garnetite (metarodingite) and eclogite from the Erzgebirge and the Lepontine Alps

Little is known about water in nominally anhydrous minerals of orogenic garnet peridotite and enclosed metabasic rocks. This study is focused on peridotite-hosted eclogite and garnetite (metarodingite) from the Erzgebirge (EG), Germany, and the Lepontine Alps (LA), Switzerland. Newly discovered, peridotite-hosted eclogite in the Erzgebirge occurs in the same ultra-high pressure (UHP) unit as gneiss-hosted coesite eclogite, from which it is petrologically indistinguishable. Garnet is present in all mafic and ultramafic high pressure (HP) rocks providing for an ideal proxy to compare the H₂O content of the different rock types. Garnet composition is very similar in EG and LA samples and depends on the rock type. Garnet from garnetite, compared to eclogite, contains more CaO (garnetite: 10.5–16.5 wt%; eclogite: 5–11 wt%) and is also characterized by an anomalous REE distribution. In contrast, the infrared (IR) spectra of garnet from both rock types reveal the same OH absorption bands that are also identical to those of previously studied peridotitic garnet from the same locations. Two groups of IR bands, SW I (3,650 ± 10 cm⁻¹) and SW II (3,570–3,630 cm⁻¹) are ascribed to structural hydroxyl (colloquially ‘water’). A third, broad band is present in about half of the analysed garnet domains and related to molecular water (MW) in submicroscopic fluid inclusions. The primary content of structural H₂O, preserved in garnet domains without fluid inclusions (and MW bands), varies systematically—depending on both the location and the rock type. Garnet from EG rocks contains more water compared to LA samples, and garnet from garnetite (EG: 121–241 wt.ppm H₂O; LA: 23–46 wt.ppm) hosts more water than eclogitic garnet (EG: 84 wt.ppm; LA: 4–11 wt.ppm). Higher contents of structural water (SW) are observed in domains with molecular water, in which the SW II band (being not restricted to HP conditions) is simultaneously enhanced. This implies that fluid influx during decompression not only led to fluid inclusions but also favoured the uptake of secondary SW. The results signify that garnet from all EG and LA samples was originally H₂O-undersaturated. Combining the data from eclogite, garnetite and previously studied peridotite, H₂O and CaO are positively correlated, pointing to the same degree of H₂O-undersaturation at peak metamorphism in all rock types. This ubiquitous water-deficiency cannot be reconciled with the derivation of any of these rocks from the lowermost part of the mantle wedge that was in contact with the subducting plate. This agrees with the previously inferred abyssal origin for part of the rocks from the LA (Cima di Gagnone). A similar origin has to be invoked for the Erzgebirge UHP unit. We suggest that all mafic and ultramafic rocks of this unit not only shared the same metamorphic evolution but also a common protolith origin, most probably on the ocean floor. This inference is supported by the presence of peridotite-hosted garnetite, representing metamorphosed rodingite.     

A new occurrence of retrogressed eclogite from the Sanbagawa belt of southwest Japan and its significance

The present paper reports, for the first time, the occurrence of an omphacite‐bearing mafic schist from the Asemi‐gawa region of the Sanbagawa belt (southwest Japan). The mafic schist occurs as thin layers within pelitic schist of the albite–biotite zone. Omphacite in the mafic schist only occurs as inclusions in garnet, and albite is the major Na phase in the matrix, suggesting that the mafic schist represents highly retrogressed eclogite. Garnet grains in the sample show prograde‐type compositional zoning with no textural or compositional break, and contain mineral inclusions of omphacite, quartz, glaucophane, barroisite/hornblende, epidote and titanite. In addition to the petrographic observations, Raman spectroscopy and focused ion beam system–transmission electron microscope analyses were used for identification of omphacite in the sample. The omphacite in the sample shows a strong Raman peak at 678 cm^?1, and concomitant Raman peaks are all consistent with those of the reference omphacite Raman spectrum. The selected area electron diffraction pattern of the omphacite is compatible with the common P2/n omphacite structure. Quartz inclusions in the mafic schist preserve high residual pressure values of Δω₁ > 8.5 cm^?1, corresponding to the eclogite facies conditions. The combination of Raman geothermobarometries and garnet–clinopyroxene geothermometry gives peak pressure–temperature (P–T) conditions of 1.7–2.0 GPa and 440–540 °C for the mafic schist. The peak P–T values are comparable to those of the schistose eclogitic rocks in other Sanbagawa eclogite units of Shikoku. These findings along with previous age constraints suggest that most of the Sanbagawa schistose eclogites and associated metasedimentary rocks share similar simple P–T histories along the Late Cretaceous subduction zone.     

