南海西部表层沉积物黏土矿物的分布

对南海西部表层沉积物进行系统取样分析表明,该区黏土矿物总体以伊利石为主,平均含量超过50%,其次为蒙脱石、绿泥石和高岭石含量较低,伊利石和蒙脱石含量变化较大,两者呈负相关关系,而绿泥石和高岭石含量变化较小,两者呈正相关关系。根据黏土矿物组合及其分布特征,南海西部海域大致可以分为A、B、C、D四区,其中A区以高伊利石和低蒙脱石含量为特征,B区伊利石含量明显下降,蒙脱石含量增多,C区以较高蒙脱石含量和低绿泥石、高岭石含量为特征,D区为相对低伊利石,高蒙脱石、绿泥石和高岭石,且往东南方向蒙脱石含量增大,而伊利石含量下降。与邻区黏土矿物组合对比研究表明,高伊利石含量的A区物源,除来自华南大陆的珠江、韩江等大小河流外,可能有相当部分来自东北方向,包括台湾岛及台湾海峡等。越南岸外的陆坡区细粒沉积物与陆架区有明显的继承性,表明其物源主要来自中南半岛,而红河物源对陆坡及深海盆的影响相对较小。南部陆架-陆坡区的物源主要有湄公河和加里曼丹岛,但两者的混合明显。因此,从区域分布来看,来自台湾海峡的细粒沉积物对南海深海盆影响最大,这可能主要是有由于表层环流所致。     

浅水三角洲物源、砂体构型与储层特征研究——以准噶尔盆地永进—莫西庄地区侏罗系三工河组二段为例

针对准噶尔盆地腹部侏罗系三工河组物源、砂体构型及储层物性认识存在争议的问题,笔者等基于岩芯、录井、钻井等方面的资料,结合前人在准噶尔盆地周缘磷灰石及锆石年龄数据,运用沉积学、层序地层学、沉积盆地分析及储层沉积学的基本原理和方法对三工河组二段物源方向、远近和类型、沉积体系展布、砂体构型及储层物性之间的关系进行了系统的研究。研究表明,在敞流盆地快速抬升/缓慢沉降的构造背景下形成辫状河三角洲退积式沉积序列,在五级层序地层格架中,河道强冲刷叠置砂体见于第1、2砂组,三角洲退积,分支河道强烈冲刷,导致河道砂体叠置,微相类型单一,单砂体厚度向上变薄,砂体全区稳定分布,储集性较好。河道弱冲刷叠置砂体见于第3、5砂组,三角洲退积,分支河道冲刷不明显,形成河道“二元结构”,单砂体厚度向上变薄,粒度变细,储集性好;河口坝组合砂体见于第4砂组,在三角洲退积过程中,水下分流河道末端形成河口坝,总体岩性向上变细,砂体不连续,储集性好,远砂坝席状砂组合砂体见于第6、7砂组,砂体零星分布,储集性很差。在浅水、低可容纳空间、快速抬升/缓慢幕式沉降构造背景之下,浅水三角洲的物源的方向、远近及类型是影响沉积微相展布的关键因素,也是影响砂体构型及其储层物性的物质基础。     

Historical variations in autochthonous and allochthonous sediment supplies to the largest freshwater lake in Central India

Lacustrine sediment preserves high-resolution biogeochemical records of past variations in watershed processes controlling lake sedimentation. The current study explores historical variations in autochthonous and allochthonous sediment supplies to a large tropical freshwater lake system (Upper Lake, Bhopal) protected under the international Ramsar Convention of 2002 against anthropogenic pressures. For this purpose, multi-proxy biogeochemical data are presented for organic matter (total organic carbon, total nitrogen, phosphorous, and loss on ignition [LOI] at 550 °C), carbonate (LOI at 950 °C), lithic sediment (aluminum, titanium, iron, calcium, magnesium, sodium, potassium, manganese, zirconium, niobium, hafnium, tantalum, thorium, uranium, and rare earth elements), and anthropogenic inputs (lead) measured in a 38 cm long sediment core retrieved from the lake. In addition to the lacustrine sediment core, the samples of catchment bedrock, surface soils, major stream sediment, and eolian dust collected from the lake periphery also are analyzed. The systematic biogeochemical excursions in the upper core section (top ～8 cm) indicate increased anthropogenic inputs, watershed denudation by agricultural activities, artificially reduced fluvial sediment supply, relatively increased dust inputs and lake eutrophication in the last few decades. The current study underscores the roles of anthropogenic land-use and wetland conservation practices in the rapid alteration of autochthonous and allochthonous sediment supplies to open aquatic ecosystems. Further, rising lake eutrophication levels despite a managed reduction in allochthonous sediment supplies seem challenging to control due to dissolved nutrient supply from urban sewage discharge and runoff from agricultural land in the watershed.     

