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Abstract: A strange, unidentified, Cu-Fe bearing zinc sulfide occurs in the Laloki massive sulfide deposit, Papua New Guinea. The mineral is optically uniform in texture but is chemically variable and zoned even within a single grain. Copper contents vary from 0.1 up to 8.85 wt%. Iron reaches 18.31 wt% at maximum and decreases as Cu increases. It is remarkable, however, that the total Fe+Cu remains essentially unchanged between roughly 18 and 20 wt%. Zn and S are least variable, giving 45.85–47.84 wt% and 33.48–34.58 wt%, respectively. Other trace elements such as Cd and Mn are in general less than 0.2 wt%. It is strongly suggested that the mineral in question constitutes a unique Fe-Cu substitutional solid solution series belonging essentially to the Zn–Fe–Cu–S system.
The ideal chemical formula of the solid solution series can well be presented as Zn10 (Fe, Cu)5 S15 or Zn2 (Fe, Cu)S3 , where Fe is always greater than Cu. It is intriguing that chalcopyrite blebs are recognizable restrictively only in nearby portions of the Cu-rich end member with the ideal composition close to Zn10 Fe3 Cu2 S15. It has been confirmed by vacuum-sealed heating experiments that this mineral is decomposed to produce chalcopyrite and Fe-bearing normal sphalerite at temperatures below 200C. This would provide another evidence for the existence of such distinct phase as suggested here. 相似文献
The ideal chemical formula of the solid solution series can well be presented as Zn
23.
Yves Moëlo Pierre Palvadeau Nicolas Meisser Alain Meerschaut 《Comptes Rendus Geoscience》2002,334(8):529-536
Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å3, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu0.15Pb2(Pb0.53Sb0.47)(Pb0.46Sb0.54)(Sb0.75Pb0.19Bi0.06)S6; the reduced one: Cu0.58Pb12.72(Sb7.04Bi0.24)S24. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536. 相似文献
24.
阿尔泰可可塔勒铅锌矿床围岩蚀变及成因 总被引:2,自引:3,他引:2
可可塔勒铅锌矿床受火山喷发中心和沉积洼地控制,铅锌沉淀于海进阶段的局限还原卤水池中;矿下存在大型蚀变带,构成成矿流体对流循环过程中的水-岩作用带;后期造山挤压过程使地层和矿体倒转,矿床最终定位于麦兹倒转向斜之北东倒转翼的东南近转折部位。指出该矿床属海底火山喷流沉积改造型块状硫化物铅锌矿床。 相似文献
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Re-Os Age of Cu-Ni Ores from the Huangshandong Cu-Ni Sulfide Deposit in the East Tianshan Mountains and Its Implication for Geodynamic Processes 总被引:4,自引:0,他引:4
MAO Jingwen YANG Jianmin QU Wenjun DU Andao WANG Zhiliang HAN Chunming Faculty of Geosciences Resources China University of Geosciences Beijing E-mail: jingwenmao@.netInstitute of Mineral Resources Chinese Academy of Geological Sciences Beijing National Research Center of Geoanalysis Chinese Academy of Geological Sciences Beijing 《《地质学报》英文版》2003,77(2):220-226
An isochron age of 282±20 (95% conf. limit) Ma of the sulfide ores in the Huangshandong Cu-Ni sulfide deposit, the East Tianshan Mountains has been obtained through Re-Os isotopic measurement. The age implies that the Cu-Ni sulfide deposit and other related deposits in the same area occurred in a Permian extensional environment of post-collision instead of Devonian-Early Carboniferous ophiolite-related oceanic or island arc environments inferred before. It shares the same ages with the orogenic and epithermal gold deposit systems in the same area. An initial 187Os/188Os ratio of 0.25±0.04 (1σ) and a γos value of 99 on average display the participation of large quantities of crustal components into the rock-forming and ore-forming system during mineralization and magmatic emplacement. 相似文献
27.
略阳煎茶岭铜镍硫化物矿床Re—Os同位素年龄及其地质意义 总被引:12,自引:0,他引:12
采用矿石Re-Os同位素方法对陕西省煎茶岭硫化镍矿床矿石进行了成矿年代学研究,获得了878士27 Ma(1σ)的等时线年龄,首次厘定了该矿床成矿时代为新元古代,成岩成矿基本同时.通过对878 Ma硫化镍矿石初始Re-Os同位素体系的γOs计算和Re/Os值分析表明,其yOs和Re/Os值变化范围大,深部条带状矿石的Re/Os值仅为0.05,yOs为-6.70;块状矿石的Re/Os值范围为4.24~24.43,γOs为-15.37~+280.65,说明成矿过程中有壳源物质的混染;两件样品的γOs为负值(-15.37,-6.70),可能指示其超镁铁质岩浆来源于Re亏损地幔.煎茶岭超基性岩体年龄及其镍矿石的Re-Os等时线年龄与扬子克拉通北缘火山岩浆活动时间相对应,它们是扬子克拉通西北缘晋宁期构造岩浆成矿作用的产物. 相似文献
28.
同位素稀释中子活化分析铼与感耦等离子体质谱法测定锇相结合,应用于辉钼矿及铜_镍硫化物矿物的铼_锇年龄测定,取得了满意的结果,扩大了铼_锇测年法的应用范围。 相似文献
29.
云南宁蒗地区喜山期斑岩带地质特征与成矿 总被引:1,自引:0,他引:1
斑岩带受近南北向的包都-波罗弧形断裂控制,由混源型岩浆被动侵位而成,属钙碱性系列,中酸性岩。研究表明为含铜或铜(钼)斑岩,具良好的成矿前景。 相似文献
30.
建德铜矿床的海底喷流沉积成因 总被引:2,自引:0,他引:2
建德铜矿床是浙江西部多金属成矿带中一个引人瞩目的重要矿床。它产于中石炭统底部伴有火山岩、硅质岩和碧玉岩的白云岩中。整合块状矿体之下有一筒状矿化蚀变带。其成分以Cu>Zn>Pb为特征。根据矿床地质、地球化学特征以及近年来研究所获得资料,认为该矿床属海底喷流沉积成因 相似文献