Ultramafic Blocks in Sumdo Region, Lhasa Block, Eastern Tibet Plateau: An Ophiolite Unit

Recently, an over 100 kin long MORB-type eclogite belt of Permian was discovered in the Sumdo (松多) region of the Lhasa block, Tibet. A critical question thus is: what is the tectonic setting of the eclogite belt and is it related to an unrecognized suture in the region? Further investigations show that there are some mafic and ultramafic rocks spatially associated with the eclogite belt in the region. Three ultramafic massifs were recognized in the Sumdo region, and called the Luomaling (罗马岭),Gongbupala (贡布爬拉) and Qiazhasumdo (卡扎松多) massifs. All the massifs are fault-contacted with greenschist (Chasagang (岔萨岗) Formation) or muscovite-quartz schist (Mabuku (马布库) Formation), and individuals are about 100 m×50 m in size extending in EW as the regional structure. All the ultramafic rocks have been entirely serpentinized, and the Gongbupala massif has been selected for study in geochemistry. Eleven chemical analyses of the rocks from the Gongbupala massif show a narrow range in contents: SiO2(35.97-40.63) wt.%, MgO (37.02-38.60) wt.%, TiO2(0.01-0.08) wt.%, Al2O3 (0.80-1.64) wt.%, (Na2O+K2O) less than 0.1 wt.%, with high volatile contents (H2O+CO2) (11.24-14.91) wt.%. After recalculation without H2O+CO2, the mean values are SiO2 45.24 wt.%, MgO 43.54 wt.%, FeOT(7.45-9.97) wt.% (8.55 wt.% in average), (MgO+FeOT) 52.09 wt.%, Mg# (100×Mg/(Mg+Fe*), where Fe* represents total Fe)=89.42-90.08, (m+f)/Si ((atomicity Mg+atomicity Fe) /atomicity Si)=1.53-1.75 (1.59 in average), respectively. The mean M/F (atomicity Mg/atomicity Fe) ratio of the rocks is 9.05, which is classified as magnesium enriched-type of ultramafic rocks. The compositional features, depleted in K, Na, Ca, Al and Ti and enriched in Mg#, indicate the characteristics of peridotite originated from a depleted mantle. The rocks have low ∑ REE with (1.60-2.68)×10-6 similar to those of the primitive mantle. The chondrite-normalized REE patterns of all samples show slightly enrichment in LREE, with (Ce/Yb)N 1.03-2.46, but a little depleted in HREE. Most samples show a slight negative anomaly in Eu, a feature In REE from a relic mantle and common features In highly serpentinized ultramafic rocks in the Yarlung-Zangbo (雅鲁藏布) ophiolite and the Bangong (班公)-Nnjiang (怒江)ophiolite in Tibet. The primitive mantle-normalized spiderdiagram of trace elements for Gongbupala ultramafic rocks yields uniform distributed pattern. They are relatively enriched in Rb, Ba, La, P element (LHSE) and depleted in Sin, Ti, Y, Yb element (HFSE), a feature of metasomatic mantle peridotite. The geochemical features of the rocks suggest that the protofith of Gongbupala serpentinite in Sumdo region is harzburgite, a typical depleted mantle rock, and may represent a dismembered ophiolite unit in the region.     

