龙门山地区泥盆纪碳酸盐与硅质碎屑的混积相与混积机理

碳酸盐与陆源碎屑的混合沉积研究至今尚未引起足够重视。文献屈指可数。扬子西经缘龙门山地区盆纪发育了了这类良好的混合沉积。作者根据实际材料，首次从这一思路出发，识别该区泥盆纪Ｅｍｓｉａｎ期到Ｇｉｖｅｔｉａｎ早期的混积相四种，混积亚相约１４种，阐明了其优势混积作用；根据混积作用特征、沉积背景关系，划分出两大混积类型，即泥质背景下的混积１型和砂灰质背景下的混积Ⅱ型；对混积作用机理进行了探讨；并指出不同级次     

多金属结核中二氧化锰的测定

用过量的含有Ｈ２ＳＯ４的（ＮＨ４）２Ｆｅ（ＳＯ４）２溶液分解多金属结核的同时，还原了试样中的ＭｎＯ２，然后以Ｋ２Ｃｒ２Ｏ７标准溶液滴定测定了多金属结核中的ＭｎＯ２。就样品分解过程中的加热温度和时间对测定结果的影响及标准溶液的标定等问题进行了讨论，经多次测定，方法重现性好。应用此方法为新研制的多金属结核标准物质提供了ＭｎＯ２的定值数据，其结果与初定值相符，无剔除值，精密度（ＲＳＤ，ｎ＝８）小于０６％。     

痕量铁和锰的化学发光检测

评述了国内外有关铁、锰的化学发光分析进展。从发光体系、操作方式、最佳条件、干扰离子、检测限等各个方面对化学发光法测定铁、锰及其它们与其它组分同时测定中的应用进行分类评述。     

加强富锰矿勘查工作,促进锰业发展

我国现有锰矿资源状况，不能满足钢铁工业发展的需要。寻找低磷低铁低硅富锰矿，是解决锰矿资源短缺的重要途径。城口锰矿具有较大的找矿前景，锰矿层产出稳定，锰含量高，铁含量低，烧失量大。加强城口矿区勘查，扩大矿床规模，可望成为我国锰矿的重要生产基地。     

湘西南区氧化锰矿成矿规律及找矿方向

湘西南区氧化锰矿以锰帽型氧化锰矿为主，赋矿地层为震旦系下统湘锰组。其特点是含锰点多，分布面广，矿体在地壳贫化，往下３～７ｍ开始富集，氧化深度４０ｍ左右。     

黔南Triticites带旋回层序碳同位素特征及冰川型海平面变化

应用层序地层学理论对黔南独山地区晚石炭世麦粒链带地层进行了详细的沉积层序分析和系统的碳同位素测定，识别出２个三级沉积层序和１７个准层序，其可与北美中大陆同期地层中发现的２个三级沉积层序和１７个亚层序对比，是晚石炭世Ｇｚｈｅｌｉａｎ期存在全球沉积记录同时性的佐证。同时探讨了碳同位素演化与全球海平面变化之间的内在联系，总结出沉积层序内碳同位素演化规律。     

Dissolved carbon in pore waters from the carbonate barrier reef of Tahiti (French Polynesia) and its basalt basement

This paper deals with dissolved inorganic carbon (DIC) and organic carbon (DOC) in pore waters from a 150 m deep hole drilled through the carbonate barrier reef of Tahiti and its underlying basalt basement. Alkalinity-pH measurements were used to calculate the DIC species concentration, and DOC was analysed according to the high temperature catalytic oxidation technique. Salinity was used as a conservative tracer to help identify water origin and mixing within the hole. Water mixing, calcium carbonate dissolution and mineralization of organic carbon combined to form three distinct groups of pore water. In the deeper basalt layers, pore water with alkalinity of 1.4 meq kg^–1 pH of 7.6 and p(CO₂) of 1.2 mAtm was undersaturated with respect to both aragonite and calcite. In the intermediate carbonate layer, pore water with alkalinity of more than 2.0 meq kg^–1, pH of 7.70 and p(CO₂) of 1.4 mAtm was supersaturated with respect to both aragonite and calcite. The transition zone between those two groups extended between 80 and 100 m depth. The shift from aragonite undersaturation to supersaturation was mainly attributed to the mixing of undersaturated pore waters from the basalt basement with supersaturated pore waters from the overlaying limestone. In the top of the reef, inputs from a brackish water lens further increased p(CO₂) up to 5.6 times the atmospheric P(CO₂).     

Reconstruction of atmospheric CO2 from ice-core data and the deep-sea record of ontong Java plateau: the Milankovitch chron

We provide a reconstruction of atmospheric CO₂ from deep-sea sediments, for the past 625000 years (Milankovitch chron). Our database consists of a Milankovitch template of sea-level variation in combination with a unique data set for the deep-sea record for Ontong Java plateau in the western equatorial Pacific. We redate the Vostok ice-core data of Barnola et al. (1987). To make the reconstructions we employ multiple regression between deep-sea data, on one hand, and ice-core CO₂ data in Antarctica, on the other. The patterns of correlation suggest that the main factors controlling atmospheric CO₂ can be described as a combination of sea-level state and sea-level change. For best results squared values of state and change are used. The square-of-sea-level rule agrees with the concept that shelf processes are important modulators of atmospheric CO₂ (e.g., budgets of shelf organic carbon and shelf carbonate, nitrate reduction). The square-of-change rule implies that, on short timescales, any major disturbance of the system results in a temporary rise in atmospheric CO₂.     

The Silurian of Gotland (Sweden): facies interpretation based on stable isotopes in brachiopod shells

The Silurian of Gotland, Sweden, consists of 440 m of carbonate deposits. Repeatedly, uniform sequences of micritic limestones and marls are interrupted by complex-structured reefs and by adjacent platform sediments. Generally, the alteration of facies is interpreted as the result of sea-level fluctuations caused by a gradual regression with superimposed minor transgressive pulses. The purpose of this study is a facies interpretation based on both field observations and stable isotope measurements of brachiopod shells. Approximately 700 samples from stratigraphically arranged localities in different facies areas have been investigated. The carbon and oxygen isotopes show principally parallel curves and a close relationship to the stratigraphic sequence. Lower values occur in periods dominated by deposition of marly sequences. Higher values are observed in periods dominated by reefs and extended carbonate platforms. The oxygen isotope ratios are interpreted to reflect paleosalinity changes due to varying freshwater input, rather than to paleotemperature. Carbon isotope ratios are believed to have been connected to global changes in the burial of organic carbon in black shales during periods of euxinic deep water conditions. Consequently, the facies succession on Gotland results from global paleoclimatic conditions. Changes in terrigenous input due to different rates of weathering and freshwater runoff, rather than sea-level fluctuations, control the carbonate formation of the Silurian on Gotland.