裂变径迹热年代学在珠江口盆地渐新统珠海组物源分析中的应用*

渐新统珠海组是南海北部珠江口盆地的主要储集层发育层位之一,但其物源区位置、沉积物搬运路径等关键问题仍存在争议。为此,选取珠江口盆地不同构造单元3口关键井珠海组上段砂岩样品开展锆石裂变径迹(ZFT)、磷灰石裂变径迹(AFT)热年代学研究,进而开展珠海组物源分析。盆地西部西江凹陷XJ28井与白云凹陷LW3井ZFT、AFT年龄组分相似,包含晚三叠世的ZFT年龄组分,且ZFT、AFT主要年龄组分分别为白垩纪、古新世;盆地东部陆丰凹陷的LF7井ZFT、AFT年龄组分明显比前2口井偏年轻,ZFT主要年龄组分为古新世。3口井的ZFT、AFT年龄组成表明其珠海组上段物源均主要来自珠江口盆地北侧的华南地块,但盆地西部与东部显示出明显的物源差异。盆地西部XJ28井以及LW3井物源特征总体一致,均由古珠江水系供源,其物源以珠江流域中生代花岗岩为主,还包括华南地块腹地的中生代沉积岩。盆地东部LF7井的物源主要为陆丰凹陷北侧的沿海中生代花岗岩,物源组成相对简单,沉积物搬运距离相对较短。     

兰州第四纪黄土/古土壤序列物源演变: 来自于碳酸盐矿物的证据*

黄土/古土壤的物源研究对于揭示第四纪气候变化和青藏高原隆升历史具有重要意义。本研究以位于黄土高原西部1.4 Ma以来的兰州黄土/古土壤沉积序列为研究对象,基于X射线衍射技术分析了黄土/古土壤中的主要矿物组成,侧重于碳酸盐矿物含量,追溯了兰州黄土/古土壤的直接物源。结果显示: (1)1.4 Ma以来兰州地区黄土/古土壤沉积物的主要直接源区为柴达木盆地沙漠区和阿拉善干旱区。(2)基于二元混合模型计算的潜在原始源区对兰州黄土白云石和总碳酸盐矿物的相对贡献率以及长石与石英比值结果一致支持1.4 Ma以来兰州黄土原始物源发生了多次变化。1.4~1.1 Ma和0.9~0.3 Ma青藏高原东北缘造山带(昆仑山、祁连山)和中亚造山带对兰州黄土的贡献相当,而1.1~0.9 Ma和0.3 Ma以来,中亚造山带对兰州黄土的物源贡献增加,这可能分别是对中更新世气候转型和0.3 Ma以来青藏高原及邻近地区干冷气候增强的响应。1.15 Ma和0.8 Ma兰州黄土/古土壤中高的白云石含量、碳酸盐矿物总含量以及0.8 Ma长石与石英比值的快速升高可能是对“昆黄运动”的响应,进而造成了昆仑山、祁连山对黄土高原物源贡献的增加。     

东北印度洋源汇过程及古环境与古季风演化

东北印度洋地理位置独特,其沉积物记录了青藏高原隆升及孟加拉扇的“源-汇”过程、印度季风与东亚季风的“海-气”交互作用、印-太暖池热传输的演变与高纬气候之间的相位关系等关键信息,是喜马拉雅地区“构造-气候-沉积”耦合演化的良好记录载体,是探讨多圈层相互作用、探索古气候与古环境演化的理想“窗口”。本文系统总结了近年来有关东北印度洋季风与表层环流特征、沉积物组成及物源、气候环境演化以及环境磁学记录等方面的研究进展。分析表明,东北印度洋为典型的季风风场,表层环流受季风影响强烈,夏季和冬季环流差异明显。沉积物类型丰富,包括河流输运而来的陆源碎屑、钙质和硅质为主的生物沉积以及火山物质等。但目前对于该区域的沉积物的具体组成、“源-汇”过程、迁移历史、季风演化与青藏高原隆升、高纬气候变化之间相互关系等方面的认识尚存在较大的分歧。同时,受样品获取难度大、磁学信号稀释严重等因素的限制,环境磁学作为一种在示踪沉积物物质来源、恢复古气候和古环境等方面被普遍认可的技术手段,在东北印度洋区并没有得到充分的发挥与应用。因此,未来需要在前人研究的基础上,将目光向东北印度洋更南、更深处延伸,对其“源-汇”过程进行全面分析。在研究方法上进一步拓展,采用更高精度的技术手段提取磁学信号,加大环境磁学的应用,寻找有效的替代性指标,解决该地区季风演化、古海洋环境变化等气候环境问题,为该地区环境气候研究提供新认识。并尝试开展地磁场长期变化(paleosecular variation, PSV)研究,建立东北印度洋的PSV记录,辅助修正全球地磁场模型,探究地球深部动力过程。     