Records of Indosinian Orogenesis in Lhasa Terrane, Tibet

Based on the deformation characteristics of the ductile shear zones in Sumdo (松多) Group, the quartz fabric by EBSD (electron backscatter diffraction), the data of muscovite 40Ar-39Ar geochronology (220-230 Ma) from ductile shear zones and the zircon SHRIMP U-Pb chronology (190 Ma) of granites in Snmdo region, Lhasa (拉萨) terrane is thought to have experienced an important Indosinian orogenic event at 220-230 Ma, which caused the closure of the paleo-Tethys Ocean along the tectonic zone of eclogite and the collision between northern part and southern part of the Lhasa terrane. The zircon SHRIMP U-Pb chronology of 190 Ma for biotite adamellite, with the distributing characteristics of the granite massif intruding in Sumdo Group, indicates that the biotite adamellitc should be the late orogenic or post-orogenic granite resulting from the lndosinian orogenesis. The discovery of Indosinian orogenic belt in Lhasa terrane expansed the southern boundary of lndosinian orogenic belt in Qinghai (青海)-Tibet plateau to Lhasa terrane from Qiangtang (羌塘) terrane, which changed the understanding about the distribution of Indosinian orogenic belt in Qinghai-Tibet plateau and extended the "T" type lndosinian orogenic belt in China. The study is very important for the formation and distribution of paleo-Tethys Ocean in Tibet. The ancient terrane framework and evolution of Qinghai-Tibet plateau need further research.     

西藏松多榴辉岩变质作用研究

西藏拉萨地块松多附近新发现一条榴辉岩带,长约100 km,宽约2~3 km。松多榴辉岩主要经历了进变质的绿帘石榴辉岩相-峰期的榴辉岩相-退变质的角闪岩相3个阶段。岩石学研究表明,峰期的特征矿物组合是石榴子石绿辉石多硅白云母金红石,峰期温压条件是760~800 ℃,33~39 GPa。这表明松多地区可能曾经历超高压变质作用,之后快速返回,p T轨迹呈“发卡”状,后期退变质经历了角闪石榴辉岩相阶段。研究松多榴辉岩表明,拉萨地块内部有一条新的缝合带,这对于了解拉萨地块和古特提斯洋的演化有重要意义。     

滇西双江县勐库地区退变质榴辉岩中闪石类矿物的成因研究

勐库地区新近发现的退变质榴辉岩中晚期退变质作用形成的闪石类矿物十分丰富,其携带了大量晚期退变质过程中的岩石成因信息。本文通过系统的矿物学研究,鉴定出了3期10种闪石类矿物,其中以镁钙闪石、镁角闪石、铁镁钙闪石、铁韭闪石、透闪石、阳起石等钙质闪石类为主,有少量冻蓝闪石、蓝透闪石等钠-钙闪石类。研究发现,随着退变质过程中时间的推移,角闪石的形成环境逐渐由还原环境向弱氧化环境、氧化环境演变。根据角闪石电子探针成分测试结果计算了相应的温度、压力条件。结合岩相学的资料,将退变质过程分为3期:(1)第1期早阶段为近等温降压过程(p=0.56~0.75 GPa,t=642~709℃),主要形成铁韭闪石、铁镁钙闪石、镁钙闪石;晚阶段为等温降压过程(p=0.39~0.56 GPa,t=619~642℃),主要形成镁钙闪石及少量镁绿钙闪石、铁韭闪石;(2)第2期为降温降压过程(p=0.23~0.42 GPa,t=460~610℃),主要形成镁角闪石、冻蓝闪石及铁角闪石;(3)第3期为近等温降压过程(p=0.09~0.31 GPa,t=350~420℃),主要形成透闪石、阳起石、蓝透闪石等。闪石类的成分变化反映了退变质榴辉岩从地壳底部的角闪石榴辉岩-高压麻粒岩相温压环境向中上地壳角闪岩相、绿片岩相温压环境的渐次退变质作用过程。这与昌宁-孟连构造带上印支期的碰撞造山作用、燕山期的区域性地壳伸展、喜马拉雅期的陆内造山运动具有较好的对应关系。