Li2S—B2O3体系玻璃的形成及其稳定性研究

本要用情性气体保护下的高温熔融反应及液氮淬冷技术制备了Li_2S-B_2O_3体系玻璃。采用XRD、ICP及化学滴定法分别确定了产物的形态和化学组成。利用DTA星热法测定了玻璃的转变温度Tg、晶化温度Tc及晶化峰值温度Tp，并根据Tg、Tc-Tg、Tp－Tg、（Tp－Tg）／Tg四种玻璃稳定性判据讨论了Li2S-B2O3玻璃的相对稳定性。实验表明，Li2S-B2O3体系能在Li2S的摩尔分数X≤0．45的浓度范围形成玻璃，且在x=0．25附近玻璃的稳定性最强。     

福建漳浦玻璃用砂矿资源特征与找矿远景

漳浦县玻璃用砂资源储量集中在六鳌、古雷两个半岛,多以大型矿床产出,矿砂质量较好,矿砂中对玻璃生产质量有影响的主要是铁矿物,通过选矿可以达到浮法玻璃用砂要求。根据成矿地质条件,在六鳌半岛等地仍有找矿远景。     

Geochemical fingerprint of hyaloclasts in glassy fragmental rocks of Macquarie Island (Southern Ocean): implications for volcanogenic sedimentary processes at a waning mid-ocean ridge

Two main types of glassy fragmental rocks formed along the Proto-Macquarie Spreading Ridge: (i) hyaloclastite breccia; and (ii) pillow-fragment breccia. Examples now exposed on Macquarie Island, Southern Ocean, were largely sourced from proximal pillow lavas. In each of seven samples examined, hyaloclasts (basaltic glass grains) have a narrow major- and trace-element geochemical range, consistent with derivation of each sample from a single volcanic eruption event. Moreover, every sample analysed within the one stratigraphic section (at three sites) displays distinctive major- and trace-element geochemistry compared with the other two sections. This suggests that hyaloclasts at each site represent discrete magma batches. A single source for these glassy fragmental rocks contrasts with the dominant fault-scarp-derived polymict sedimentary rocks on Macquarie Island. We suggest that the hyaloclasts analysed in this study were deposited in small basins between the slopes of growing pillow cones along the mid-ocean ridge. The geochemical analyses presented here encompass (weakly) fractionated (e.g. Bauer Bay) to near-primitive (e.g. Pyramid Peak) compositions. All samples presented here lie within the range of the enriched- to normal-MORB suites previously reported for the island that include the least fractionated MORB melts known globally. The interpretation of geochemically distinct magma batches over the small area of the island suggests very limited magma mixing consistent with an immature or waning magmatic system. We relate these geochemical characteristics to: (i) volcanism near a very long offset transform; and (ii) genesis of magmas during the waning stages of slow seafloor spreading within a very narrow (<50 km-wide) spreading corridor.     

重庆忠县翠屏山西晋崖墓出土宝玉石和玻璃饰品的工艺初探

利用显微镜对重庆忠县翠屏山西晋时期崖墓出土的玛瑙珠、琥珀饰品和玻璃珠的表面痕迹进行了显微观察,对它们的加工工艺进行了分析和探讨。其中,玛瑙珠在粗磨过程中应使用了粒径较大、粒度不均匀的石英砂粒,导致玛瑙珠的外形不规整,表面多大而深的凹坑;琥珀饰品的钻孔外缘和表面存在较多应力裂纹,显示当时的玉匠对琥珀的加工尚不能克服琥珀性脆、怕热的缺点;玻璃珠至少可见铸造——切削成形、缠珠和直管切割3种制作工艺。这些饰品的特点反映了西晋时期平民社会所使用的饰品的面貌和工艺水平,为中国古代宝玉石和玻璃器的断代以及工艺研究提供了新的信息。     

显微CT技术在古代料珠研究中的应用——以河南淅川县马川墓地出土料珠为例

本文首次运用显微CT技术对中国早期料珠进行研究。X-射线衍射（XRD）及CT切片分析结果表明,河南淅川县马川墓地出土的料珠为玻璃珠,与西周时期的釉砂珠在结构上存在显著区别。显微CT技术为料珠材质的鉴定提供了一种新方法。结合玻璃珠的三维模型表明,战国时期玻璃珠内的气泡以球形为主,内部存在许多细小不规则的空隙,应是采用模压法工艺制造;这是在研究中首次发现战国时期采用模压法工艺制造玻璃珠。西汉时期玻璃珠内的气泡是纺锤状,应是采用拉制法工艺制造。显微CT技术能清晰无损地揭示古代玻璃珠内部结构特点,显示了该技术在古代玻璃珠制造工艺研究中有着广阔的运用前景。     

Calibration of a hysteretic model for glass fiber reinforced gypsum wall panels

Glass fi ber reinforced gypsum(GFRG) wall panels are prefabricated panels with hollow cores, originally developed in Australia and subsequently adopted by India and China for use in buildings. This paper discusses identifi cation and calibration of a suitable hysteretic model for GFRG wall panels fi lled with reinforced concrete. As considerable pinching was observed in the experimental results, a suitable hysteretic model with pinched hysteretic rule is used to conduct a series of quasi-static as inelastic hysteretic response analyses of GFRG panels with two different widths. The calibration of the pinching model parameters was carried out to approximately match the simulated and experimental responses up to 80% of the peak load in the post peak region. Interestingly, the same values of various parameters(energy dissipation and pinching related parameters) were obtained for all fi ve test specimens.     