Luminescence and ESR dating of the sedimentary infill from the multi-level cave system of Alkerdi-Zelaieta (Navarre,N Spain)

The finding of Upper Paleolithic engravings in 2016 triggered a multidisciplinary investigation of the Alkerdi cave system (Urdazubi, N Spain). The study of the speleogenetic processes led to the identification of at least 6 paragenetic cave levels with associated sedimentary infill. In order to unravel the timing of changes in the karst dynamics and to get some insights about sediment origin, two sediment samples were collected from cave levels 4 and 1 for numerical dating purpose, using both Optically Stimulated Luminescence (OSL) and Electron Spin Resonance (ESR) methods. One additional modern-age sample was also taken from the entrance of the karst to evaluate the magnitude of the optical bleaching achieved by the quartz grains before entering the cave system. Last, one sample was collected from a flowstone for U-series dating, providing independent age control.OSL measurements were carried out using small quartz multi-grain (MG) and single-grain (SG) Single Aliquot Regenerative-dose (SAR) protocol. Initial Equivalent Dose (D_e) results show evidence of saturated OSL signal for the sample of the higher level (with ∼60% of saturated aliquots). Unlike SA data, SG analyses do not meet the usual quality criteria (e.g., relatively high recuperation ratios, only a few grains with useable signal), suggesting that corresponding dating results should be treated with caution.Hence, both MG and SG TT-OSL and MG ESR methods were subsequently employed, as the corresponding signals are known to have higher saturation levels than OSL ones. ESR analyses were based on the Multiple Centre (MC) approach using the standard multi-grain multi-aliquot additive (MAA) dose method, while TT-OSL measurements were performed following Demuro et al. (2020). The latter, however, did not return any useful results for both samples. MC ESR data show the usual D_e pattern (D_e(Al)>D_e(Ti op. D)>D_e(Ti–H)) indicating that among the three ESR signals analyzed, the Ti–H most likely provides the closest estimate to the true burial age. However, low measurement repeatability and goodness-of-of fit indicate that the reliability of the ESR results may be reasonably questioned.Results derived from this multi-technique dating approach provide the first chronological constraints for the sedimentary infill of the Alkerdi cave system. In particular, they suggest that sediment deposition in Cave Level 4 (ALK-OSL01) occurred around 130 ka, which is in good agreement with the minimum age constraint given by the speleothem (80.5 ± 9.0 ka). In comparison, the young age obtained for sample ALK-OSL02 (5.0 ± 0.9 ka) suggests recent Holocene formation of the lowest cave level 1.Finally, the MG De value obtained for the modern sample is close to zero (<1 Gy), indicating that the OSL signal is almost fully reset at a multi-grain level before entering the cave. Additionally, despite the large De overdispersion measured in this modern sample, the De values are one to two order of magnitude lower than those obtained with the same model in the other two samples. Therefore, the large OSL D_e overdispersion (OD) values of up to 64% obtained for the two samples from Cave Level 4 and 1 are most likely related to re-sedimentation processes inside the cave system.     

