酸溶——催化极谱法测定地质样品中的钨、钼

本文采用混合酸溶解样品,对影响催化体系稳定的酸度、温度和不同反应时间的因素分别进行了对比试验,确定催化体系相对稳定的最佳条件,经过大量样品的分析验证,分析方法可靠。     

矿井涌水量混沌时间序列分析与预测

矿井地下水系统是个非线性系统,由于地下水系统的复杂性,很难完全确定影响矿井涌水量的因素,因此传统的矿井涌水预测表现出较大的局限性。而混沌时间序列分析能够利用单变量处理方法,分析矿井地下水系统中,由于多因素耦合作用所产生的矿井涌水量时间序列。通过对某矿区1985年9月至2005年2月矿井涌水量时间序列资料的分析,显示矿井涌水量时间序列具有混沌特征;通过对比预测值和实测值,表明预测精度高。因此,混沌时间序列分析方法用于矿井涌水量预测是可行的。     

GNSS three carrier ambiguity resolution using ionosphere-reduced virtual signals

This paper presents a general modeling strategy for ambiguity resolution (AR) and position estimation (PE) using three or more phase-based ranging signals from a global navigation satellite system (GNSS). The proposed strategy will identify three best “virtual” signals to allow for more reliable AR under certain observational conditions characterized by ionospheric and tropospheric delay variability, level of phase noise and orbit accuracy. The selected virtual signals suffer from minimal or relatively low ionospheric effects, and thus are known as ionosphere-reduced virtual signals. As a result, the ionospheric parameters in the geometry-based observational models can be eliminated for long baselines, typically those of length tens to hundreds of kilometres. The proposed modeling comprises three major steps. Step 1 is the geometry-free determination of the extra-widelane (EWL) formed between the two closest L-band carrier measurements, directly from the two corresponding code measurements. Step 2 forms the second EWL signal and resolves the integer ambiguity with a geometry-based estimator alone or together with the first EWL. This is followed by a procedure to correct for the first-order ionospheric delay using the two ambiguity-fixed widelane (WL) signals derived from the integer-fixed EWL signals. Step 3 finds an independent narrow-lane (NL) signal, which is used together with a refined WL to resolve NL ambiguity with geometry-based integer estimation and search algorithms. As a result, the above two AR processes performed with WL/NL and EWL/WL signals respectively, either in sequence or in parallel, can support real time kinematic (RTK) positioning over baselines of tens to hundreds of kilometres, thus enabling centimetre-to-decimentre positioning at the local, regional and even global scales in the future.     

描述岩石粘弹性固体性质的开尔文模型

大多数固体材料都具有弹性,但真实的固体却极少严格遵从弹性的虎克定律。这些固体材料的变形往往有对时间的依赖性,这种性质是流变学研究的内容。岩石是自然界最普遍的固体,它的力学性质在通常条件下可用虎克定律作精确的描述,而在漫长的地质过程中,岩石的流变特征就逐渐显现出来。地质作用越缓慢,岩石对变形时间的依赖性越明显。为精确描述岩石在地质过程的力学性质,流变学方法被引入地质学。笔者已经介绍过描述"牛顿流体"的马克斯威尔流变模型,文中介绍描述粘弹性固体的开尔文流变模型。和马克斯威尔模型一样,开尔文模型也是流变学的基本模型,它是由一个弹性元件和一个阻尼元件并联而成。文中给出开尔文模型的本构关系和地质应用的简介。     

土地更新调查成果与二次调查数据衔接问题的探讨

结合广西第二次土地调查工作实际,论述了在调查工作中对原土地更新调查成果的利用,对需补充、完善的调查内容逐一进行了分析和阐述,并对如何处理两次调查数据衔接中存在的问题提出了一些建议和看法。     

动态最小二乘支持向量机学习算法

针对大样本集的训练问题和动态训练样本的模型更新问题,提出了动态最小二乘支持向量机学习算法.该算法充分利用已建好的模型,逐渐加入新样本,并可删除位于任何位置的非支持向量,避免了矩阵求逆运算,保证了算法的高效率.大坝变形及电离层延迟两个时间序列的预报实例表明,该算法具有计算时间短、预报精度高的特点.     

葛店矿双庙扩大区三维地震勘探

葛店煤矿双庙扩大区位于豫、皖两省交界处。勘探区为一轴向北北东向的不对称向斜构造,地层倾角26°～30°,测区深部有岩浆岩侵入体,严重影响煤层赋存形态;地表条件复杂,村庄密集、河流较多,测区东侧塌陷区水塘大面积分布．三维地震勘探野外施工难度大。本区地震勘探观测系统设计为12线18炮制,为避免偏移归位及叠加次数降低等问题,在向斜轴部两侧、村子周边及河岸处适当加密炮点,并在塌陷区利用钢钎插置检波器以保证CDP点完整性。数据处理采取了叠前反褶积、叠前时间偏移等技术,数据处理效果显著。遵循多波组对比、多个数据体综合解释的原则,以纵向、横向和任意时间剖面相结合,充分利用三维可视化技术进行地震资料解释。本次勘探成果查明了主采煤层三2^2、二2煤层的构造形态及埋藏深度;解释落差5m以上断层34条,其中修改原有断层5条;另外新发现小于5m的异常断点22个。经巷道验证煤层底板标高误差0．43％～1．96％,巷道已揭露断层7条,与解释成果基本一致。     

叠前时间偏移方法在煤田勘探中的应用

根据克希霍夫积分法的原理,介绍了叠前时间偏移的方法特点,实现过程,以及对地震资料的要求,依托国家重大产业技术专项“西部煤炭资源高精度三维地震勘探”工程,对“青海省鱼卡煤田四井田高精度三维地震勘探”资料进行叠前时间偏移,结果表明其能较好地解决成像质量差、能量聚焦不明显、绕射波收敛不理想等方面的难题。通过与叠后时间偏移对比,对于大倾角地层、断块小且多的破碎带、陡倾角不对称向斜等地质问题,其叠前时间偏移剖面成像质量都有明显的提高,反映的构造关系更加清晰,同相轴连续性增强。总结该方法在多个矿区的推广经验．认为合理的观测系统、较高的资料信噪比,准确的测量资料及较高的中表层速度调查精度是做好叠前时间偏移的前提。     

第二次土地调查若干问题探讨

第二次土地调查的目的是全面查清全国土地利用状况,掌握真实的土地基础数据,如何保证调查的质量?文章以江阴市为例进行探讨。     

Group Time Delay in the Reflection of P-Polarized Electromagnetic Plane Waves at a Stratigraphic Interface

The group time delay (GTD) formulae of quasi-total reflection of inhomogeneous P-polarized electromagnetic waves (P-PEW, whose electric field parallels to the plane of incidence), caused by the Goos–Hänchen effect, is derived by the phase shift of the wave. A numerical example where the frequency equals to 1 GHz is given. The curves of calculating results show that there are three discontinuous points at the critical angle of phase shift vector, the critical angle of attenuation vector and 90^○. When the angle of incidence is equal to one of these three angles, the GTD will become infinite, and the electromagnetic wave will propagate along the interface. The GTD will be very large, when the angle of incidence is close to one of these three angles. The results indicate that there is an important relationship between the two critical angles and the conductivity and permittivity of the two strata, and that the GTD has an important relationship with the angle of incidence. These results can be used to determine the lithology of the strata and to delimit the interfaces of strata more effectively. It is suggested that this research may prove useful in electromagnetic logging analysis and, perhaps, in the design of logging instruments.