X射线荧光光谱法测试重晶石中的多元素

采用玻璃熔片法制样,建立了重晶石中多元素X射线荧光光谱分析方法.准确称取待测样品0.5000 g,X射线荧光专用熔剂5.000 g;二者混合后,通过高频熔样机在1150℃进行熔片处理8 min;将最终得到的样片放入干燥器中冷却至室温,然后准确称取玻璃片质量;上机测试,所得到的数据为该元素在玻璃片中的含量;通过换算最终得到实际样品中的该元素含量.使用理论α系数法和经验系数法相结合来回归校正共存元素间的吸收增强效应.本方法对于重晶石中各元素的测试相对标准偏差处于0.2%~4.7%之间,方法检出限在3.3×10^-6~170.6×10^-6之间.测试数据通过与国家标准物质比对,结果合理.     

The Preparation and Preliminary Characterisation of Three Synthetic Andesite Reference Glass Materials (ARM‐1, ARM‐2, ARM‐3) for In Situ Microanalysis

Three synthetic reference glasses were prepared by directly fusing and stirring 3.8 kg of high‐purity oxide powders to provide reference materials for microanalytical work. These glasses have andesitic major compositions and are doped with fifty‐four trace elements in nearly identical abundance (500, 50, 5 µg g^?1) using oxide powders or element solutions, and are named ARM‐1, 2 and 3, respectively. We further document that sector‐field (SF) ICP‐MS (Element 2 or Element XR) is capable of sweeping seventy‐seven isotopes (from ⁷Li to ²³⁸U, a total of sixty‐eight elements) in 1 s and, thus, is able to quantify up to sixty‐eight elements by laser sampling. Micro‐ and bulk analyses indicate that the glasses are homogeneous with respect to major and trace elements. This paper provides preliminary data for the ARM glasses using a variety of analytical techniques (EPMA, XRF, ICP‐OES, ICP‐MS, LA‐Q‐ICP‐MS and LA‐SF‐ICP‐MS) performed in ten laboratories. Discrepancies in the data of V, Cr, Ni and Tl exist, mainly caused by analytical limitations. Preliminary reference and information values for fifty‐six elements were calculated with uncertainties [2 relative standard error (RSE)] estimated in the range of 1–20%.     

新型酸性水玻璃-碳酸钙注浆材料试验研究

研究水玻璃-碳酸钙注浆材料随着碳酸钙加入量的变化胶凝时间的变化规律发现,随着碳酸钙加入量的减少,溶胶胶凝时间随之增加,但并非均匀增加,当碳酸钙的量减少到一定量时,溶胶的胶凝时间会有一个突增点,溶液对碳酸钙的加入量非常敏感,凝胶时间不易准确控制。这是因为碳酸钙在整个反应体系中充当碱性反应剂,与溶液体系中的H+反应,降低了硫酸的浓度,提高了溶胶的pH值,从而改变了溶胶的胶凝时间。选择胶凝时间适宜的胶体测定其本身的强度以及对应的固砂体强度,得出两种强度的变化规律：在硫酸用量一定的条件下,一般随碳酸钙的增加,纯胶体强度会相应增加,但加入到一定量后,其强度不再增加。而固砂体强度随碳酸钙的变化并不明显。选择较优配比浆液作为新型注浆材料,并根据浆液的性能,建议相应的注浆工艺。为后续工程应用作了较好的铺垫。     

K‐ and Si‐rich glasses in harzburgite from Damaping,north China

A study of potassium‐ and silica‐rich glass (SiO₂ = 65.3–67.4%, K₂O = 7.1–9.8%, Na₂O = 4.4–6.5%) in spongy clinopyroxene rims from anhydrous spinel harzburgite, collected from Damaping (Hannuoba, north China), is reported here. The corroded surface of clinopyroxene along with clear chemical zonation (homogeneous core and partially melted rim) suggests that incongruent melting of primary clinopyroxene is responsible for generating the Si‐rich glass in clinopyroxene rims. The degree of clinopyroxene melting is estimated to be higher than 15%. In order to generate glass with K₂O contents of 7.0 to 9.8% by clinopyroxene melting at a degree of 15% in a closed system, K₂O contents in the primary clinopyroxene should be greater than 1.0 wt%, suggesting a very deep origin for the Damaping harzburgite.