内蒙古额尔古纳红水泉地区奥陶系乌宾敖包组沉积时代及物源区分析:碎屑锆石U-Pb年代学,Lu-Hf同位素地球化学证据

选取内蒙古额尔古纳红水泉地区奥陶系乌宾敖包组石英砂岩进行碎屑锆石U-Pb年龄、原位Lu-Hf同位素研究,尝试限定该地层形成时代及碎屑物质来源,并探讨其沉积大地构造环境。结果显示,采自该地层的2个砂岩样品中的碎屑锆石多数发育典型的岩浆振荡生长环带,呈自形–半自形且具有较高的Th/U值(0.12~1.63),均暗示它们多数为岩浆成因。结合微量元素特征及稀土元素配分模式图,认为碎屑锆石寄主岩石应为花岗质杂岩体。2个砂岩样品具有相似的年龄和Hf同位素组成,锆石年龄分布大致可分为3个主要年龄区间:(1)440~540 Ma,主峰值年龄约为492 Ma和506 Ma,次峰值年龄为447 Ma;ε_Hf(t)值介于?2.77~+11.73之间,Hf的两阶段模式年龄为680~1636 Ma;(2)750~950 Ma,主峰值年龄为805 Ma,次峰值年龄为825 Ma和961 Ma;ε_Hf(t)值介于?1.14~+11.43之间,Hf的两阶段模式年龄为1100~1824 Ma;(3)1700~2000 Ma,峰值年龄为1787 Ma;ε_Hf(t)值介于?9.18~?2.75之间,Hf的两阶段模式年龄为2682~3016 Ma。所有样品碎屑锆石ε_Hf(t)值为?9.18~+11.73,Hf的两阶段模式年龄为680~3016 Ma,大部分锆石的Hf同位素组成集中于球粒陨石与亏损地幔标准线之间,表明沉积物源以早古生代和新元古代新增生地壳物质为主,同时存在少量中元古代晚期古老地壳物质的活化改造。结合前人已报道的邻区相关岩体年代学及地球化学资料,研究区乌宾敖包组的沉积时代不早于晚奥陶世,沉积物主要来自额尔古纳和兴安地块的近缘碎屑物,其形成与早古生代时期古亚洲洋演化过程中额尔古纳与兴安地块碰撞拼贴以及随后的伸展垮塌相关。     

赣南西华山成矿花岗岩锆石U-Pb年代学和Hf同位素特征及其地质意义北大核心CSCD

赣南西华山钨矿是与侏罗纪花岗岩有关的大型石英脉型矿床,也是我国南岭成矿带赣南地区典型的钨矿床。本文选取西华山钨矿成矿花岗岩进行了锆石LA-ICP-MS U-Pb定年、微量元素和Hf同位素分析,旨在揭示花岗岩的形成时间并推断岩石成因及其对成矿的指示。锆石U-Pb测年结果表明,西华山中粒黑云母花岗岩锆石206 Pb/238 U加权平均年龄为154.8±6.0 Ma。锆石形态、激光拉曼和地球化学特征表明,该花岗岩受到岩浆热液的影响。锆石的176 Yb/177 Hf和176 Lu/177 Hf比值较高,表明源岩浆有强烈的流体出溶作用。西华山黑云母花岗岩的εHf(t)变化范围较小,呈明显负值(-12.8~-10.8),且集中在华夏地块古老基底范畴内,指示其形成于古老地壳物质的部分熔融。     

珠江口盆地惠州凹陷古近纪多幕裂陷旋回的沉积物源响应

为阐明惠州凹陷古近纪构造活动对物源供给与沉积充填的控制作用,以LA-ICPMS锆石U-Pb定年为主要技术手段,对惠州凹陷古近系不同层段的8件样品中的锆石形态及年代组成进行分析,定量研究其物源供给规律.南部物源,即盆内基岩凸起与东沙隆起,以中生代火成岩为主;北部物源,即盆外华南褶皱带,岩性及年代学复杂.结果显示从下文昌组-上文昌组-恩平组的砂岩样品中,中生代锆石颗粒含量逐渐降低,前寒武-古生代锆石颗粒含量逐渐增加,表明惠州凹陷具有早期南部供源逐渐到晚期北部供源的转换规律.惠州凹陷构造演化分为3幕:裂陷Ⅰ_A、Ⅰ_B和Ⅱ幕.裂陷Ⅰ_A幕,下文昌组沉积时期,凹陷南部断层活动强烈,砂岩中锆石以中生代颗粒为主,沉积相类型以靠近南部断裂带发育的扇三角洲及中深湖相为主;裂陷Ⅰ_B幕,上文昌组沉积时期,北部边界断裂带活动强度增加,中生代锆石颗粒含量为68%,前寒武-古生代颗粒含量为32%,表明该时期南北同时供源,沉积体系以扇三角洲、辫状河三角洲及中深湖相为特色;裂陷Ⅱ幕,恩平组沉积时期,北部断层持续活动,前寒武-古生代锆石颗粒含量为64%,中生代颗粒含量为36%,证实恩平组沉积时期以北部物源为主,发育了浅水辫状河三角洲、滩坝以及薄煤层.