江西省德兴铜矿矿区重金属元素的环境效应

本文系统研究了德兴铜矿排石场和尾砂库的环境问题,以环境介质（水土植物）中重金属元素含量为研究对象,论述矿区重金属的环境效应。研究结果表明祝家村低品位矿石堆浸场淋滤产生的酸性废水是造成大坞河流域重金属污染的主要来源。大坞河上游水体中Cu元素含量高达14506μg/L,是国家Ⅲ级水标准的14倍之多,Zn元素含量高达2938μg/L,是国家Ⅲ级水标准的2.9倍,同时pH值在3~4范围内;到中下游水体中Cu元素含量减小到几千到几百μg/L,水质有所改善。大坞河沿岸上游和中游土壤重金属含量受河水影响,随着与河岸距离的增加而减小。同时水稻中Pb元素含量是国家粮食标准的2倍。推测4#尾砂库尾砂表层氧化带深度大于80cm;而1#尾砂库库内尾砂中氧化带估计在0~25cm处。推测两个尾砂库产酸能力小于酸中和能力,故坝底水中pH值在7左右,对周围水体影响较小。与4#尾砂库距离近的石墩头村稻田表层土壤中Cu、Mo元素含量较高,远离尾砂库土壤中重金属含量降低。同时4#尾砂库周围土壤中Cd、Pb、Cu元素的吸附态、碳酸盐态比例在20%左右,因而在酸性环境下较容易被植物吸收。1#尾砂库矿建村种植的小白菜中Pb元素含量超过国家蔬菜标准的4倍,Cu、Pb、Zn元素含量严重超过背景值。     

Multivariate analysis of heavy metal contents of sediments from Gumusler creek, Nigde, Turkey

In this study, heavy metal contents of samples from Gumusler creek in Turkey were studied and the metal contamination characteristics were investigated. In this respect, considering the pollutant sites in the area, systematic sediment samples were collected in a zone starting from the manifestation part of the water to the entrance of the Karasu creek in Gumusler town. Samples were taken from lower section of the river bed at 30 stations along Gumusler creek, 13 km in length and their heavy metal contents were analyzed with XRF Spectrometer. Correlation coefficients, element coefitic coefficient correlation, dendogram hierarchical cluster, model summary and Annova analysis statistical methods were applied to data. Strong positive correlations were determined for some elements which are believed to have possibly the same origin. In addition, mineralizations in the area are thought to cause variation in metal contents. Results of chemical analysis show that soil limit values and clark values were exceeded. The heavy metal accumulation in the creek is believed to be derived from non-operated Sb-Hg-W and Fe quarries.     

土壤聚合物对几种重金属离子固化效果的研究

土壤聚合物是一种新型的无机聚合物,其分子链由Si、O、Al等以共价键或离子键连接而成,形成网络结构,对重金属有较强的固定作用.本文试图利用土壤聚合物固化铜、锌、铅三种重金属离子,实现资源化利用.实验以固化体抗压强度和浸出毒性作为性能表征量,结果表明:土壤聚合物对不同重金属的固化有各自的极限浓度,Cu2 、Zn2 、Pb2 的理想固化量分别为0.9%、1%、2%;若固化过程中添加一定量的高炉矿渣,则可以提高固化体的抗压强度.本文通过土壤聚合物固化体SEM分析,从固化体微观结构的形态来阐述土壤聚合物宏观上的优越表现.     

近江牡蛎作为重金属污染生物指示种的初步研究

对近江牡砺作为监测广东岸海域Ｃｕ，Ｚｎ，Ｃｄ，Ｐｂ污染的生物指示种的可能性进行了初步研究和评价，应用ＰＯＬＹＤＩＶ统计技术对采自广东沿岩海域１４个站点的近江牡盛的重金属含量进行了统计分析，结果表明近江牡蛎受Ｃｕ，Ｚｎ，Ｃｄ污染的地理分布类型与广东沿海排放的工业废水的分布以及潮间带生物和表层沉积物的Ｃｕ，Ｚｎ，Ｃｄ含量分布相一致，因此，近江牡蛎可作为监测研究Ｃｕ，Ｚｎ，Ｃｄ污染的可靠生物指示种，但能     

大亚湾沉积物中重金属元素背景值研究

根据大亚湾的自然条件认为,大亚湾沉积物的物质来源是其周围集水区的岩石风化壳,并计算了其风化壳中重金属元素的平均丰度值;又根据沉积物的粒度和深层沉积物重金属元素的含量资料,列方程计算出湾内沉积物中重金属元素的平均含量,根据这两组数据,确定该区域内重金属元素的平均背景值。再通过粒度关系,计算得出大亚湾内各站沉积物中重金属元素的背景值。应用此结果和大亚湾沉积物重金属元素实测结果,计算了由人为影响带入沉积物中的重金属元素含量,了解其受污染的程度。     

珠江口沉积物酸挥发性硫化物与重金属生物毒性的研究

研究了2003年10月采于珠江口5个站位的沉积物剖面酸挥发性硫化物(AVS)和同时提取的重金属(SEM:Pb,Zn,Cu,Cd,Ni)。其中,站位1、2位于中滩,其沉积物的AVS含量变化范围较小,为0.25—4.06μmol.g-1;站位3、4位于西滩,其沉积物的AVS含量变化范围较大,为0—26.09μmol.g-1。中滩和西滩沉积物的AVS含量均随深度增加。西滩表层沉积物的AVS含量接近于零,这可能与该水域较强的底层流和沉积物的再悬浮作用有关。站位5位于珠江口外侧,其表层沉积物的AVS含量相对较高,且垂向变化较小,可能是还原性沉积物间歇性再悬浮后重新沉积的结果。站位1、2和5沉积物中同时提取的重金属含量大体在0.95±0.2μmol.g-1范围内,随深度增加略呈下降趋势;而西滩沉积物重金属含量相对较高,为1.43—2.42μmol.g-1,且在一定深度范围内随深度增加呈明显下降的趋势,表明珠江口西滩沉积物中的重金属污染有加重的趋势。对AVS/SEM摩尔比值和单个金属的毒性效应研究显示,珠江口内尤其是西滩的表层沉积物存在重金属污染,对其中生活的底栖生物具有潜在的毒性效应。     

渤海湾表层沉积物重金属与污染评价

用原子吸收法测定了渤海湾表层沉积物中重金属的含量,同时用2种评价方法对该海域底质环境进行了评价。结果表明:沉积物中汞、锌含量平均值超过标准,其余项目未发现超标;其分布特征由于受沿岸不同污染源的污染影响,重金属污染物难以形成一定规律的分布状态。同时该海域底质环境质量总指数已达到污染程度和很强的生态危害,其中主要污染元素是Hg,已达重污染,并形成极强的生态危害。     

Trichodesmium erythraeum (Ehrenberg) bloom along the southwest coast of India (Arabian Sea) and its impact on trace metal concentrations in seawater

The incidence of a large scale Trichodesmium erythraeum bloom along the southwest coast of India (Arabian Sea) observed in May 2005 is reported. Around 4802 filaments of T. erythraeum ml⁻¹ seawater was observed and a colony consisted of 3.6 × 10⁵ cells. The bloom was predominant off Suratkal (12° 59′N and 74° 31′E) with a depth of about 47 m, covering an area of 7 km in length and 2 km width. The concentrations of Zinc, Cadmium, Lead, Copper, Nickel and Cobalt were determined in samples collected from the bloom and non-bloom sites using stripping voltammetry. The observed hydrographical and meteorological parameters were found to be favorable for the bloom. The concentrations of Zinc, Cadmium and Nickel were found to be higher at bloom stations, while the concentrations of Lead, Copper and Cobalt were found to be very low at bloom stations. Elevated concentrations of Cadmium and Cobalt were observed at Valappad mainly due to the decomposition of detrital material produced in the bloom. Statistically significant differences (P > 0.01) in metal concentrations between the bloom and non-bloom stations were not observed except for Copper. Metals such as Lead, Copper and Cobalt were removed from the seawater at all places where bloom was observed. Cadmium was found to be slowly released during the decaying process of the bloom.     

上海潮滩沉积物重金属的动力学累积特征

１９９３年７－８月，在上海长江口南岸和杭州湾北岸淤泥质潮滩不同地貌部位，采集表层沉积物和柱状沉积物样品，采用筛析法，离心法、火焰原子吸收法，＾２１０Ｐｂ法等分别对沉积物粒度、重金属总量，不同粒级重金属含量以及沉积速率等进行了和测定。结果表明，潮滩沉积物重金属的空间分布格局并不受沿岸排污的直接影响，而与沉积动力作用密切相关。在水动力条件较弱的淤涨岸段和高潮滩部位，伴随着细颗粒起泥沙的大量堆积，Ｃｕ，